# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2014

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
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#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
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#  except for the purpose of generating routine backup copies
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data_2

_database_code_CSD               'CCDC 870723'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_formula_moiety         'C46 H41 Dy N10 O4, C2 H6 O, 2(N O3), 4(H2 O)'
_chemical_formula_sum            'C48 H55 Dy N12 O15'
_chemical_melting_point          ?

_exptl_crystal_description       bloc
_exptl_crystal_colour            'very pale yellow'

_diffrn_ambient_temperature      100(1)
_chemical_formula_weight         1202.54

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_symmetry_int_tables_number      2
_chemical_absolute_configuration .

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.507(4)
_cell_length_b                   12.912(5)
_cell_length_c                   17.853(5)
_cell_angle_alpha                97.274(4)
_cell_angle_beta                 100.839(5)
_cell_angle_gamma                102.255(5)
_cell_volume                     2507.3(15)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(1)
_cell_measurement_reflns_used    9693
_cell_measurement_theta_min      2.63
_cell_measurement_theta_max      43.32
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.11
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.593
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1226
_exptl_absorpt_coefficient_mu    1.572
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6853
_exptl_absorpt_correction_T_max  0.8461
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
;
 ?
;
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_type              'kappa X8 APEX II Bruker ICMMO'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            85656
_diffrn_reflns_av_R_equivalents  0.0146
_diffrn_reflns_av_sigmaI/netI    0.0120
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_theta_min         1.86
_diffrn_reflns_theta_max         43.41
_reflns_number_total             22076
_reflns_number_gt                21154
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0275P)²+1.5177P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         22076
_refine_ls_number_parameters     682
_refine_ls_number_restraints     15
_refine_ls_R_factor_all          0.0233
_refine_ls_R_factor_gt           0.0212
_refine_ls_wR_factor_ref         0.0560
_refine_ls_wR_factor_gt          0.0540
_refine_ls_goodness_of_fit_ref   1.119
_refine_ls_restrained_S_all      1.120
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.88455(8) 0.27498(11) 0.38607(5) 0.0088(2) Uani 1 1 d . . .
C2 C 0.82916(8) 0.18416(11) 0.42176(5) 0.0101(3) Uani 1 1 d . . .
C3 C 0.70284(9) 0.14558(11) 0.40255(6) 0.0128(3) Uani 1 1 d . . .
H3 H 0.6561 0.1752 0.3667 0.015 Uiso 1 1 calc R . .
C4 C 0.64550(10) 0.06339(12) 0.43623(7) 0.0154(3) Uani 1 1 d . . .
H4 H 0.5610 0.0390 0.4235 0.019 Uiso 1 1 calc R . .
C5 C 0.71530(11) 0.01823(12) 0.48881(7) 0.0165(3) Uani 1 1 d . . .
H5 H 0.6776 -0.0362 0.5120 0.020 Uiso 1 1 calc R . .
C6 C 0.84156(11) 0.05423(13) 0.50693(7) 0.0195(3) Uani 1 1 d . . .
H6 H 0.8882 0.0223 0.5411 0.023 Uiso 1 1 calc R . .
C7 C 0.89865(9) 0.13745(12) 0.47439(7) 0.0159(3) Uani 1 1 d . . .
H7 H 0.9831 0.1621 0.4876 0.019 Uiso 1 1 calc R . .
C8 C 1.11810(8) 0.49427(11) 0.42088(5) 0.0101(3) Uani 1 1 d . . .
C9 C 1.18281(10) 0.50221(12) 0.50318(6) 0.0149(3) Uani 1 1 d . . .
H9A H 1.1378 0.4483 0.5263 0.022 Uiso 1 1 calc R . .
H9B H 1.1891 0.5722 0.5315 0.022 Uiso 1 1 calc R . .
H9C H 1.2630 0.4912 0.5046 0.022 Uiso 1 1 calc R . .
C10 C 1.14759(8) 0.58610(11) 0.38039(5) 0.0098(3) Uani 1 1 d . . .
C11 C 1.24241(9) 0.67655(12) 0.41477(6) 0.0134(3) Uani 1 1 d . . .
H11 H 1.2921 0.6784 0.4627 0.016 Uiso 1 1 calc R . .
C12 C 1.26116(10) 0.76314(12) 0.37643(7) 0.0152(3) Uani 1 1 d . . .
H12 H 1.3238 0.8240 0.3982 0.018 Uiso 1 1 calc R . .
C13 C 1.18516(9) 0.75801(11) 0.30498(6) 0.0129(3) Uani 1 1 d . . .
H13 H 1.1935 0.8164 0.2791 0.015 Uiso 1 1 calc R . .
C14 C 1.09616(8) 0.66335(11) 0.27312(6) 0.0096(3) Uani 1 1 d . . .
C15 C 1.01887(8) 0.64901(11) 0.19435(6) 0.0098(3) Uani 1 1 d . . .
C16 C 1.03193(10) 0.73676(12) 0.14739(7) 0.0153(3) Uani 1 1 d . . .
H16A H 1.0082 0.7060 0.0933 0.023 Uiso 1 1 calc R . .
H16B H 1.1154 0.7772 0.1595 0.023 Uiso 1 1 calc R . .
H16C H 0.9807 0.7835 0.1591 0.023 Uiso 1 1 calc R . .
C17 C 0.85184(8) 0.42763(11) 0.06405(5) 0.0101(3) Uani 1 1 d . . .
C18 C 0.78350(8) 0.39476(11) -0.01729(5) 0.0106(3) Uani 1 1 d . . .
C19 C 0.78840(10) 0.46702(12) -0.06950(6) 0.0148(3) Uani 1 1 d . . .
H19 H 0.8315 0.5384 -0.0529 0.018 Uiso 1 1 calc R . .
C20 C 0.72800(10) 0.43076(13) -0.14652(6) 0.0175(3) Uani 1 1 d . . .
H20 H 0.7321 0.4777 -0.1819 0.021 Uiso 1 1 calc R . .
C21 C 0.66188(9) 0.32510(13) -0.17079(6) 0.0160(3) Uani 1 1 d . . .
H21 H 0.6214 0.3017 -0.2224 0.019 Uiso 1 1 calc R . .
C22 C 0.65541(9) 0.25355(12) -0.11884(6) 0.0150(3) Uani 1 1 d . . .
H22 H 0.6100 0.1828 -0.1354 0.018 Uiso 1 1 calc R . .
C23 C 0.71709(9) 0.28826(12) -0.04215(6) 0.0128(3) Uani 1 1 d . . .
H23 H 0.7141 0.2405 -0.0073 0.015 Uiso 1 1 calc R . .
C24 C 1.16085(8) 0.32028(11) 0.25013(5) 0.0094(3) Uani 1 1 d . . .
C25 C 1.29379(8) 0.33141(11) 0.27549(6) 0.0105(3) Uani 1 1 d . . .
C26 C 1.36618(9) 0.43218(12) 0.31417(6) 0.0117(3) Uani 1 1 d . . .
H26 H 1.3309 0.4897 0.3233 0.014 Uiso 1 1 calc R . .
C27 C 1.49137(9) 0.44542(12) 0.33887(7) 0.0153(3) Uani 1 1 d . . .
H27 H 1.5399 0.5121 0.3648 0.018 Uiso 1 1 calc R . .
C28 C 1.54406(9) 0.35997(12) 0.32513(6) 0.0147(3) Uani 1 1 d . . .
H28 H 1.6277 0.3692 0.3422 0.018 Uiso 1 1 calc R . .
C29 C 1.47182(9) 0.26027(12) 0.28579(6) 0.0130(3) Uani 1 1 d . . .
H29 H 1.5073 0.2030 0.2762 0.016 Uiso 1 1 calc R . .
C30 C 1.34661(9) 0.24624(12) 0.26089(6) 0.0120(3) Uani 1 1 d . . .
H30 H 1.2984 0.1797 0.2345 0.014 Uiso 1 1 calc R . .
C31 C 0.89319(9) 0.12595(12) 0.18596(6) 0.0114(3) Uani 1 1 d . . .
C32 C 0.93369(11) 0.02586(13) 0.16718(8) 0.0164(3) Uani 1 1 d . . .
H32A H 1.0179 0.0440 0.1643 0.025 Uiso 1 1 calc R . .
H32B H 0.8851 -0.0142 0.1183 0.025 Uiso 1 1 calc R . .
H32C H 0.9243 -0.0170 0.2068 0.025 Uiso 1 1 calc R . .
C33 C 0.76360(8) 0.12925(11) 0.15997(6) 0.0101(3) Uani 1 1 d . . .
C34 C 0.67370(9) 0.03529(12) 0.12567(6) 0.0128(3) Uani 1 1 d . . .
H34 H 0.6923 -0.0316 0.1217 0.015 Uiso 1 1 calc R . .
C35 C 0.55601(9) 0.04442(12) 0.09771(6) 0.0149(3) Uani 1 1 d . . .
H35 H 0.4939 -0.0168 0.0758 0.018 Uiso 1 1 calc R . .
C36 C 0.53194(9) 0.14496(11) 0.10264(6) 0.0123(3) Uani 1 1 d . . .
H36 H 0.4545 0.1529 0.0820 0.015 Uiso 1 1 calc R . .
C37 C 0.62620(8) 0.23481(11) 0.13926(5) 0.0101(3) Uani 1 1 d . . .
C38 C 0.60676(8) 0.34428(11) 0.15007(5) 0.0099(3) Uani 1 1 d . . .
C39 C 0.48796(9) 0.36935(12) 0.11831(6) 0.0141(3) Uani 1 1 d . . .
H39A H 0.4676 0.4160 0.1575 0.021 Uiso 1 1 calc R . .
H39B H 0.4251 0.3038 0.1026 0.021 Uiso 1 1 calc R . .
H39C H 0.4949 0.4043 0.0745 0.021 Uiso 1 1 calc R . .
C40 C 0.76480(8) 0.58299(11) 0.27025(5) 0.0100(3) Uani 1 1 d . . .
C41 C 0.76094(8) 0.69646(11) 0.28459(6) 0.0109(3) Uani 1 1 d . . .
C42 C 0.86768(9) 0.77275(13) 0.32441(7) 0.0151(3) Uani 1 1 d . . .
H42 H 0.9369 0.7505 0.3449 0.018 Uiso 1 1 calc R . .
C43 C 0.86973(11) 0.88070(14) 0.33319(8) 0.0196(3) Uani 1 1 d . . .
H43 H 0.9415 0.9315 0.3578 0.023 Uiso 1 1 calc R . .
C44 C 0.76514(13) 0.91407(14) 0.30548(8) 0.0190(3) Uani 1 1 d . . .
H44 H 0.7670 0.9870 0.3118 0.023 Uiso 1 1 calc R . .
C45 C 0.65786(12) 0.83879(15) 0.26830(8) 0.0206(3) Uani 1 1 d . . .
H45 H 0.5874 0.8612 0.2509 0.025 Uiso 1 1 calc R . .
C46 C 0.65587(10) 0.73083(13) 0.25720(7) 0.0162(3) Uani 1 1 d . . .
H46 H 0.5844 0.6806 0.2314 0.019 Uiso 1 1 calc R . .
C47 C 1.28999(10) 0.26627(13) 0.52262(7) 0.0178(3) Uani 1 1 d . . .
H47A H 1.2676 0.2025 0.5452 0.021 Uiso 1 1 calc R . .
H47B H 1.2823 0.3279 0.5569 0.021 Uiso 1 1 calc R . .
C48 C 1.41919(12) 0.28177(17) 0.51211(11) 0.0311(4) Uani 1 1 d . . .
H48A H 1.4245 0.2227 0.4755 0.047 Uiso 1 1 calc R . .
H48B H 1.4729 0.2846 0.5609 0.047 Uiso 1 1 calc R . .
H48C H 1.4424 0.3478 0.4933 0.047 Uiso 1 1 calc R . .
N1 N 0.99812(7) 0.32854(9) 0.42008(5) 0.0109(2) Uani 1 1 d . . .
N2 N 1.03174(7) 0.41389(9) 0.38197(5) 0.0097(2) Uani 1 1 d . . .
N3 N 1.07747(7) 0.57891(9) 0.30994(5) 0.0089(2) Uani 1 1 d . . .
N4 N 0.94582(7) 0.55504(9) 0.17133(5) 0.0095(2) Uani 1 1 d . . .
N5 N 0.87731(8) 0.53189(10) 0.09571(5) 0.011 Uani 1 1 d . . .
H101 H 0.8377(17) 0.5772(17) 0.0785(11) 0.014 Uiso 1 1 d . . .
N6 N 1.08774(7) 0.22151(10) 0.24280(5) 0.010 Uani 1 1 d . . .
H102 H 1.1079(17) 0.1681(17) 0.2649(11) 0.014 Uiso 1 1 d . . .
N7 N 0.96455(7) 0.21774(9) 0.22071(5) 0.0100(2) Uani 1 1 d . . .
N8 N 0.73991(7) 0.22616(10) 0.16834(5) 0.0097(2) Uani 1 1 d . . .
N9 N 0.70013(7) 0.41704(9) 0.19132(5) 0.0095(2) Uani 1 1 d . . .
N10 N 0.68648(7) 0.52039(10) 0.20624(5) 0.010 Uani 1 1 d . . .
H100 H 0.6487(17) 0.5455(16) 0.1721(11) 0.013 Uiso 1 1 d . . .
N11 N 0.35685(9) -0.01234(10) 0.26370(6) 0.0143(2) Uani 1 1 d . . .
N12 N 0.64890(9) 0.69260(11) 0.06983(6) 0.0154(3) Uani 1 1 d . . .
O1 O 0.81894(6) 0.29962(8) 0.32809(4) 0.01023(19) Uani 1 1 d . . .
O2 O 0.88853(7) 0.36164(8) 0.10235(4) 0.01112(19) Uani 1 1 d . . .
O3 O 1.11831(6) 0.39814(8) 0.23561(5) 0.01107(19) Uani 1 1 d . . .
O4 O 0.83722(7) 0.54393(8) 0.31245(4) 0.0111(2) Uani 1 1 d . . .
O5 O 0.45439(9) -0.00928(11) 0.24346(7) 0.0231(3) Uani 1 1 d . . .
O6 O 0.35348(8) 0.00493(10) 0.33411(5) 0.0191(2) Uani 1 1 d . . .
O7 O 0.25743(8) -0.03236(10) 0.21381(5) 0.0197(2) Uani 1 1 d . . .
O8 O 0.75910(9) 0.69522(11) 0.06801(8) 0.0277(3) Uani 1 1 d . . .
O9 O 0.58311(9) 0.60904(9) 0.08293(5) 0.0199(2) Uani 1 1 d . . .
O10 O 0.60855(9) 0.77122(10) 0.05783(6) 0.0212(2) Uani 1 1 d . . .
O11 O 1.21222(9) 0.25483(12) 0.44799(6) 0.0274(3) Uani 1 1 d . . .
H11A H 1.1465 0.2664 0.4531 0.041 Uiso 1 1 calc R . .
O12 O 0.13852(8) 0.07808(9) 0.33434(5) 0.017 Uani 1 1 d D . .
H12A H 0.1715(14) 0.1323(12) 0.3797(7) 0.022 Uiso 1 1 d D . .
H12B H 0.2030(11) 0.0432(13) 0.3290(10) 0.022 Uiso 1 1 d D . .
O13 O 0.95727(13) 0.17899(13) 0.03087(7) 0.030 Uani 1 1 d D . .
H13A H 0.9257(16) 0.2375(11) 0.0500(12) 0.038 Uiso 1 1 d D . .
H13B H 0.8875(11) 0.1265(12) -0.0004(11) 0.038 Uiso 1 1 d D . .
O14 O 0.75542(11) 0.02730(13) -0.05505(7) 0.033 Uani 1 1 d D . .
H14A H 0.749(2) 0.0277(18) -0.1093(3) 0.043 Uiso 1 1 d D . .
H14B H 0.7968(15) -0.0280(10) -0.0442(11) 0.043 Uiso 1 1 d D . .
O15 O 0.80409(12) -0.17047(13) -0.04746(9) 0.041 Uani 1 1 d D . .
H15A H 0.7795(18) -0.197(2) -0.0036(9) 0.053 Uiso 1 1 d D . .
H15B H 0.8899(6) -0.166(2) -0.0387(13) 0.053 Uiso 1 1 d D . .
Dy Dy 0.912518(3) 0.398211(4) 0.246556(2) 0.00717(2) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O1 1.2784(12) . ?
C1 N1 1.3291(12) . ?
C1 C2 1.4872(14) . ?
C2 C3 1.3930(14) . ?
C2 C7 1.3971(15) . ?
C3 C4 1.3917(15) . ?
C3 H3 0.9300 . ?
C4 C5 1.3856(18) . ?
C4 H4 0.9300 . ?
C5 C6 1.3893(17) . ?
C5 H5 0.9300 . ?
C6 C7 1.3877(16) . ?
C6 H6 0.9300 . ?
C7 H7 0.9300 . ?
C8 N2 1.2912(14) . ?
C8 C10 1.4772(16) . ?
C8 C9 1.4973(13) . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C10 N3 1.3411(12) . ?
C10 C11 1.3989(16) . ?
C11 C12 1.3827(18) . ?
C11 H11 0.9300 . ?
C12 C13 1.3895(15) . ?
C12 H12 0.9300 . ?
C13 C14 1.3928(16) . ?
C13 H13 0.9300 . ?
C14 N3 1.3425(15) . ?
C14 C15 1.4821(13) . ?
C15 N4 1.2878(16) . ?
C15 C16 1.4916(16) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 O2 1.2503(14) . ?
C17 N5 1.3397(19) . ?
C17 C18 1.4766(13) . ?
C18 C23 1.3942(18) . ?
C18 C19 1.4000(15) . ?
C19 C20 1.3902(16) . ?
C19 H19 0.9300 . ?
C20 C21 1.383(2) . ?
C20 H20 0.9300 . ?
C21 C22 1.3904(18) . ?
C21 H21 0.9300 . ?
C22 C23 1.3868(15) . ?
C22 H22 0.9300 . ?
C23 H23 0.9300 . ?
C24 O3 1.2429(16) . ?
C24 N6 1.3462(16) . ?
C24 C25 1.4817(14) . ?
C25 C30 1.385(2) . ?
C25 C26 1.3999(18) . ?
C26 C27 1.3915(15) . ?
C26 H26 0.9300 . ?
C27 C28 1.384(2) . ?
C27 H27 0.9300 . ?
C28 C29 1.392(2) . ?
C28 H28 0.9300 . ?
C29 C30 1.3907(15) . ?
C29 H29 0.9300 . ?
C30 H30 0.9300 . ?
C31 N7 1.2933(16) . ?
C31 C32 1.485(3) . ?
C31 C33 1.4875(16) . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C33 N8 1.332(2) . ?
C33 C34 1.3993(17) . ?
C34 C35 1.3876(17) . ?
C34 H34 0.9300 . ?
C35 C36 1.379(2) . ?
C35 H35 0.9300 . ?
C36 C37 1.3988(16) . ?
C36 H36 0.9300 . ?
C37 N8 1.3474(14) . ?
C37 C38 1.472(2) . ?
C38 N9 1.2953(14) . ?
C38 C39 1.4959(16) . ?
C39 H39A 0.9600 . ?
C39 H39B 0.9600 . ?
C39 H39C 0.9600 . ?
C40 O4 1.2470(14) . ?
C40 N10 1.3568(14) . ?
C40 C41 1.467(2) . ?
C41 C46 1.3994(18) . ?
C41 C42 1.4018(16) . ?
C42 C43 1.377(3) . ?
C42 H42 0.9300 . ?
C43 C44 1.389(2) . ?
C43 H43 0.9300 . ?
C44 C45 1.389(2) . ?
C44 H44 0.9300 . ?
C45 C46 1.378(3) . ?
C45 H45 0.9300 . ?
C46 H46 0.9300 . ?
C47 O11 1.4294(16) . ?
C47 C48 1.5078(19) . ?
C47 H47A 0.9700 . ?
C47 H47B 0.9700 . ?
C48 H48A 0.9600 . ?
C48 H48B 0.9600 . ?
C48 H48C 0.9600 . ?
N1 N2 1.3910(13) . ?
N2 Dy 2.5057(10) . ?
N3 Dy 2.6402(12) . ?
N4 N5 1.3896(12) . ?
N4 Dy 2.5697(11) . ?
N5 H101 0.87(2) . ?
N6 N7 1.3867(13) . ?
N6 H102 0.89(2) . ?
N7 Dy 2.5349(15) . ?
N8 Dy 2.6699(11) . ?
N9 N10 1.375(2) . ?
N9 Dy 2.5320(12) . ?
N10 H100 0.822(19) . ?
N11 O5 1.2366(15) . ?
N11 O6 1.2581(15) . ?
N11 O7 1.2656(13) . ?
N12 O10 1.2288(18) . ?
N12 O9 1.2552(15) . ?
N12 O8 1.2678(16) . ?
O1 Dy 2.3185(8) . ?
O2 Dy 2.5094(10) . ?
O3 Dy 2.4126(11) . ?
O4 Dy 2.4880(12) . ?
O11 H11A 0.8200 . ?
O12 H12A 0.958(2) . ?
O12 H12B 0.959(2) . ?
O13 H13A 0.958(2) . ?
O13 H13B 0.959(2) . ?
O14 H14A 0.958(2) . ?
O14 H14B 0.958(2) . ?
O15 H15A 0.959(2) . ?
O15 H15B 0.959(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C1 N1 124.64(9) . . ?
O1 C1 C2 118.58(8) . . ?
N1 C1 C2 116.69(8) . . ?
C3 C2 C7 119.02(9) . . ?
C3 C2 C1 118.40(9) . . ?
C7 C2 C1 122.58(9) . . ?
C4 C3 C2 120.98(10) . . ?
C4 C3 H3 119.5 . . ?
C2 C3 H3 119.5 . . ?
C5 C4 C3 119.47(10) . . ?
C5 C4 H4 120.3 . . ?
C3 C4 H4 120.3 . . ?
C4 C5 C6 120.03(10) . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
C7 C6 C5 120.51(11) . . ?
C7 C6 H6 119.7 . . ?
C5 C6 H6 119.7 . . ?
C6 C7 C2 119.95(10) . . ?
C6 C7 H7 120.0 . . ?
C2 C7 H7 120.0 . . ?
N2 C8 C10 115.54(8) . . ?
N2 C8 C9 124.95(10) . . ?
C10 C8 C9 119.42(10) . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
N3 C10 C11 122.02(10) . . ?
N3 C10 C8 116.56(9) . . ?
C11 C10 C8 121.40(9) . . ?
C12 C11 C10 119.03(9) . . ?
C12 C11 H11 120.5 . . ?
C10 C11 H11 120.5 . . ?
C11 C12 C13 119.12(11) . . ?
C11 C12 H12 120.4 . . ?
C13 C12 H12 120.4 . . ?
C12 C13 C14 118.37(11) . . ?
C12 C13 H13 120.8 . . ?
C14 C13 H13 120.8 . . ?
N3 C14 C13 122.80(9) . . ?
N3 C14 C15 115.96(10) . . ?
C13 C14 C15 121.20(10) . . ?
N4 C15 C14 113.84(9) . . ?
N4 C15 C16 125.17(9) . . ?
C14 C15 C16 120.95(10) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
O2 C17 N5 120.20(9) . . ?
O2 C17 C18 121.73(12) . . ?
N5 C17 C18 118.04(10) . . ?
C23 C18 C19 120.27(10) . . ?
C23 C18 C17 118.42(9) . . ?
C19 C18 C17 121.27(11) . . ?
C20 C19 C18 119.18(12) . . ?
C20 C19 H19 120.4 . . ?
C18 C19 H19 120.4 . . ?
C21 C20 C19 120.29(10) . . ?
C21 C20 H20 119.9 . . ?
C19 C20 H20 119.9 . . ?
C20 C21 C22 120.65(10) . . ?
C20 C21 H21 119.7 . . ?
C22 C21 H21 119.7 . . ?
C23 C22 C21 119.59(13) . . ?
C23 C22 H22 120.2 . . ?
C21 C22 H22 120.2 . . ?
C22 C23 C18 120.01(10) . . ?
C22 C23 H23 120.0 . . ?
C18 C23 H23 120.0 . . ?
O3 C24 N6 121.24(9) . . ?
O3 C24 C25 121.78(10) . . ?
N6 C24 C25 116.98(11) . . ?
C30 C25 C26 120.26(10) . . ?
C30 C25 C24 121.87(11) . . ?
C26 C25 C24 117.86(12) . . ?
C27 C26 C25 119.37(14) . . ?
C27 C26 H26 120.3 . . ?
C25 C26 H26 120.3 . . ?
C28 C27 C26 120.41(12) . . ?
C28 C27 H27 119.8 . . ?
C26 C27 H27 119.8 . . ?
C27 C28 C29 119.98(10) . . ?
C27 C28 H28 120.0 . . ?
C29 C28 H28 120.0 . . ?
C30 C29 C28 120.03(14) . . ?
C30 C29 H29 120.0 . . ?
C28 C29 H29 120.0 . . ?
C25 C30 C29 119.94(12) . . ?
C25 C30 H30 120.0 . . ?
C29 C30 H30 120.0 . . ?
N7 C31 C32 124.94(10) . . ?
N7 C31 C33 113.99(13) . . ?
C32 C31 C33 120.93(11) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
N8 C33 C34 122.63(11) . . ?
N8 C33 C31 116.36(10) . . ?
C34 C33 C31 120.96(13) . . ?
C35 C34 C33 118.29(14) . . ?
C35 C34 H34 120.9 . . ?
C33 C34 H34 120.9 . . ?
C36 C35 C34 119.46(11) . . ?
C36 C35 H35 120.3 . . ?
C34 C35 H35 120.3 . . ?
C35 C36 C37 118.75(11) . . ?
C35 C36 H36 120.6 . . ?
C37 C36 H36 120.6 . . ?
N8 C37 C36 122.00(13) . . ?
N8 C37 C38 115.83(10) . . ?
C36 C37 C38 122.15(10) . . ?
N9 C38 C37 114.45(10) . . ?
N9 C38 C39 122.54(13) . . ?
C37 C38 C39 122.98(9) . . ?
C38 C39 H39A 109.5 . . ?
C38 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C38 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
O4 C40 N10 120.04(13) . . ?
O4 C40 C41 123.30(10) . . ?
N10 C40 C41 116.64(10) . . ?
C46 C41 C42 119.39(14) . . ?
C46 C41 C40 122.06(10) . . ?
C42 C41 C40 118.50(11) . . ?
C43 C42 C41 119.84(12) . . ?
C43 C42 H42 120.1 . . ?
C41 C42 H42 120.1 . . ?
C42 C43 C44 120.29(12) . . ?
C42 C43 H43 119.9 . . ?
C44 C43 H43 119.9 . . ?
C45 C44 C43 120.20(16) . . ?
C45 C44 H44 119.9 . . ?
C43 C44 H44 119.9 . . ?
C46 C45 C44 119.93(14) . . ?
C46 C45 H45 120.0 . . ?
C44 C45 H45 120.0 . . ?
C45 C46 C41 120.28(12) . . ?
C45 C46 H46 119.9 . . ?
C41 C46 H46 119.9 . . ?
O11 C47 C48 107.67(12) . . ?
O11 C47 H47A 110.2 . . ?
C48 C47 H47A 110.2 . . ?
O11 C47 H47B 110.2 . . ?
C48 C47 H47B 110.2 . . ?
H47A C47 H47B 108.5 . . ?
C47 C48 H48A 109.5 . . ?
C47 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C47 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C1 N1 N2 108.62(8) . . ?
C8 N2 N1 116.70(8) . . ?
C8 N2 Dy 126.88(7) . . ?
N1 N2 Dy 116.38(6) . . ?
C10 N3 C14 118.53(10) . . ?
C10 N3 Dy 119.23(8) . . ?
C14 N3 Dy 122.21(6) . . ?
C15 N4 N5 117.51(9) . . ?
C15 N4 Dy 128.30(6) . . ?
N5 N4 Dy 114.17(7) . . ?
C17 N5 N4 113.52(9) . . ?
C17 N5 H101 124.1(13) . . ?
N4 N5 H101 119.6(13) . . ?
C24 N6 N7 113.75(11) . . ?
C24 N6 H102 125.5(12) . . ?
N7 N6 H102 117.3(12) . . ?
C31 N7 N6 116.92(12) . . ?
C31 N7 Dy 128.64(8) . . ?
N6 N7 Dy 114.29(8) . . ?
C33 N8 C37 118.74(10) . . ?
C33 N8 Dy 120.41(6) . . ?
C37 N8 Dy 120.80(10) . . ?
C38 N9 N10 117.41(10) . . ?
C38 N9 Dy 128.90(10) . . ?
N10 N9 Dy 113.66(6) . . ?
C40 N10 N9 114.76(10) . . ?
C40 N10 H100 122.6(14) . . ?
N9 N10 H100 120.2(14) . . ?
O5 N11 O6 121.20(10) . . ?
O5 N11 O7 120.68(11) . . ?
O6 N11 O7 118.12(10) . . ?
O10 N12 O9 121.52(12) . . ?
O10 N12 O8 119.37(11) . . ?
O9 N12 O8 119.11(13) . . ?
C1 O1 Dy 119.48(6) . . ?
C17 O2 Dy 118.12(9) . . ?
C24 O3 Dy 119.86(6) . . ?
C40 O4 Dy 116.33(8) . . ?
C47 O11 H11A 109.5 . . ?
H12A O12 H12B 104.9(3) . . ?
H13A O13 H13B 105.0(3) . . ?
H14A O14 H14B 105.0(3) . . ?
H15A O15 H15B 104.8(3) . . ?
O1 Dy O3 121.38(3) . . ?
O1 Dy O4 82.39(4) . . ?
O3 Dy O4 128.52(3) . . ?
O1 Dy N2 62.67(3) . . ?
O3 Dy N2 74.12(3) . . ?
O4 Dy N2 80.67(4) . . ?
O1 Dy O2 130.85(3) . . ?
O3 Dy O2 78.46(3) . . ?
O4 Dy O2 122.23(3) . . ?
N2 Dy O2 151.95(3) . . ?
O1 Dy N9 84.65(3) . . ?
O3 Dy N9 151.38(3) . . ?
O4 Dy N9 61.41(3) . . ?
N2 Dy N9 133.12(3) . . ?
O2 Dy N9 74.91(3) . . ?
O1 Dy N7 76.45(4) . . ?
O3 Dy N7 62.21(3) . . ?
O4 Dy N7 158.42(3) . . ?
N2 Dy N7 85.86(3) . . ?
O2 Dy N7 76.13(3) . . ?
N9 Dy N7 119.83(3) . . ?
O1 Dy N4 153.79(3) . . ?
O3 Dy N4 82.47(3) . . ?
O4 Dy N4 73.35(4) . . ?
N2 Dy N4 121.14(3) . . ?
O2 Dy N4 59.75(4) . . ?
N9 Dy N4 75.23(3) . . ?
N7 Dy N4 128.23(4) . . ?
O1 Dy N3 117.84(3) . . ?
O3 Dy N3 64.69(4) . . ?
O4 Dy N3 63.85(4) . . ?
N2 Dy N3 61.53(3) . . ?
O2 Dy N3 111.30(3) . . ?
N9 Dy N3 116.15(4) . . ?
N7 Dy N3 123.29(4) . . ?
N4 Dy N3 59.62(3) . . ?
O1 Dy N8 67.84(3) . . ?
O3 Dy N8 115.95(4) . . ?
O4 Dy N8 115.33(4) . . ?
N2 Dy N8 125.02(3) . . ?
O2 Dy N8 63.19(3) . . ?
N9 Dy N8 59.84(4) . . ?
N7 Dy N8 60.09(4) . . ?
N4 Dy N8 113.82(3) . . ?
N3 Dy N8 173.44(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 C2 C3 -14.12(19) . . . . ?
N1 C1 C2 C3 162.37(13) . . . . ?
O1 C1 C2 C7 166.82(13) . . . . ?
N1 C1 C2 C7 -16.7(2) . . . . ?
C7 C2 C3 C4 1.4(2) . . . . ?
C1 C2 C3 C4 -177.67(13) . . . . ?
C2 C3 C4 C5 -0.9(2) . . . . ?
C3 C4 C5 C6 -0.7(2) . . . . ?
C4 C5 C6 C7 1.8(2) . . . . ?
C5 C6 C7 C2 -1.3(2) . . . . ?
C3 C2 C7 C6 -0.3(2) . . . . ?
C1 C2 C7 C6 178.75(14) . . . . ?
N2 C8 C10 N3 3.74(17) . . . . ?
C9 C8 C10 N3 -172.89(11) . . . . ?
N2 C8 C10 C11 -177.47(12) . . . . ?
C9 C8 C10 C11 5.90(19) . . . . ?
N3 C10 C11 C12 2.8(2) . . . . ?
C8 C10 C11 C12 -175.90(13) . . . . ?
C10 C11 C12 C13 0.2(2) . . . . ?
C11 C12 C13 C14 -2.9(2) . . . . ?
C12 C13 C14 N3 2.9(2) . . . . ?
C12 C13 C14 C15 -174.86(12) . . . . ?
N3 C14 C15 N4 -1.73(16) . . . . ?
C13 C14 C15 N4 176.19(12) . . . . ?
N3 C14 C15 C16 -179.45(12) . . . . ?
C13 C14 C15 C16 -1.52(19) . . . . ?
O2 C17 C18 C23 26.04(15) . . . . ?
N5 C17 C18 C23 -155.98(10) . . . . ?
O2 C17 C18 C19 -151.51(11) . . . . ?
N5 C17 C18 C19 26.46(16) . . . . ?
C23 C18 C19 C20 -1.07(19) . . . . ?
C17 C18 C19 C20 176.44(12) . . . . ?
C18 C19 C20 C21 1.3(2) . . . . ?
C19 C20 C21 C22 -0.4(2) . . . . ?
C20 C21 C22 C23 -0.8(2) . . . . ?
C21 C22 C23 C18 0.99(19) . . . . ?
C19 C18 C23 C22 -0.08(19) . . . . ?
C17 C18 C23 C22 -177.66(11) . . . . ?
O3 C24 C25 C30 -152.12(10) . . . . ?
N6 C24 C25 C30 27.33(13) . . . . ?
O3 C24 C25 C26 26.91(14) . . . . ?
N6 C24 C25 C26 -153.63(10) . . . . ?
C30 C25 C26 C27 -1.03(14) . . . . ?
C24 C25 C26 C27 179.92(9) . . . . ?
C25 C26 C27 C28 0.24(15) . . . . ?
C26 C27 C28 C29 0.55(16) . . . . ?
C27 C28 C29 C30 -0.57(15) . . . . ?
C26 C25 C30 C29 1.02(14) . . . . ?
C24 C25 C30 C29 -179.97(9) . . . . ?
C28 C29 C30 C25 -0.22(15) . . . . ?
N7 C31 C33 N8 6.58(12) . . . . ?
C32 C31 C33 N8 -169.31(9) . . . . ?
N7 C31 C33 C34 -176.08(9) . . . . ?
C32 C31 C33 C34 8.03(14) . . . . ?
N8 C33 C34 C35 1.61(15) . . . . ?
C31 C33 C34 C35 -175.57(9) . . . . ?
C33 C34 C35 C36 1.67(16) . . . . ?
C34 C35 C36 C37 -3.06(15) . . . . ?
C35 C36 C37 N8 1.36(15) . . . . ?
C35 C36 C37 C38 -177.17(9) . . . . ?
N8 C37 C38 N9 -4.79(12) . . . . ?
C36 C37 C38 N9 173.83(9) . . . . ?
N8 C37 C38 C39 177.07(9) . . . . ?
C36 C37 C38 C39 -4.32(14) . . . . ?
O4 C40 C41 C46 -155.52(10) . . . . ?
N10 C40 C41 C46 26.21(14) . . . . ?
O4 C40 C41 C42 27.03(14) . . . . ?
N10 C40 C41 C42 -151.24(9) . . . . ?
C46 C41 C42 C43 -2.85(16) . . . . ?
C40 C41 C42 C43 174.67(10) . . . . ?
C41 C42 C43 C44 2.58(18) . . . . ?
C42 C43 C44 C45 -0.4(2) . . . . ?
C43 C44 C45 C46 -1.6(2) . . . . ?
C44 C45 C46 C41 1.3(2) . . . . ?
C42 C41 C46 C45 0.92(17) . . . . ?
C40 C41 C46 C45 -176.51(11) . . . . ?
O1 C1 N1 N2 -0.12(18) . . . . ?
C2 C1 N1 N2 -176.38(11) . . . . ?
C10 C8 N2 N1 -176.97(11) . . . . ?
C9 C8 N2 N1 -0.56(19) . . . . ?
C10 C8 N2 Dy 0.49(16) . . . . ?
C9 C8 N2 Dy 176.90(10) . . . . ?
C1 N1 N2 C8 156.62(12) . . . . ?
C1 N1 N2 Dy -21.12(13) . . . . ?
C11 C10 N3 C14 -2.88(18) . . . . ?
C8 C10 N3 C14 175.90(11) . . . . ?
C11 C10 N3 Dy 175.29(10) . . . . ?
C8 C10 N3 Dy -5.93(14) . . . . ?
C13 C14 N3 C10 -0.03(18) . . . . ?
C15 C14 N3 C10 177.85(11) . . . . ?
C13 C14 N3 Dy -178.15(9) . . . . ?
C15 C14 N3 Dy -0.26(14) . . . . ?
C14 C15 N4 N5 -174.82(10) . . . . ?
C16 C15 N4 N5 2.78(19) . . . . ?
C14 C15 N4 Dy 3.26(15) . . . . ?
C16 C15 N4 Dy -179.15(9) . . . . ?
O2 C17 N5 N4 0.36(13) . . . . ?
C18 C17 N5 N4 -177.65(8) . . . . ?
C15 N4 N5 C17 149.53(11) . . . . ?
Dy N4 N5 C17 -28.81(10) . . . . ?
O3 C24 N6 N7 -2.01(14) . . . . ?
C25 C24 N6 N7 178.53(9) . . . . ?
C32 C31 N7 N6 -0.99(14) . . . . ?
C33 C31 N7 N6 -176.69(8) . . . . ?
C32 C31 N7 Dy 174.28(8) . . . . ?
C33 C31 N7 Dy -1.42(12) . . . . ?
C24 N6 N7 C31 155.58(9) . . . . ?
C24 N6 N7 Dy -20.38(10) . . . . ?
C34 C33 N8 C37 -3.34(14) . . . . ?
C31 C33 N8 C37 173.96(8) . . . . ?
C34 C33 N8 Dy 174.10(7) . . . . ?
C31 C33 N8 Dy -8.61(11) . . . . ?
C36 C37 N8 C33 1.83(13) . . . . ?
C38 C37 N8 C33 -179.55(8) . . . . ?
C36 C37 N8 Dy -175.59(7) . . . . ?
C38 C37 N8 Dy 3.03(10) . . . . ?
C37 C38 N9 N10 -177.48(8) . . . . ?
C39 C38 N9 N10 0.68(13) . . . . ?
C37 C38 N9 Dy 4.85(11) . . . . ?
C39 C38 N9 Dy -177.00(7) . . . . ?
O4 C40 N10 N9 -3.60(12) . . . . ?
C41 C40 N10 N9 174.73(8) . . . . ?
C38 N9 N10 C40 156.49(8) . . . . ?
Dy N9 N10 C40 -25.48(9) . . . . ?
N1 C1 O1 Dy 23.83(18) . . . . ?
C2 C1 O1 Dy -159.99(9) . . . . ?
N5 C17 O2 Dy 30.12(11) . . . . ?
C18 C17 O2 Dy -151.95(7) . . . . ?
N6 C24 O3 Dy 25.86(13) . . . . ?
C25 C24 O3 Dy -154.71(7) . . . . ?
N10 C40 O4 Dy 32.17(11) . . . . ?
C41 C40 O4 Dy -146.05(8) . . . . ?
C1 O1 Dy O3 23.92(11) . . . . ?
C1 O1 Dy O4 -106.95(10) . . . . ?
C1 O1 Dy N2 -23.55(10) . . . . ?
C1 O1 Dy O2 126.49(9) . . . . ?
C1 O1 Dy N9 -168.76(10) . . . . ?
C1 O1 Dy N7 68.80(10) . . . . ?
C1 O1 Dy N4 -129.11(10) . . . . ?
C1 O1 Dy N3 -51.95(11) . . . . ?
C1 O1 Dy N8 131.68(11) . . . . ?
C24 O3 Dy O1 25.57(9) . . . . ?
C24 O3 Dy O4 132.25(8) . . . . ?
C24 O3 Dy N2 68.46(8) . . . . ?
C24 O3 Dy O2 -105.53(9) . . . . ?
C24 O3 Dy N9 -127.27(9) . . . . ?
C24 O3 Dy N7 -25.27(8) . . . . ?
C24 O3 Dy N4 -166.09(9) . . . . ?
C24 O3 Dy N3 134.03(9) . . . . ?
C24 O3 Dy N8 -53.22(9) . . . . ?
C40 O4 Dy O1 -119.38(7) . . . . ?
C40 O4 Dy O3 116.22(7) . . . . ?
C40 O4 Dy N2 177.20(7) . . . . ?
C40 O4 Dy O2 14.71(8) . . . . ?
C40 O4 Dy N9 -31.34(7) . . . . ?
C40 O4 Dy N7 -130.68(8) . . . . ?
C40 O4 Dy N4 50.61(7) . . . . ?
C40 O4 Dy N3 114.43(7) . . . . ?
C40 O4 Dy N8 -58.34(7) . . . . ?
C8 N2 Dy O1 -153.86(12) . . . . ?
N1 N2 Dy O1 23.61(8) . . . . ?
C8 N2 Dy O3 67.00(11) . . . . ?
N1 N2 Dy O3 -115.53(9) . . . . ?
C8 N2 Dy O4 -67.66(11) . . . . ?
N1 N2 Dy O4 109.81(9) . . . . ?
C8 N2 Dy O2 79.58(14) . . . . ?
N1 N2 Dy O2 -102.95(9) . . . . ?
C8 N2 Dy N9 -102.76(10) . . . . ?
N1 N2 Dy N9 74.71(10) . . . . ?
C8 N2 Dy N7 129.26(11) . . . . ?
N1 N2 Dy N7 -53.27(9) . . . . ?
C8 N2 Dy N4 -3.67(12) . . . . ?
N1 N2 Dy N4 173.80(8) . . . . ?
C8 N2 Dy N3 -2.44(10) . . . . ?
N1 N2 Dy N3 175.03(10) . . . . ?
C8 N2 Dy N8 177.86(10) . . . . ?
N1 N2 Dy N8 -4.67(10) . . . . ?
C17 O2 Dy O1 119.11(7) . . . . ?
C17 O2 Dy O3 -119.15(7) . . . . ?
C17 O2 Dy O4 9.36(7) . . . . ?
C17 O2 Dy N2 -131.50(8) . . . . ?
C17 O2 Dy N9 50.26(7) . . . . ?
C17 O2 Dy N7 176.93(7) . . . . ?
C17 O2 Dy N4 -31.20(7) . . . . ?
C17 O2 Dy N3 -62.37(8) . . . . ?
C17 O2 Dy N8 113.72(8) . . . . ?
C38 N9 Dy O1 -69.91(8) . . . . ?
N10 N9 Dy O1 112.34(7) . . . . ?
C38 N9 Dy O3 87.04(10) . . . . ?
N10 N9 Dy O3 -90.71(9) . . . . ?
C38 N9 Dy O4 -154.15(9) . . . . ?
N10 N9 Dy O4 28.10(6) . . . . ?
C38 N9 Dy N2 -113.89(8) . . . . ?
N10 N9 Dy N2 68.36(7) . . . . ?
C38 N9 Dy O2 64.97(8) . . . . ?
N10 N9 Dy O2 -112.78(6) . . . . ?
C38 N9 Dy N7 1.12(9) . . . . ?
N10 N9 Dy N7 -176.63(5) . . . . ?
C38 N9 Dy N4 127.03(9) . . . . ?
N10 N9 Dy N4 -50.72(6) . . . . ?
C38 N9 Dy N3 171.63(7) . . . . ?
N10 N9 Dy N3 -6.12(7) . . . . ?
C38 N9 Dy N8 -2.48(7) . . . . ?
N10 N9 Dy N8 179.77(7) . . . . ?
C31 N7 Dy O1 70.07(8) . . . . ?
N6 N7 Dy O1 -114.54(7) . . . . ?
C31 N7 Dy O3 -152.84(9) . . . . ?
N6 N7 Dy O3 22.55(6) . . . . ?
C31 N7 Dy O4 81.61(11) . . . . ?
N6 N7 Dy O4 -103.01(8) . . . . ?
C31 N7 Dy N2 132.94(8) . . . . ?
N6 N7 Dy N2 -51.68(6) . . . . ?
C31 N7 Dy O2 -68.73(8) . . . . ?
N6 N7 Dy O2 106.65(6) . . . . ?
C31 N7 Dy N9 -5.52(9) . . . . ?
N6 N7 Dy N9 169.86(6) . . . . ?
C31 N7 Dy N4 -99.97(8) . . . . ?
N6 N7 Dy N4 75.41(7) . . . . ?
C31 N7 Dy N3 -175.32(7) . . . . ?
N6 N7 Dy N3 0.06(7) . . . . ?
C31 N7 Dy N8 -1.93(8) . . . . ?
N6 N7 Dy N8 173.45(7) . . . . ?
C15 N4 Dy O1 89.51(11) . . . . ?
N5 N4 Dy O1 -92.36(10) . . . . ?
C15 N4 Dy O3 -67.50(11) . . . . ?
N5 N4 Dy O3 110.62(8) . . . . ?
C15 N4 Dy O4 66.54(11) . . . . ?
N5 N4 Dy O4 -115.33(8) . . . . ?
C15 N4 Dy N2 -1.23(12) . . . . ?
N5 N4 Dy N2 176.90(7) . . . . ?
C15 N4 Dy O2 -148.50(12) . . . . ?
N5 N4 Dy O2 29.63(7) . . . . ?
C15 N4 Dy N9 130.59(11) . . . . ?
N5 N4 Dy N9 -51.29(8) . . . . ?
C15 N4 Dy N7 -112.85(11) . . . . ?
N5 N4 Dy N7 65.27(9) . . . . ?
C15 N4 Dy N3 -2.49(10) . . . . ?
N5 N4 Dy N3 175.64(9) . . . . ?
C15 N4 Dy N8 177.40(10) . . . . ?
N5 N4 Dy N8 -4.47(9) . . . . ?
C10 N3 Dy O1 33.04(10) . . . . ?
C14 N3 Dy O1 -148.86(9) . . . . ?
C10 N3 Dy O3 -80.64(9) . . . . ?
C14 N3 Dy O3 97.46(9) . . . . ?
C10 N3 Dy O4 97.81(9) . . . . ?
C14 N3 Dy O4 -84.09(10) . . . . ?
C10 N3 Dy N2 4.32(8) . . . . ?
C14 N3 Dy N2 -177.58(10) . . . . ?
C10 N3 Dy O2 -145.69(8) . . . . ?
C14 N3 Dy O2 32.41(10) . . . . ?
C10 N3 Dy N9 131.19(9) . . . . ?
C14 N3 Dy N9 -50.71(10) . . . . ?
C10 N3 Dy N7 -58.67(9) . . . . ?
C14 N3 Dy N7 119.43(9) . . . . ?
C10 N3 Dy N4 -176.91(10) . . . . ?
C14 N3 Dy N4 1.19(9) . . . . ?
C10 N3 Dy N8 -177.8(2) . . . . ?
C14 N3 Dy N8 0.3(3) . . . . ?
C33 N8 Dy O1 -81.11(7) . . . . ?
C37 N8 Dy O1 96.27(7) . . . . ?
C33 N8 Dy O3 34.17(7) . . . . ?
C37 N8 Dy O3 -148.45(6) . . . . ?
C33 N8 Dy O4 -150.56(6) . . . . ?
C37 N8 Dy O4 26.82(7) . . . . ?
C33 N8 Dy N2 -54.08(8) . . . . ?
C37 N8 Dy N2 123.30(7) . . . . ?
C33 N8 Dy O2 94.49(7) . . . . ?
C37 N8 Dy O2 -88.13(7) . . . . ?
C33 N8 Dy N9 -178.01(8) . . . . ?
C37 N8 Dy N9 -0.63(6) . . . . ?
C33 N8 Dy N7 5.59(6) . . . . ?
C37 N8 Dy N7 -177.03(8) . . . . ?
C33 N8 Dy N4 127.35(7) . . . . ?
C37 N8 Dy N4 -55.27(8) . . . . ?
C33 N8 Dy N3 128.2(3) . . . . ?
C37 N8 Dy N3 -54.4(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.581
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.957
_refine_diff_density_max         1.584
_refine_diff_density_min         -1.675
_refine_diff_density_rms         0.085
_database_code_depnum_ccdc_archive 'CCDC 870723'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
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#  data retrieval see:
#                         www.ccdc.cam.ac.uk
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#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_1



_database_code_CSD               'CCDC 870724'


_audit_creation_method           SHELXL-97
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_formula_moiety         '(C46 H42 Dy N10 O4), 3(N O3), 2.5(H2 O) '
_chemical_formula_sum            'C46 H47 Dy N13 O15.50'
_chemical_melting_point          ?

_exptl_crystal_description       bloc
_exptl_crystal_colour            'very pale yellow'

_diffrn_ambient_temperature      100(1)
_chemical_formula_weight         1192.47

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0031 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0109 0.0061 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1890 4.4100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_symmetry_int_tables_number      2
_chemical_absolute_configuration .

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.9478(9)
_cell_length_b                   12.4520(9)
_cell_length_c                   18.3958(12)
_cell_angle_alpha                95.818(2)
_cell_angle_beta                 102.994(2)
_cell_angle_gamma                108.904(2)
_cell_volume                     2477.4(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(1)
_cell_measurement_reflns_used    9010
_cell_measurement_theta_min      2.27
_cell_measurement_theta_max      35.83
_exptl_crystal_size_min          0.05
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_max          0.09
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.599
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1208
_exptl_absorpt_coefficient_mu    1.592
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_correction_T_min  0.7953
_exptl_absorpt_correction_T_max  0.9288
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
;
 ?
;
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_type              'kappa X8 APEX II Bruker ICMMO'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            40295
_diffrn_reflns_av_R_equivalents  0.0389
_diffrn_reflns_av_sigmaI/netI    0.0536
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_theta_min         1.76
_diffrn_reflns_theta_max         36.34
_reflns_number_total             18317
_reflns_number_gt                15696
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0783P)²+7.6996P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.0016(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         18317
_refine_ls_number_parameters     732
_refine_ls_number_restraints     49
_refine_ls_R_factor_all          0.0689
_refine_ls_R_factor_gt           0.0569
_refine_ls_wR_factor_ref         0.1558
_refine_ls_wR_factor_gt          0.1473
_refine_ls_goodness_of_fit_ref   1.091
_refine_ls_restrained_S_all      1.089
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.4330(3) 0.1342(3) 0.5726(2) 0.0177(6) Uani 1 1 d . . .
C2 C 0.3577(3) 0.0321(3) 0.5120(2) 0.0188(6) Uani 1 1 d . . .
C3 C 0.2710(4) -0.0594(4) 0.5302(2) 0.0249(7) Uani 1 1 d . . .
H3 H 0.2597 -0.0541 0.5787 0.030 Uiso 1 1 calc R . .
C4 C 0.2019(4) -0.1583(4) 0.4755(3) 0.0274(8) Uani 1 1 d . . .
H4 H 0.1438 -0.2194 0.4872 0.033 Uiso 1 1 calc R . .
C5 C 0.2193(4) -0.1660(4) 0.4035(3) 0.0278(8) Uani 1 1 d . . .
H5 H 0.1741 -0.2330 0.3673 0.033 Uiso 1 1 calc R . .
C6 C 0.3035(4) -0.0746(4) 0.3851(2) 0.0258(8) Uani 1 1 d . . .
H6 H 0.3132 -0.0796 0.3362 0.031 Uiso 1 1 calc R . .
C7 C 0.3735(4) 0.0244(3) 0.4393(2) 0.0219(7) Uani 1 1 d . . .
H7 H 0.4309 0.0854 0.4271 0.026 Uiso 1 1 calc R . .
C8 C 0.6250(3) 0.4167(3) 0.5926(2) 0.0201(6) Uani 1 1 d . . .
C9 C 0.6284(4) 0.4338(4) 0.5139(3) 0.0311(9) Uani 1 1 d . . .
H9A H 0.6527 0.5147 0.5124 0.047 Uiso 1 1 calc R . .
H9B H 0.5483 0.3934 0.4795 0.047 Uiso 1 1 calc R . .
H9C H 0.6865 0.4041 0.4993 0.047 Uiso 1 1 calc R . .
C10 C 0.7163(3) 0.5019(3) 0.6595(2) 0.0203(7) Uani 1 1 d . . .
C11 C 0.8175(4) 0.5887(4) 0.6499(3) 0.0273(8) Uani 1 1 d . . .
H11 H 0.8259 0.5981 0.6017 0.033 Uiso 1 1 calc R . .
C12 C 0.9049(4) 0.6603(4) 0.7143(3) 0.0337(10) Uani 1 1 d . . .
H12 H 0.9727 0.7199 0.7100 0.040 Uiso 1 1 calc R . .
C13 C 0.8904(4) 0.6425(4) 0.7843(3) 0.0306(9) Uani 1 1 d . . .
H13 H 0.9487 0.6897 0.8281 0.037 Uiso 1 1 calc R . .
C14 C 0.7875(4) 0.5531(3) 0.7896(2) 0.0219(7) Uani 1 1 d . . .
C15 C 0.7675(4) 0.5291(4) 0.8639(2) 0.0245(7) Uani 1 1 d . . .
C16 C 0.8526(5) 0.6062(5) 0.9370(3) 0.0367(11) Uani 1 1 d . . .
H16A H 0.8143 0.5913 0.9773 0.055 Uiso 1 1 calc R . .
H16B H 0.8700 0.6855 0.9320 0.055 Uiso 1 1 calc R . .
H16C H 0.9279 0.5910 0.9482 0.055 Uiso 1 1 calc R . .
C17 C 0.5246(3) 0.3493(3) 0.9157(2) 0.0177(6) Uani 1 1 d . . .
C18 C 0.4835(3) 0.3264(3) 0.9843(2) 0.0188(6) Uani 1 1 d . . .
C19 C 0.5444(4) 0.3999(4) 1.0546(2) 0.0283(8) Uani 1 1 d . . .
H19 H 0.6153 0.4633 1.0598 0.034 Uiso 1 1 calc R . .
C20 C 0.4987(5) 0.3780(4) 1.1168(3) 0.0349(10) Uani 1 1 d . . .
H20 H 0.5393 0.4269 1.1637 0.042 Uiso 1 1 calc R . .
C21 C 0.3932(5) 0.2838(4) 1.1095(3) 0.0304(9) Uani 1 1 d . . .
H21 H 0.3633 0.2697 1.1514 0.036 Uiso 1 1 calc R . .
C22 C 0.3319(4) 0.2103(4) 1.0395(3) 0.0247(7) Uani 1 1 d . . .
H22 H 0.2609 0.1472 1.0346 0.030 Uiso 1 1 calc R . .
C23 C 0.3768(3) 0.2312(3) 0.9770(2) 0.0206(6) Uani 1 1 d . . .
H23 H 0.3359 0.1820 0.9302 0.025 Uiso 1 1 calc R . .
C24 C 0.3550(3) 0.4380(3) 0.6778(2) 0.0166(6) Uani 1 1 d . . .
C25 C 0.3210(3) 0.5400(3) 0.6624(2) 0.0190(6) Uani 1 1 d . . .
C26 C 0.4151(4) 0.6476(3) 0.6833(2) 0.0227(7) Uani 1 1 d . . .
H26 H 0.4965 0.6533 0.7009 0.027 Uiso 1 1 calc R . .
C27 C 0.3865(4) 0.7469(4) 0.6776(3) 0.0284(8) Uani 1 1 d . . .
H27 H 0.4488 0.8193 0.6918 0.034 Uiso 1 1 calc R . .
C28 C 0.2646(5) 0.7378(4) 0.6506(3) 0.0334(10) Uani 1 1 d . . .
H28 H 0.2457 0.8043 0.6477 0.040 Uiso 1 1 calc R . .
C29 C 0.1718(5) 0.6311(4) 0.6282(3) 0.0337(10) Uani 1 1 d . . .
H29 H 0.0910 0.6260 0.6086 0.040 Uiso 1 1 calc R . .
C30 C 0.1978(4) 0.5306(4) 0.6346(3) 0.0262(8) Uani 1 1 d . . .
H30 H 0.1349 0.4585 0.6208 0.031 Uiso 1 1 calc R . .
C31 C 0.2066(3) 0.1548(3) 0.6817(2) 0.0197(6) Uani 1 1 d . . .
C32 C 0.0726(3) 0.1283(4) 0.6453(3) 0.0263(8) Uani 1 1 d . . .
H32A H 0.0626 0.1918 0.6225 0.039 Uiso 1 1 calc R . .
H32B H 0.0284 0.1167 0.6832 0.039 Uiso 1 1 calc R . .
H32C H 0.0411 0.0595 0.6070 0.039 Uiso 1 1 calc R . .
C33 C 0.2425(3) 0.0764(3) 0.7300(2) 0.0199(6) Uani 1 1 d . . .
C34 C 0.1528(4) -0.0146(4) 0.7462(3) 0.0265(8) Uani 1 1 d . . .
H34 H 0.0698 -0.0328 0.7226 0.032 Uiso 1 1 calc R . .
C35 C 0.1912(4) -0.0777(4) 0.7987(3) 0.0287(9) Uani 1 1 d . . .
H35 H 0.1337 -0.1368 0.8124 0.034 Uiso 1 1 calc R . .
C36 C 0.3149(4) -0.0514(4) 0.8300(3) 0.0256(8) Uani 1 1 d . . .
H36 H 0.3423 -0.0926 0.8649 0.031 Uiso 1 1 calc R . .
C37 C 0.3984(3) 0.0380(3) 0.8086(2) 0.0210(7) Uani 1 1 d . . .
C38 C 0.5329(4) 0.0655(4) 0.8371(2) 0.0234(7) Uani 1 1 d . . .
C39 C 0.5807(5) -0.0146(5) 0.8779(4) 0.0413(13) Uani 1 1 d . . .
H39A H 0.5926 0.0071 0.9315 0.062 Uiso 1 1 calc R . .
H39B H 0.6577 -0.0104 0.8685 0.062 Uiso 1 1 calc R . .
H39C H 0.5227 -0.0922 0.8601 0.062 Uiso 1 1 calc R . .
C40 C 0.7860(3) 0.2502(3) 0.7967(2) 0.0201(6) Uani 1 1 d . . .
C41 C 0.9201(3) 0.2747(4) 0.8111(2) 0.0228(7) Uani 1 1 d . . .
C42 C 0.9908(4) 0.3717(4) 0.7894(3) 0.0298(9) Uani 1 1 d . . .
H42 H 0.9547 0.4204 0.7670 0.036 Uiso 1 1 calc R . .
C43 C 1.1171(4) 0.3954(5) 0.8014(3) 0.0354(10) Uani 1 1 d . . .
H43 H 1.1657 0.4613 0.7881 0.043 Uiso 1 1 calc R . .
C44 C 1.1697(4) 0.3212(5) 0.8330(3) 0.0363(11) Uani 1 1 d . . .
H44 H 1.2533 0.3365 0.8399 0.044 Uiso 1 1 calc R . .
C45 C 1.0985(4) 0.2239(5) 0.8546(3) 0.0375(11) Uani 1 1 d . . .
H45 H 1.1348 0.1749 0.8765 0.045 Uiso 1 1 calc R . .
C46 C 0.9726(4) 0.1994(4) 0.8434(3) 0.0315(9) Uani 1 1 d . . .
H46 H 0.9244 0.1340 0.8572 0.038 Uiso 1 1 calc R . .
N1 N 0.4749(3) 0.2365(3) 0.55120(19) 0.0193(6) Uani 1 1 d . . .
H103 H 0.4552 0.2449 0.5048 0.023 Uiso 1 1 calc R . .
N2 N 0.5520(3) 0.3271(3) 0.60948(18) 0.0181(5) Uani 1 1 d . . .
N3 N 0.7009(3) 0.4834(3) 0.72758(19) 0.0168(5) Uani 1 1 d . . .
N4 N 0.6733(3) 0.4385(3) 0.85904(19) 0.0202(6) Uani 1 1 d . . .
N5 N 0.6437(3) 0.4132(3) 0.92590(19) 0.0220(6) Uani 1 1 d . . .
H101 H 0.6968 0.4364 0.9697 0.026 Uiso 1 1 calc R . .
N6 N 0.2701(3) 0.3321(3) 0.6470(2) 0.0202(6) Uani 1 1 d . . .
H102 H 0.2056 0.3199 0.6105 0.024 Uiso 1 1 calc R . .
N7 N 0.2969(3) 0.2445(3) 0.67990(19) 0.0173(5) Uani 1 1 d . . .
N8 N 0.3637(3) 0.1038(3) 0.76041(17) 0.0151(5) Uani 1 1 d . . .
N9 N 0.6001(3) 0.1580(3) 0.8189(2) 0.0222(6) Uani 1 1 d . . .
N10 N 0.7265(3) 0.1834(4) 0.8397(2) 0.0274(7) Uani 1 1 d . . .
H100 H 0.7633 0.1589 0.8764 0.033 Uiso 1 1 calc R . .
N11 N 0.9285(3) 0.7838(3) 0.5326(2) 0.0264(7) Uani 1 1 d . . .
N12 N 0.2060(4) 0.1186(4) 0.2334(3) 0.0366(9) Uani 1 1 d . . .
O1 O 0.4590(2) 0.1262(2) 0.64108(16) 0.0184(5) Uani 1 1 d . . .
O2 O 0.4521(2) 0.3130(2) 0.85053(15) 0.0183(5) Uani 1 1 d . . .
O3 O 0.4564(2) 0.4497(2) 0.72120(16) 0.0183(5) Uani 1 1 d . . .
O4 O 0.7287(2) 0.2856(2) 0.74537(16) 0.0178(5) Uani 1 1 d . . .
O5 O 0.8580(3) 0.8393(3) 0.5166(2) 0.0361(8) Uani 1 1 d . . .
O6 O 0.9113(3) 0.6930(3) 0.4868(2) 0.0305(7) Uani 1 1 d . . .
O7 O 1.0141(3) 0.8166(3) 0.5918(2) 0.0343(7) Uani 1 1 d . . .
O8 O 0.1293(4) 0.0945(5) 0.2699(3) 0.0594(14) Uani 1 1 d . . .
O9 O 0.3173(4) 0.1696(4) 0.2681(2) 0.0510(12) Uani 1 1 d . . .
O10 O 0.1752(4) 0.0941(5) 0.1626(3) 0.0685(17) Uani 1 1 d . . .
O16 O 0.6629(3) 0.7391(3) 0.58240(19) 0.030 Uani 1 1 d D . .
H16E H 0.665(5) 0.761(5) 0.6340(16) 0.039 Uiso 1 1 d D . .
H16D H 0.735(6) 0.782(6) 0.574(3) 0.039 Uiso 1 1 d D . .
O17 O 0.9459(6) 0.0253(5) 0.0559(3) 0.078 Uani 1 1 d D . .
H17A H 0.978(15) 0.032(17) 0.012(6) 0.101 Uiso 0.50 1 d PD A 1
H17B H 1.018(10) 0.043(19) 0.098(7) 0.101 Uiso 0.50 1 d PD B 1
H17C H 0.920(15) 0.087(7) 0.039(5) 0.101 Uiso 0.50 1 d PD C 2
H17D H 1.029(7) 0.065(11) 0.086(11) 0.101 Uiso 0.50 1 d PD D 2
Dy Dy 0.527191(13) 0.292823(13) 0.740468(9) 0.01395(5) Uani 1 1 d . . .
N13A N 0.7803(9) 0.3240(8) 0.0845(6) 0.043(2) Uani 0.50 1 d PU E 1
O14A O 0.8146(7) 0.4195(8) 0.0571(5) 0.0406(19) Uani 0.50 1 d PU E 1
O13A O 0.6983(7) 0.2338(7) 0.0409(6) 0.047(2) Uani 0.50 1 d PU E 1
O12A O 0.8297(14) 0.3237(11) 0.1501(9) 0.103(7) Uani 0.50 1 d PU E 1
O15 O 0.8446(8) 0.1516(9) -0.0219(5) 0.040 Uani 0.50 1 d PD F 1
H15A H 0.875(12) 0.095(7) -0.003(4) 0.053 Uiso 0.50 1 d PD G 1
H15B H 0.840(18) 0.197(13) 0.022(4) 0.053 Uiso 0.50 1 d PD H 1
O13B O 0.8223(16) 0.1954(11) -0.0008(7) 0.074(4) Uani 0.50 1 d PU I 2
O12B O 0.8355(10) 0.2797(12) 0.1035(7) 0.072(4) Uani 0.50 1 d PU I 2
O14B O 0.8413(8) 0.3815(9) 0.0170(7) 0.060(3) Uani 0.50 1 d PU I 2
N13B N 0.8296(9) 0.2876(9) 0.0405(6) 0.042(2) Uani 0.50 1 d PU I 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O1 1.250(5) . ?
C1 N1 1.343(5) . ?
C1 C2 1.480(5) . ?
C2 C7 1.389(6) . ?
C2 C3 1.398(6) . ?
C3 C4 1.389(6) . ?
C4 C5 1.385(7) . ?
C5 C6 1.382(7) . ?
C6 C7 1.386(6) . ?
C8 N2 1.290(5) . ?
C8 C10 1.487(6) . ?
C8 C9 1.491(6) . ?
C10 N3 1.337(5) . ?
C10 C11 1.396(5) . ?
C11 C12 1.384(7) . ?
C12 C13 1.368(7) . ?
C13 C14 1.397(6) . ?
C14 N3 1.346(5) . ?
C14 C15 1.483(6) . ?
C15 N4 1.288(5) . ?
C15 C16 1.501(6) . ?
C17 O2 1.249(4) . ?
C17 N5 1.346(5) . ?
C17 C18 1.476(5) . ?
C18 C19 1.394(6) . ?
C18 C23 1.400(5) . ?
C19 C20 1.389(6) . ?
C20 C21 1.384(7) . ?
C21 C22 1.390(7) . ?
C22 C23 1.387(6) . ?
C24 O3 1.246(4) . ?
C24 N6 1.346(5) . ?
C24 C25 1.489(5) . ?
C25 C26 1.390(5) . ?
C25 C30 1.406(5) . ?
C26 C27 1.394(6) . ?
C27 C28 1.392(7) . ?
C28 C29 1.376(7) . ?
C29 C30 1.394(6) . ?
C31 N7 1.287(5) . ?
C31 C33 1.485(5) . ?
C31 C32 1.500(5) . ?
C33 N8 1.342(5) . ?
C33 C34 1.395(5) . ?
C34 C35 1.396(6) . ?
C35 C36 1.374(6) . ?
C36 C37 1.391(5) . ?
C37 N8 1.354(5) . ?
C37 C38 1.483(5) . ?
C38 N9 1.297(5) . ?
C38 C39 1.489(6) . ?
C40 O4 1.242(4) . ?
C40 N10 1.351(5) . ?
C40 C41 1.485(5) . ?
C41 C42 1.385(6) . ?
C41 C46 1.397(6) . ?
C42 C43 1.401(6) . ?
C43 C44 1.381(7) . ?
C44 C45 1.390(8) . ?
C45 C46 1.396(6) . ?
N1 N2 1.381(5) . ?
N2 Dy 2.554(3) . ?
N3 Dy 2.672(3) . ?
N4 N5 1.392(5) . ?
N4 Dy 2.555(3) . ?
N6 N7 1.390(4) . ?
N7 Dy 2.567(3) . ?
N8 Dy 2.647(3) . ?
N9 N10 1.390(4) . ?
N9 Dy 2.556(3) . ?
N11 O7 1.240(5) . ?
N11 O5 1.257(5) . ?
N11 O6 1.269(5) . ?
N12 O8 1.233(6) . ?
N12 O10 1.248(6) . ?
N12 O9 1.253(5) . ?
O1 Dy 2.404(3) . ?
O2 Dy 2.414(3) . ?
O3 Dy 2.395(3) . ?
O4 Dy 2.420(3) . ?
N13A O12A 1.219(16) . ?
N13A O13A 1.271(13) . ?
N13A O14A 1.317(14) . ?
O13B N13B 1.278(17) . ?
O12B N13B 1.160(15) . ?
O14B N13B 1.264(13) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C1 N1 120.8(3) . . ?
O1 C1 C2 121.8(3) . . ?
N1 C1 C2 117.4(3) . . ?
C7 C2 C3 120.1(4) . . ?
C7 C2 C1 121.9(3) . . ?
C3 C2 C1 118.0(4) . . ?
C4 C3 C2 119.5(4) . . ?
C5 C4 C3 120.1(4) . . ?
C6 C5 C4 120.4(4) . . ?
C5 C6 C7 120.1(4) . . ?
C6 C7 C2 119.8(4) . . ?
N2 C8 C10 114.2(3) . . ?
N2 C8 C9 125.0(4) . . ?
C10 C8 C9 120.6(3) . . ?
N3 C10 C11 123.4(4) . . ?
N3 C10 C8 116.2(3) . . ?
C11 C10 C8 120.1(4) . . ?
C12 C11 C10 118.0(4) . . ?
C13 C12 C11 119.3(4) . . ?
C12 C13 C14 119.5(4) . . ?
N3 C14 C13 122.0(4) . . ?
N3 C14 C15 116.1(3) . . ?
C13 C14 C15 121.9(4) . . ?
N4 C15 C14 114.2(4) . . ?
N4 C15 C16 124.8(4) . . ?
C14 C15 C16 121.1(4) . . ?
O2 C17 N5 120.8(3) . . ?
O2 C17 C18 121.9(3) . . ?
N5 C17 C18 117.3(3) . . ?
C19 C18 C23 119.8(4) . . ?
C19 C18 C17 121.7(4) . . ?
C23 C18 C17 118.4(3) . . ?
C20 C19 C18 119.7(4) . . ?
C21 C20 C19 120.5(4) . . ?
C20 C21 C22 120.1(4) . . ?
C23 C22 C21 119.9(4) . . ?
C22 C23 C18 120.1(4) . . ?
O3 C24 N6 120.7(3) . . ?
O3 C24 C25 121.2(3) . . ?
N6 C24 C25 117.9(3) . . ?
C26 C25 C30 120.7(4) . . ?
C26 C25 C24 117.1(3) . . ?
C30 C25 C24 121.9(3) . . ?
C25 C26 C27 119.4(4) . . ?
C28 C27 C26 120.0(4) . . ?
C29 C28 C27 120.5(4) . . ?
C28 C29 C30 120.6(4) . . ?
C29 C30 C25 118.8(4) . . ?
N7 C31 C33 114.3(3) . . ?
N7 C31 C32 126.7(3) . . ?
C33 C31 C32 118.8(3) . . ?
N8 C33 C34 123.4(4) . . ?
N8 C33 C31 116.1(3) . . ?
C34 C33 C31 120.3(3) . . ?
C33 C34 C35 118.1(4) . . ?
C36 C35 C34 119.3(4) . . ?
C35 C36 C37 118.9(4) . . ?
N8 C37 C36 123.0(3) . . ?
N8 C37 C38 115.8(3) . . ?
C36 C37 C38 121.1(4) . . ?
N9 C38 C37 114.5(3) . . ?
N9 C38 C39 125.1(4) . . ?
C37 C38 C39 120.3(4) . . ?
O4 C40 N10 120.5(3) . . ?
O4 C40 C41 121.9(4) . . ?
N10 C40 C41 117.5(3) . . ?
C42 C41 C46 121.0(4) . . ?
C42 C41 C40 118.4(4) . . ?
C46 C41 C40 120.6(4) . . ?
C41 C42 C43 119.3(4) . . ?
C44 C43 C42 120.1(5) . . ?
C43 C44 C45 120.4(4) . . ?
C44 C45 C46 120.1(5) . . ?
C45 C46 C41 119.1(4) . . ?
C1 N1 N2 114.9(3) . . ?
C8 N2 N1 118.3(3) . . ?
C8 N2 Dy 128.1(3) . . ?
N1 N2 Dy 113.5(2) . . ?
C10 N3 C14 117.8(3) . . ?
C10 N3 Dy 120.8(2) . . ?
C14 N3 Dy 120.5(2) . . ?
C15 N4 N5 117.9(3) . . ?
C15 N4 Dy 128.6(3) . . ?
N5 N4 Dy 113.4(2) . . ?
C17 N5 N4 113.9(3) . . ?
C24 N6 N7 113.5(3) . . ?
C31 N7 N6 118.2(3) . . ?
C31 N7 Dy 127.8(2) . . ?
N6 N7 Dy 113.8(2) . . ?
C33 N8 C37 117.2(3) . . ?
C33 N8 Dy 121.6(2) . . ?
C37 N8 Dy 120.9(2) . . ?
C38 N9 N10 116.9(3) . . ?
C38 N9 Dy 127.6(3) . . ?
N10 N9 Dy 115.3(2) . . ?
C40 N10 N9 113.8(3) . . ?
O7 N11 O5 121.2(4) . . ?
O7 N11 O6 119.8(4) . . ?
O5 N11 O6 119.0(4) . . ?
O8 N12 O10 121.6(5) . . ?
O8 N12 O9 119.3(5) . . ?
O10 N12 O9 119.2(4) . . ?
C1 O1 Dy 121.3(2) . . ?
C17 O2 Dy 120.9(2) . . ?
C24 O3 Dy 123.6(2) . . ?
C40 O4 Dy 122.7(2) . . ?
O3 Dy O1 120.19(9) . . ?
O3 Dy O2 79.15(9) . . ?
O1 Dy O2 127.77(9) . . ?
O3 Dy O4 128.46(9) . . ?
O1 Dy O4 83.45(9) . . ?
O2 Dy O4 124.18(9) . . ?
O3 Dy N2 76.53(10) . . ?
O1 Dy N2 62.41(10) . . ?
O2 Dy N2 154.95(10) . . ?
O4 Dy N2 76.85(10) . . ?
O3 Dy N4 81.78(10) . . ?
O1 Dy N4 155.98(10) . . ?
O2 Dy N4 61.86(10) . . ?
O4 Dy N4 74.45(10) . . ?
N2 Dy N4 119.68(11) . . ?
O3 Dy N9 154.87(11) . . ?
O1 Dy N9 81.66(11) . . ?
O2 Dy N9 77.21(10) . . ?
O4 Dy N9 61.60(10) . . ?
N2 Dy N9 127.70(11) . . ?
N4 Dy N9 79.65(12) . . ?
O3 Dy N7 61.95(9) . . ?
O1 Dy N7 72.67(10) . . ?
O2 Dy N7 77.99(10) . . ?
O4 Dy N7 154.96(10) . . ?
N2 Dy N7 85.31(10) . . ?
N4 Dy N7 130.30(10) . . ?
N9 Dy N7 120.32(10) . . ?
O3 Dy N8 115.49(9) . . ?
O1 Dy N8 64.15(9) . . ?
O2 Dy N8 63.84(10) . . ?
O4 Dy N8 116.05(9) . . ?
N2 Dy N8 122.62(10) . . ?
N4 Dy N8 117.59(10) . . ?
N9 Dy N8 60.33(10) . . ?
N7 Dy N8 60.00(9) . . ?
O3 Dy N3 66.46(9) . . ?
O1 Dy N3 117.45(10) . . ?
O2 Dy N3 114.74(10) . . ?
O4 Dy N3 62.03(9) . . ?
N2 Dy N3 59.98(10) . . ?
N4 Dy N3 59.72(10) . . ?
N9 Dy N3 116.75(10) . . ?
N7 Dy N3 122.92(10) . . ?
N8 Dy N3 176.78(9) . . ?
O12A N13A O13A 121.9(11) . . ?
O12A N13A O14A 119.4(10) . . ?
O13A N13A O14A 118.7(10) . . ?
O12B N13B O14B 123.0(14) . . ?
O12B N13B O13B 113.4(12) . . ?
O14B N13B O13B 123.3(12) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 C2 C7 -149.3(4) . . . . ?
N1 C1 C2 C7 29.5(5) . . . . ?
O1 C1 C2 C3 29.1(5) . . . . ?
N1 C1 C2 C3 -152.2(4) . . . . ?
C7 C2 C3 C4 0.7(6) . . . . ?
C1 C2 C3 C4 -177.7(4) . . . . ?
C2 C3 C4 C5 0.2(7) . . . . ?
C3 C4 C5 C6 -1.4(7) . . . . ?
C4 C5 C6 C7 1.7(7) . . . . ?
C5 C6 C7 C2 -0.8(6) . . . . ?
C3 C2 C7 C6 -0.4(6) . . . . ?
C1 C2 C7 C6 177.9(4) . . . . ?
N2 C8 C10 N3 -8.8(5) . . . . ?
C9 C8 C10 N3 175.7(4) . . . . ?
N2 C8 C10 C11 165.5(4) . . . . ?
C9 C8 C10 C11 -10.1(6) . . . . ?
N3 C10 C11 C12 -1.2(7) . . . . ?
C8 C10 C11 C12 -175.0(4) . . . . ?
C10 C11 C12 C13 1.1(7) . . . . ?
C11 C12 C13 C14 -0.4(8) . . . . ?
C12 C13 C14 N3 -0.3(7) . . . . ?
C12 C13 C14 C15 179.4(5) . . . . ?
N3 C14 C15 N4 4.7(6) . . . . ?
C13 C14 C15 N4 -175.0(4) . . . . ?
N3 C14 C15 C16 -175.4(4) . . . . ?
C13 C14 C15 C16 4.9(7) . . . . ?
O2 C17 C18 C19 -153.7(4) . . . . ?
N5 C17 C18 C19 25.1(6) . . . . ?
O2 C17 C18 C23 22.9(5) . . . . ?
N5 C17 C18 C23 -158.2(4) . . . . ?
C23 C18 C19 C20 0.1(7) . . . . ?
C17 C18 C19 C20 176.8(4) . . . . ?
C18 C19 C20 C21 -0.1(8) . . . . ?
C19 C20 C21 C22 -0.1(8) . . . . ?
C20 C21 C22 C23 0.2(7) . . . . ?
C21 C22 C23 C18 -0.1(6) . . . . ?
C19 C18 C23 C22 0.0(6) . . . . ?
C17 C18 C23 C22 -176.8(3) . . . . ?
O3 C24 C25 C26 14.6(5) . . . . ?
N6 C24 C25 C26 -169.2(4) . . . . ?
O3 C24 C25 C30 -159.5(4) . . . . ?
N6 C24 C25 C30 16.7(6) . . . . ?
C30 C25 C26 C27 1.0(6) . . . . ?
C24 C25 C26 C27 -173.2(4) . . . . ?
C25 C26 C27 C28 -0.5(7) . . . . ?
C26 C27 C28 C29 -1.0(8) . . . . ?
C27 C28 C29 C30 2.2(8) . . . . ?
C28 C29 C30 C25 -1.8(8) . . . . ?
C26 C25 C30 C29 0.2(7) . . . . ?
C24 C25 C30 C29 174.0(4) . . . . ?
N7 C31 C33 N8 -5.0(5) . . . . ?
C32 C31 C33 N8 179.4(4) . . . . ?
N7 C31 C33 C34 170.5(4) . . . . ?
C32 C31 C33 C34 -5.1(6) . . . . ?
N8 C33 C34 C35 2.3(7) . . . . ?
C31 C33 C34 C35 -172.8(4) . . . . ?
C33 C34 C35 C36 -2.7(7) . . . . ?
C34 C35 C36 C37 0.3(7) . . . . ?
C35 C36 C37 N8 2.7(7) . . . . ?
C35 C36 C37 C38 -176.3(4) . . . . ?
N8 C37 C38 N9 7.7(6) . . . . ?
C36 C37 C38 N9 -173.2(4) . . . . ?
N8 C37 C38 C39 -168.2(5) . . . . ?
C36 C37 C38 C39 10.9(7) . . . . ?
O4 C40 C41 C42 25.2(6) . . . . ?
N10 C40 C41 C42 -157.4(4) . . . . ?
O4 C40 C41 C46 -152.5(4) . . . . ?
N10 C40 C41 C46 24.8(6) . . . . ?
C46 C41 C42 C43 -1.3(7) . . . . ?
C40 C41 C42 C43 -179.1(4) . . . . ?
C41 C42 C43 C44 1.5(8) . . . . ?
C42 C43 C44 C45 -1.4(9) . . . . ?
C43 C44 C45 C46 0.9(9) . . . . ?
C44 C45 C46 C41 -0.7(8) . . . . ?
C42 C41 C46 C45 0.9(8) . . . . ?
C40 C41 C46 C45 178.6(5) . . . . ?
O1 C1 N1 N2 3.3(5) . . . . ?
C2 C1 N1 N2 -175.4(3) . . . . ?
C10 C8 N2 N1 -171.7(3) . . . . ?
C9 C8 N2 N1 3.6(6) . . . . ?
C10 C8 N2 Dy 9.0(5) . . . . ?
C9 C8 N2 Dy -175.7(3) . . . . ?
C1 N1 N2 C8 158.8(3) . . . . ?
C1 N1 N2 Dy -21.8(4) . . . . ?
C11 C10 N3 C14 0.5(6) . . . . ?
C8 C10 N3 C14 174.6(3) . . . . ?
C11 C10 N3 Dy -168.7(3) . . . . ?
C8 C10 N3 Dy 5.3(4) . . . . ?
C13 C14 N3 C10 0.2(6) . . . . ?
C15 C14 N3 C10 -179.5(4) . . . . ?
C13 C14 N3 Dy 169.5(3) . . . . ?
C15 C14 N3 Dy -10.2(5) . . . . ?
C14 C15 N4 N5 -176.5(3) . . . . ?
C16 C15 N4 N5 3.6(7) . . . . ?
C14 C15 N4 Dy 3.6(6) . . . . ?
C16 C15 N4 Dy -176.3(4) . . . . ?
O2 C17 N5 N4 3.5(5) . . . . ?
C18 C17 N5 N4 -175.3(3) . . . . ?
C15 N4 N5 C17 155.5(4) . . . . ?
Dy N4 N5 C17 -24.6(4) . . . . ?
O3 C24 N6 N7 12.3(5) . . . . ?
C25 C24 N6 N7 -163.9(3) . . . . ?
C33 C31 N7 N6 -169.2(3) . . . . ?
C32 C31 N7 N6 6.0(6) . . . . ?
C33 C31 N7 Dy 5.2(5) . . . . ?
C32 C31 N7 Dy -179.6(3) . . . . ?
C24 N6 N7 C31 149.4(4) . . . . ?
C24 N6 N7 Dy -25.8(4) . . . . ?
C34 C33 N8 C37 0.5(6) . . . . ?
C31 C33 N8 C37 175.9(4) . . . . ?
C34 C33 N8 Dy -172.3(3) . . . . ?
C31 C33 N8 Dy 3.0(5) . . . . ?
C36 C37 N8 C33 -3.1(6) . . . . ?
C38 C37 N8 C33 176.0(4) . . . . ?
C36 C37 N8 Dy 169.8(3) . . . . ?
C38 C37 N8 Dy -11.1(5) . . . . ?
C37 C38 N9 N10 -175.7(4) . . . . ?
C39 C38 N9 N10 0.0(7) . . . . ?
C37 C38 N9 Dy -0.7(6) . . . . ?
C39 C38 N9 Dy 175.0(4) . . . . ?
O4 C40 N10 N9 1.7(6) . . . . ?
C41 C40 N10 N9 -175.7(4) . . . . ?
C38 N9 N10 C40 156.1(4) . . . . ?
Dy N9 N10 C40 -19.5(5) . . . . ?
N1 C1 O1 Dy 19.7(5) . . . . ?
C2 C1 O1 Dy -161.7(3) . . . . ?
N5 C17 O2 Dy 22.4(5) . . . . ?
C18 C17 O2 Dy -158.8(3) . . . . ?
N6 C24 O3 Dy 9.9(5) . . . . ?
C25 C24 O3 Dy -174.0(2) . . . . ?
N10 C40 O4 Dy 19.5(5) . . . . ?
C41 C40 O4 Dy -163.3(3) . . . . ?
C24 O3 Dy O1 28.6(3) . . . . ?
C24 O3 Dy O2 -99.0(3) . . . . ?
C24 O3 Dy O4 135.7(3) . . . . ?
C24 O3 Dy N2 75.0(3) . . . . ?
C24 O3 Dy N4 -161.7(3) . . . . ?
C24 O3 Dy N9 -119.1(3) . . . . ?
C24 O3 Dy N7 -16.9(3) . . . . ?
C24 O3 Dy N8 -45.0(3) . . . . ?
C24 O3 Dy N3 137.8(3) . . . . ?
C1 O1 Dy O3 30.8(3) . . . . ?
C1 O1 Dy O2 130.9(3) . . . . ?
C1 O1 Dy O4 -100.3(3) . . . . ?
C1 O1 Dy N2 -21.8(3) . . . . ?
C1 O1 Dy N4 -123.3(3) . . . . ?
C1 O1 Dy N9 -162.5(3) . . . . ?
C1 O1 Dy N7 72.0(3) . . . . ?
C1 O1 Dy N8 136.5(3) . . . . ?
C1 O1 Dy N3 -46.6(3) . . . . ?
C17 O2 Dy O3 -111.2(3) . . . . ?
C17 O2 Dy O1 128.9(3) . . . . ?
C17 O2 Dy O4 18.3(3) . . . . ?
C17 O2 Dy N2 -125.2(3) . . . . ?
C17 O2 Dy N4 -24.8(3) . . . . ?
C17 O2 Dy N9 60.2(3) . . . . ?
C17 O2 Dy N7 -174.5(3) . . . . ?
C17 O2 Dy N8 123.2(3) . . . . ?
C17 O2 Dy N3 -53.6(3) . . . . ?
C40 O4 Dy O3 131.4(3) . . . . ?
C40 O4 Dy O1 -104.8(3) . . . . ?
C40 O4 Dy O2 27.0(3) . . . . ?
C40 O4 Dy N2 -168.0(3) . . . . ?
C40 O4 Dy N4 65.7(3) . . . . ?
C40 O4 Dy N9 -20.8(3) . . . . ?
C40 O4 Dy N7 -122.3(3) . . . . ?
C40 O4 Dy N8 -47.8(3) . . . . ?
C40 O4 Dy N3 129.3(3) . . . . ?
C8 N2 Dy O3 65.6(3) . . . . ?
N1 N2 Dy O3 -113.7(2) . . . . ?
C8 N2 Dy O1 -159.2(4) . . . . ?
N1 N2 Dy O1 21.5(2) . . . . ?
C8 N2 Dy O2 79.8(4) . . . . ?
N1 N2 Dy O2 -99.5(3) . . . . ?
C8 N2 Dy O4 -69.8(3) . . . . ?
N1 N2 Dy O4 110.9(2) . . . . ?
C8 N2 Dy N4 -6.6(4) . . . . ?
N1 N2 Dy N4 174.1(2) . . . . ?
C8 N2 Dy N9 -106.9(3) . . . . ?
N1 N2 Dy N9 73.8(3) . . . . ?
C8 N2 Dy N7 127.9(3) . . . . ?
N1 N2 Dy N7 -51.4(2) . . . . ?
C8 N2 Dy N8 177.5(3) . . . . ?
N1 N2 Dy N8 -1.8(3) . . . . ?
C8 N2 Dy N3 -4.7(3) . . . . ?
N1 N2 Dy N3 176.0(3) . . . . ?
C15 N4 Dy O3 -73.7(4) . . . . ?
N5 N4 Dy O3 106.4(3) . . . . ?
C15 N4 Dy O1 83.8(4) . . . . ?
N5 N4 Dy O1 -96.1(3) . . . . ?
C15 N4 Dy O2 -155.8(4) . . . . ?
N5 N4 Dy O2 24.4(2) . . . . ?
C15 N4 Dy O4 60.1(4) . . . . ?
N5 N4 Dy O4 -119.8(3) . . . . ?
C15 N4 Dy N2 -4.4(4) . . . . ?
N5 N4 Dy N2 175.7(2) . . . . ?
C15 N4 Dy N9 123.3(4) . . . . ?
N5 N4 Dy N9 -56.6(3) . . . . ?
C15 N4 Dy N7 -115.5(4) . . . . ?
N5 N4 Dy N7 64.6(3) . . . . ?
C15 N4 Dy N8 171.8(3) . . . . ?
N5 N4 Dy N8 -8.1(3) . . . . ?
C15 N4 Dy N3 -6.2(3) . . . . ?
N5 N4 Dy N3 173.9(3) . . . . ?
C38 N9 Dy O3 83.9(5) . . . . ?
N10 N9 Dy O3 -101.1(3) . . . . ?
C38 N9 Dy O1 -68.3(4) . . . . ?
N10 N9 Dy O1 106.8(3) . . . . ?
C38 N9 Dy O2 63.6(4) . . . . ?
N10 N9 Dy O2 -121.3(3) . . . . ?
C38 N9 Dy O4 -155.3(4) . . . . ?
N10 N9 Dy O4 19.8(3) . . . . ?
C38 N9 Dy N2 -113.5(4) . . . . ?
N10 N9 Dy N2 61.6(3) . . . . ?
C38 N9 Dy N4 126.9(4) . . . . ?
N10 N9 Dy N4 -58.1(3) . . . . ?
C38 N9 Dy N7 -4.0(4) . . . . ?
N10 N9 Dy N7 171.0(3) . . . . ?
C38 N9 Dy N8 -3.4(4) . . . . ?
N10 N9 Dy N8 171.7(3) . . . . ?
C38 N9 Dy N3 175.1(4) . . . . ?
N10 N9 Dy N3 -9.8(3) . . . . ?
C31 N7 Dy O3 -153.3(4) . . . . ?
N6 N7 Dy O3 21.2(2) . . . . ?
C31 N7 Dy O1 66.9(3) . . . . ?
N6 N7 Dy O1 -118.5(3) . . . . ?
C31 N7 Dy O2 -69.3(3) . . . . ?
N6 N7 Dy O2 105.2(3) . . . . ?
C31 N7 Dy O4 85.1(4) . . . . ?
N6 N7 Dy O4 -100.4(3) . . . . ?
C31 N7 Dy N2 129.4(4) . . . . ?
N6 N7 Dy N2 -56.0(3) . . . . ?
C31 N7 Dy N4 -105.0(3) . . . . ?
N6 N7 Dy N4 69.6(3) . . . . ?
C31 N7 Dy N9 -2.1(4) . . . . ?
N6 N7 Dy N9 172.5(2) . . . . ?
C31 N7 Dy N8 -2.8(3) . . . . ?
N6 N7 Dy N8 171.8(3) . . . . ?
C31 N7 Dy N3 178.8(3) . . . . ?
N6 N7 Dy N3 -6.6(3) . . . . ?
C33 N8 Dy O3 28.2(3) . . . . ?
C37 N8 Dy O3 -144.4(3) . . . . ?
C33 N8 Dy O1 -84.6(3) . . . . ?
C37 N8 Dy O1 102.8(3) . . . . ?
C33 N8 Dy O2 90.4(3) . . . . ?
C37 N8 Dy O2 -82.2(3) . . . . ?
C33 N8 Dy O4 -152.4(3) . . . . ?
C37 N8 Dy O4 35.0(3) . . . . ?
C33 N8 Dy N2 -61.7(3) . . . . ?
C37 N8 Dy N2 125.7(3) . . . . ?
C33 N8 Dy N4 122.3(3) . . . . ?
C37 N8 Dy N4 -50.3(3) . . . . ?
C33 N8 Dy N9 -179.8(3) . . . . ?
C37 N8 Dy N9 7.6(3) . . . . ?
C33 N8 Dy N7 -0.5(3) . . . . ?
C37 N8 Dy N7 -173.1(3) . . . . ?
C10 N3 Dy O3 -88.6(3) . . . . ?
C14 N3 Dy O3 102.5(3) . . . . ?
C10 N3 Dy O2 -153.3(3) . . . . ?
C14 N3 Dy O2 37.7(3) . . . . ?
C10 N3 Dy O4 89.6(3) . . . . ?
C14 N3 Dy O4 -79.4(3) . . . . ?
C10 N3 Dy N2 -1.0(3) . . . . ?
C14 N3 Dy N2 -169.9(3) . . . . ?
C10 N3 Dy N4 177.2(3) . . . . ?
C14 N3 Dy N4 8.2(3) . . . . ?
C10 N3 Dy N9 119.0(3) . . . . ?
C14 N3 Dy N9 -49.9(3) . . . . ?
C10 N3 Dy N7 -61.8(3) . . . . ?
C14 N3 Dy N7 129.2(3) . . . . ?


_diffrn_measured_fraction_theta_max 0.761
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.958
_refine_diff_density_max         1.741
_refine_diff_density_min         -1.301
_refine_diff_density_rms         0.190

_database_code_depnum_ccdc_archive 'CCDC 870724'
