# Electronic Supplementary Material (ESI) for Chemical Science
# This journal is © The Royal Society of Chemistry 2012


data_global
#TrackingRef '1853_web_deposit_cif_file_0_JeromeLONG_1279726640.cif'

_journal_name_full               'Chemical Science'

_journal_coden_Cambridge         1475

_publ_contact_author_name        'Muralee Murugesu'
_publ_contact_author_email       M.MURUGESU@UOTTAWA.CA

_publ_section_title              
;
A Dysprosium(III) Quadruple-Stranded Helicate: First Example of
a Lanthanide Helicate Showing a Single-Molecule Magnet Behaviour
;
loop_
_publ_author_name
H.Murugesu
F.Habib

data_mm033
_database_code_depnum_ccdc_archive 'CCDC 785130'
#TrackingRef '1853_web_deposit_cif_file_0_JeromeLONG_1279726640.cif'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C104.75 H113.50 Dy2 N10 O16.25'
_chemical_formula_weight         2097.56

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   21.5894(8)
_cell_length_b                   20.9227(9)
_cell_length_c                   23.8146(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 109.321(2)
_cell_angle_gamma                90.00
_cell_volume                     10151.4(7)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9932
_cell_measurement_theta_min      2.21
_cell_measurement_theta_max      28.00

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.11
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.05
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.372
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             4296
_exptl_absorpt_coefficient_mu    1.529
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8498
_exptl_absorpt_correction_T_max  0.9275
_exptl_absorpt_process_details   'SADABS, Bruker (2003)'

_exptl_special_details           
;
Data collection is performed with three batch runs at phi = 0.00 deg
(650 frames), at phi = 120.00 deg (650 frames), and at phi = 240.00 deg
(650 frames).
Frame width = 0.30 deg in omega.
Data is merged, corrected for decay (if any), and treated with multi-scan
absorption corrections (if required). All symmetry-equivalent reflections
are merged for centrosymmetric data.
Friedel pairs are not merged for noncentrosymmetric data.
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            114324
_diffrn_reflns_av_R_equivalents  0.0679
_diffrn_reflns_av_sigmaI/netI    0.0376
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         1.47
_diffrn_reflns_theta_max         21.49
_reflns_number_total             11611
_reflns_number_gt                8746
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'APEX II, Bruker (2009)'
_computing_cell_refinement       'APEX II, Bruker (2009)'
_computing_data_reduction        'XPREP, Bruker (2009)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'SHELXTL, Bruker (2004)'
_computing_publication_material  'SHELXTL, Bruker (2004)'

_refine_special_details          
;
Refinement of F² against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F², conventional R-factors R are based
on F, with F set to zero for negative F². The threshold expression of
F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F² are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0666P)²+33.7569P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         11611
_refine_ls_number_parameters     1203
_refine_ls_number_restraints     5
_refine_ls_R_factor_all          0.0704
_refine_ls_R_factor_gt           0.0466
_refine_ls_wR_factor_ref         0.1296
_refine_ls_wR_factor_gt          0.1134
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_restrained_S_all      1.034
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.759294(17) 0.179589(18) 0.203172(16) 0.03976(14) Uani 1 1 d . . .
Dy2 Dy 0.305299(18) 0.23811(2) 0.296585(17) 0.04617(15) Uani 1 1 d . . .
N1 N 0.7565(3) 0.0861(3) 0.2782(3) 0.0444(16) Uani 1 1 d . . .
N2 N 0.5880(3) 0.1202(3) 0.4140(3) 0.0513(17) Uani 1 1 d . . .
N3 N 0.4560(3) 0.1379(3) 0.0802(3) 0.0502(17) Uani 1 1 d . . .
N4 N 0.2893(3) 0.1432(3) 0.2193(3) 0.0447(16) Uani 1 1 d . . .
N5 N 0.6995(3) 0.2871(3) 0.1519(3) 0.0416(16) Uani 1 1 d . . .
N6 N 0.4246(3) 0.3087(3) 0.0998(3) 0.0479(17) Uani 1 1 d . . .
N7 N 0.6594(3) 0.2949(4) 0.4017(3) 0.0538(18) Uani 1 1 d . . .
N8 N 0.3875(3) 0.3271(3) 0.3585(3) 0.0524(18) Uani 1 1 d . . .
N9 N 0.6500(4) 0.9487(4) 0.1249(4) 0.077(2) Uani 1 1 d . . .
N10 N 0.1794(5) 0.4928(4) 0.1168(4) 0.094(3) Uani 1 1 d . . .
O1 O 0.8213(3) 0.0995(3) 0.1923(2) 0.0536(14) Uani 1 1 d . . .
O2 O 0.8968(3) 0.0440(4) 0.1385(3) 0.091(2) Uani 1 1 d . . .
O3 O 0.3965(2) 0.1813(2) 0.3441(2) 0.0469(13) Uani 1 1 d . . .
O4 O 0.3262(3) 0.2137(3) 0.4082(2) 0.0621(16) Uani 1 1 d . . .
O5 O 0.6569(2) 0.1443(2) 0.1513(2) 0.0414(12) Uani 1 1 d . . .
O6 O 0.7342(2) 0.1609(3) 0.0905(2) 0.0559(15) Uani 1 1 d . . .
O7 O 0.2255(3) 0.1747(3) 0.3033(2) 0.0602(16) Uani 1 1 d . . .
O8 O 0.1226(4) 0.1489(4) 0.3445(3) 0.092(2) Uani 1 1 d . . .
O9 O 0.8323(2) 0.2418(3) 0.1835(3) 0.0547(15) Uani 1 1 d . . .
O10 O 0.9615(3) 0.2722(4) 0.1963(3) 0.080(2) Uani 1 1 d . . .
O11 O 0.3348(2) 0.2830(3) 0.2247(2) 0.0496(14) Uani 1 1 d . . .
O12 O 0.2089(3) 0.2661(3) 0.1983(2) 0.0613(16) Uani 1 1 d . . .
O13 O 0.7371(2) 0.2283(2) 0.2776(2) 0.0435(13) Uani 1 1 d . . .
O14 O 0.8584(2) 0.1935(3) 0.3021(2) 0.0541(15) Uani 1 1 d . . .
O15 O 0.2476(3) 0.3165(3) 0.3185(3) 0.0672(17) Uani 1 1 d . . .
O16 O 0.1348(4) 0.3672(4) 0.3114(4) 0.103(3) Uani 1 1 d . . .
C1 C 0.8540(4) 0.0495(4) 0.2171(4) 0.051(2) Uani 1 1 d . . .
C2 C 0.8971(4) 0.0190(5) 0.1908(5) 0.066(3) Uani 1 1 d . . .
C3 C 0.9333(5) -0.0318(5) 0.2182(6) 0.088(3) Uani 1 1 d . . .
H3A H 0.9611 -0.0509 0.2005 0.105 Uiso 1 1 calc R . .
C4 C 0.9309(5) -0.0560(5) 0.2698(7) 0.107(4) Uani 1 1 d . . .
H4A H 0.9578 -0.0901 0.2879 0.128 Uiso 1 1 calc R . .
C5 C 0.8885(5) -0.0299(6) 0.2954(6) 0.104(4) Uani 1 1 d . . .
H5A H 0.8860 -0.0473 0.3305 0.125 Uiso 1 1 calc R . .
C6 C 0.8488(4) 0.0227(4) 0.2696(5) 0.062(2) Uani 1 1 d . . .
C7 C 0.9196(7) 0.0071(9) 0.0984(6) 0.170(8) Uani 1 1 d . . .
H7A H 0.9163 0.0322 0.0638 0.254 Uiso 1 1 calc R . .
H7B H 0.8933 -0.0307 0.0869 0.254 Uiso 1 1 calc R . .
H7C H 0.9646 -0.0048 0.1179 0.254 Uiso 1 1 calc R . .
C8 C 0.8010(4) 0.0423(4) 0.2961(4) 0.057(2) Uani 1 1 d . . .
H8A H 0.8022 0.0208 0.3306 0.068 Uiso 1 1 calc R . .
C9 C 0.7138(4) 0.0935(4) 0.3125(4) 0.047(2) Uani 1 1 d . . .
C10 C 0.7356(4) 0.0899(4) 0.3736(4) 0.055(2) Uani 1 1 d . . .
H10N H 0.7797 0.0819 0.3938 0.066 Uiso 1 1 calc R . .
C11 C 0.6929(4) 0.0979(4) 0.4054(4) 0.053(2) Uani 1 1 d . . .
H11A H 0.7088 0.0947 0.4467 0.063 Uiso 1 1 calc R . .
C12 C 0.6274(4) 0.1105(4) 0.3770(3) 0.047(2) Uani 1 1 d . . .
C13 C 0.6054(4) 0.1145(4) 0.3157(4) 0.060(2) Uani 1 1 d . . .
H13A H 0.5614 0.1232 0.2956 0.071 Uiso 1 1 calc R . .
C14 C 0.6476(4) 0.1058(4) 0.2838(4) 0.055(2) Uani 1 1 d . . .
H14A H 0.6316 0.1082 0.2425 0.066 Uiso 1 1 calc R . .
C15 C 0.5311(4) 0.1457(4) 0.3931(3) 0.045(2) Uani 1 1 d . . .
H15A H 0.5146 0.1555 0.3527 0.054 Uiso 1 1 calc R . .
C16 C 0.4258(4) 0.1791(4) 0.4022(3) 0.0423(19) Uani 1 1 d . . .
C17 C 0.4916(4) 0.1598(4) 0.4302(3) 0.045(2) Uani 1 1 d . . .
C18 C 0.5184(4) 0.1601(4) 0.4921(4) 0.058(2) Uani 1 1 d . . .
H18A H 0.5619 0.1481 0.5103 0.070 Uiso 1 1 calc R . .
C19 C 0.4818(5) 0.1776(5) 0.5262(4) 0.074(3) Uani 1 1 d . . .
H19A H 0.5006 0.1774 0.5674 0.089 Uiso 1 1 calc R . .
C20 C 0.4167(4) 0.1958(5) 0.5004(4) 0.061(2) Uani 1 1 d . . .
H20A H 0.3918 0.2070 0.5241 0.073 Uiso 1 1 calc R . .
C21 C 0.3896(4) 0.1972(4) 0.4401(4) 0.052(2) Uani 1 1 d . . .
C22 C 0.2831(5) 0.2282(6) 0.4401(4) 0.092(4) Uani 1 1 d . . .
H22A H 0.2406 0.2389 0.4127 0.138 Uiso 1 1 calc R . .
H22B H 0.3001 0.2638 0.4661 0.138 Uiso 1 1 calc R . .
H22C H 0.2794 0.1917 0.4633 0.138 Uiso 1 1 calc R . .
C23 C 0.6287(4) 0.1534(4) 0.0940(3) 0.0413(19) Uani 1 1 d . . .
C24 C 0.6677(4) 0.1627(4) 0.0576(3) 0.045(2) Uani 1 1 d . . .
C25 C 0.6407(4) 0.1731(5) -0.0025(4) 0.068(3) Uani 1 1 d . . .
H25A H 0.6676 0.1783 -0.0256 0.082 Uiso 1 1 calc R . .
C26 C 0.5732(4) 0.1757(5) -0.0284(4) 0.066(3) Uani 1 1 d . . .
H26A H 0.5547 0.1847 -0.0688 0.079 Uiso 1 1 calc R . .
C27 C 0.5340(4) 0.1653(4) 0.0049(4) 0.055(2) Uani 1 1 d . . .
H27A H 0.4887 0.1659 -0.0134 0.066 Uiso 1 1 calc R . .
C28 C 0.5600(4) 0.1536(3) 0.0662(3) 0.0390(18) Uani 1 1 d . . .
C29 C 0.7799(4) 0.1583(6) 0.0599(4) 0.087(3) Uani 1 1 d . . .
H29A H 0.8236 0.1572 0.0881 0.130 Uiso 1 1 calc R . .
H29B H 0.7750 0.1954 0.0351 0.130 Uiso 1 1 calc R . .
H29C H 0.7724 0.1205 0.0357 0.130 Uiso 1 1 calc R . .
C30 C 0.5179(4) 0.1448(4) 0.1015(3) 0.045(2) Uani 1 1 d . . .
H30A H 0.5373 0.1441 0.1427 0.054 Uiso 1 1 calc R . .
C31 C 0.4174(3) 0.1351(4) 0.1182(3) 0.045(2) Uani 1 1 d . . .
C32 C 0.3498(4) 0.1386(4) 0.0899(3) 0.043(2) Uani 1 1 d . . .
H32A H 0.3327 0.1396 0.0486 0.052 Uiso 1 1 calc R . .
C33 C 0.3083(4) 0.1408(4) 0.1231(3) 0.050(2) Uani 1 1 d . . .
H33A H 0.2633 0.1436 0.1036 0.060 Uiso 1 1 calc R . .
C34 C 0.3313(3) 0.1391(4) 0.1841(3) 0.0393(19) Uani 1 1 d . . .
C35 C 0.3984(4) 0.1362(4) 0.2121(4) 0.057(2) Uani 1 1 d . . .
H35A H 0.4152 0.1360 0.2534 0.069 Uiso 1 1 calc R . .
C36 C 0.4411(4) 0.1336(4) 0.1797(3) 0.057(2) Uani 1 1 d . . .
H36A H 0.4861 0.1309 0.1995 0.069 Uiso 1 1 calc R . .
C37 C 0.2383(4) 0.1070(4) 0.2007(4) 0.059(2) Uani 1 1 d . . .
H37A H 0.2354 0.0814 0.1680 0.071 Uiso 1 1 calc R . .
C38 C 0.1812(4) 0.1345(5) 0.2743(4) 0.059(2) Uani 1 1 d . . .
C39 C 0.1845(4) 0.1012(5) 0.2248(4) 0.066(3) Uani 1 1 d . . .
C40 C 0.1350(5) 0.0559(7) 0.1956(5) 0.108(4) Uani 1 1 d . . .
H40A H 0.1376 0.0337 0.1626 0.129 Uiso 1 1 calc R . .
C41 C 0.0841(7) 0.0451(8) 0.2160(7) 0.144(6) Uani 1 1 d . . .
H41A H 0.0522 0.0150 0.1974 0.173 Uiso 1 1 calc R . .
C42 C 0.0797(5) 0.0788(7) 0.2642(6) 0.107(4) Uani 1 1 d . . .
H42A H 0.0440 0.0721 0.2772 0.128 Uiso 1 1 calc R . .
C43 C 0.1262(5) 0.1213(5) 0.2930(4) 0.072(3) Uani 1 1 d . . .
C44 C 0.1076(5) 0.2156(7) 0.3391(6) 0.111(4) Uani 1 1 d . . .
H44A H 0.1065 0.2317 0.3765 0.167 Uiso 1 1 calc R . .
H44B H 0.0656 0.2220 0.3091 0.167 Uiso 1 1 calc R . .
H44C H 0.1407 0.2379 0.3280 0.167 Uiso 1 1 calc R . .
C45 C 0.8444(4) 0.2969(5) 0.1658(3) 0.050(2) Uani 1 1 d . . .
C46 C 0.9099(4) 0.3139(5) 0.1712(4) 0.060(2) Uani 1 1 d . . .
C47 C 0.9241(5) 0.3751(5) 0.1550(5) 0.076(3) Uani 1 1 d . . .
H47A H 0.9674 0.3857 0.1598 0.091 Uiso 1 1 calc R . .
C48 C 0.8762(5) 0.4197(5) 0.1326(5) 0.084(3) Uani 1 1 d . . .
H48A H 0.8868 0.4600 0.1220 0.101 Uiso 1 1 calc R . .
C49 C 0.8119(5) 0.4045(5) 0.1255(4) 0.069(3) Uani 1 1 d . . .
H49A H 0.7791 0.4346 0.1099 0.082 Uiso 1 1 calc R . .
C50 C 0.7955(4) 0.3437(4) 0.1419(3) 0.049(2) Uani 1 1 d . . .
C51 C 0.9595(5) 0.2143(6) 0.1641(5) 0.087(3) Uani 1 1 d . . .
H51A H 0.9967 0.1883 0.1848 0.131 Uiso 1 1 calc R . .
H51B H 0.9607 0.2242 0.1251 0.131 Uiso 1 1 calc R . .
H51C H 0.9198 0.1916 0.1607 0.131 Uiso 1 1 calc R . .
C52 C 0.7277(4) 0.3354(4) 0.1357(3) 0.047(2) Uani 1 1 d . . .
H52A H 0.7001 0.3690 0.1176 0.057 Uiso 1 1 calc R . .
C53 C 0.6297(3) 0.2933(4) 0.1392(3) 0.0418(19) Uani 1 1 d . . .
C54 C 0.5884(4) 0.3147(4) 0.0843(3) 0.049(2) Uani 1 1 d . . .
H54A H 0.6059 0.3256 0.0548 0.059 Uiso 1 1 calc R . .
C55 C 0.5223(4) 0.3196(4) 0.0734(4) 0.051(2) Uani 1 1 d . . .
H55A H 0.4956 0.3341 0.0364 0.062 Uiso 1 1 calc R . .
C56 C 0.4942(4) 0.3039(4) 0.1156(3) 0.043(2) Uani 1 1 d . . .
C57 C 0.5361(4) 0.2812(4) 0.1709(3) 0.045(2) Uani 1 1 d . . .
H57A H 0.5186 0.2693 0.2002 0.054 Uiso 1 1 calc R . .
C58 C 0.6024(4) 0.2764(4) 0.1819(4) 0.047(2) Uani 1 1 d . . .
H58A H 0.6294 0.2616 0.2187 0.057 Uiso 1 1 calc R . .
C59 C 0.3958(4) 0.3043(4) 0.1373(4) 0.047(2) Uani 1 1 d . . .
H59A H 0.4215 0.3025 0.1772 0.056 Uiso 1 1 calc R . .
C60 C 0.2997(3) 0.2885(4) 0.1685(3) 0.042(2) Uani 1 1 d . . .
C61 C 0.3253(4) 0.3017(4) 0.1228(3) 0.043(2) Uani 1 1 d . . .
C62 C 0.2828(4) 0.3074(4) 0.0642(4) 0.053(2) Uani 1 1 d . . .
H62A H 0.3004 0.3179 0.0346 0.063 Uiso 1 1 calc R . .
C63 C 0.2164(4) 0.2979(4) 0.0484(4) 0.058(2) Uani 1 1 d . . .
H63A H 0.1901 0.3012 0.0088 0.070 Uiso 1 1 calc R . .
C64 C 0.1883(4) 0.2834(4) 0.0917(4) 0.056(2) Uani 1 1 d . . .
H64A H 0.1434 0.2768 0.0817 0.067 Uiso 1 1 calc R . .
C65 C 0.2301(4) 0.2792(4) 0.1508(3) 0.0418(19) Uani 1 1 d . . .
C66 C 0.1403(4) 0.2688(5) 0.1903(4) 0.078(3) Uani 1 1 d . . .
H66A H 0.1336 0.2589 0.2272 0.117 Uiso 1 1 calc R . .
H66B H 0.1172 0.2384 0.1606 0.117 Uiso 1 1 calc R . .
H66C H 0.1241 0.3110 0.1778 0.117 Uiso 1 1 calc R . .
C67 C 0.7750(4) 0.2338(4) 0.3337(3) 0.0424(19) Uani 1 1 d . . .
C68 C 0.8417(4) 0.2168(4) 0.3494(3) 0.047(2) Uani 1 1 d . . .
C69 C 0.8849(4) 0.2247(4) 0.4065(4) 0.057(2) Uani 1 1 d . . .
H69A H 0.9291 0.2146 0.4156 0.068 Uiso 1 1 calc R . .
C70 C 0.8611(4) 0.2483(5) 0.4508(4) 0.062(3) Uani 1 1 d . . .
H70A H 0.8894 0.2536 0.4896 0.075 Uiso 1 1 calc R . .
C71 C 0.7967(4) 0.2633(4) 0.4366(3) 0.054(2) Uani 1 1 d . . .
H71A H 0.7815 0.2791 0.4661 0.064 Uiso 1 1 calc R . .
C72 C 0.7521(4) 0.2558(4) 0.3785(3) 0.045(2) Uani 1 1 d . . .
C73 C 0.9252(4) 0.1831(5) 0.3095(4) 0.076(3) Uani 1 1 d . . .
H73A H 0.9293 0.1676 0.2730 0.114 Uiso 1 1 calc R . .
H73B H 0.9430 0.1522 0.3404 0.114 Uiso 1 1 calc R . .
H73C H 0.9489 0.2226 0.3203 0.114 Uiso 1 1 calc R . .
C74 C 0.6828(4) 0.2695(4) 0.3651(4) 0.045(2) Uani 1 1 d . . .
H74A H 0.6542 0.2590 0.3275 0.055 Uiso 1 1 calc R . .
C75 C 0.5908(4) 0.3030(4) 0.3882(4) 0.049(2) Uani 1 1 d . . .
C76 C 0.5688(4) 0.3128(4) 0.4354(4) 0.062(2) Uani 1 1 d . . .
H76A H 0.5986 0.3142 0.4739 0.074 Uiso 1 1 calc R . .
C77 C 0.5032(4) 0.3203(5) 0.4263(4) 0.064(3) Uani 1 1 d . . .
H77A H 0.4894 0.3261 0.4590 0.077 Uiso 1 1 calc R . .
C78 C 0.4566(4) 0.3196(4) 0.3696(4) 0.051(2) Uani 1 1 d . . .
C79 C 0.4789(4) 0.3104(4) 0.3222(4) 0.059(2) Uani 1 1 d . . .
H79A H 0.4491 0.3089 0.2837 0.071 Uiso 1 1 calc R . .
C80 C 0.5457(4) 0.3033(4) 0.3318(4) 0.058(2) Uani 1 1 d . . .
H80A H 0.5601 0.2986 0.2993 0.069 Uiso 1 1 calc R . .
C81 C 0.3723(4) 0.3746(4) 0.3860(4) 0.061(2) Uani 1 1 d . . .
H81A H 0.4075 0.3982 0.4103 0.073 Uiso 1 1 calc R . .
C82 C 0.2494(5) 0.3673(5) 0.3500(4) 0.067(3) Uani 1 1 d . . .
C83 C 0.3087(5) 0.3959(4) 0.3844(4) 0.062(2) Uani 1 1 d . . .
C84 C 0.3067(6) 0.4497(5) 0.4193(5) 0.084(3) Uani 1 1 d . . .
H84A H 0.3459 0.4679 0.4432 0.101 Uiso 1 1 calc R . .
C85 C 0.2484(7) 0.4759(6) 0.4187(5) 0.093(4) Uani 1 1 d . . .
H85A H 0.2479 0.5113 0.4421 0.112 Uiso 1 1 calc R . .
C86 C 0.1900(6) 0.4489(6) 0.3827(5) 0.089(4) Uani 1 1 d . . .
H86A H 0.1503 0.4676 0.3812 0.107 Uiso 1 1 calc R . .
C87 C 0.1894(5) 0.3963(6) 0.3500(4) 0.075(3) Uani 1 1 d . . .
C88 C 0.0729(5) 0.3921(7) 0.3091(6) 0.130(5) Uani 1 1 d . . .
H88A H 0.0386 0.3678 0.2812 0.194 Uiso 1 1 calc R . .
H88B H 0.0697 0.4360 0.2965 0.194 Uiso 1 1 calc R . .
H88C H 0.0685 0.3895 0.3478 0.194 Uiso 1 1 calc R . .
C89 C 0.6168(6) 0.9949(5) 0.1533(6) 0.110(4) Uani 1 1 d . . .
H89A H 0.6060 1.0333 0.1291 0.133 Uiso 1 1 calc R . .
H89B H 0.6470 1.0069 0.1920 0.133 Uiso 1 1 calc R . .
C90 C 0.5548(10) 0.9686(8) 0.1609(13) 0.273(16) Uani 1 1 d . . .
H90A H 0.5362 1.0001 0.1799 0.409 Uiso 1 1 calc R . .
H90B H 0.5651 0.9308 0.1850 0.409 Uiso 1 1 calc R . .
H90C H 0.5239 0.9583 0.1226 0.409 Uiso 1 1 calc R . .
C91 C 0.6598(9) 0.8863(6) 0.1512(6) 0.152(7) Uani 1 1 d . . .
H91A H 0.6745 0.8570 0.1267 0.182 Uiso 1 1 calc R . .
H91B H 0.6189 0.8703 0.1544 0.182 Uiso 1 1 calc R . .
C92 C 0.7137(15) 0.8914(8) 0.2156(6) 0.312(19) Uani 1 1 d . . .
H92A H 0.7211 0.8499 0.2338 0.469 Uiso 1 1 calc R . .
H92B H 0.6986 0.9200 0.2398 0.469 Uiso 1 1 calc R . .
H92C H 0.7540 0.9073 0.2121 0.469 Uiso 1 1 calc R . .
C93 C 0.7088(5) 0.9852(6) 0.1200(6) 0.103(4) Uani 1 1 d . . .
H93A H 0.7387 0.9937 0.1598 0.123 Uiso 1 1 calc R . .
H93B H 0.6938 1.0261 0.1013 0.123 Uiso 1 1 calc R . .
C94 C 0.7465(7) 0.9513(8) 0.0850(7) 0.159(7) Uani 1 1 d . . .
H94A H 0.7824 0.9776 0.0838 0.239 Uiso 1 1 calc R . .
H94B H 0.7177 0.9434 0.0452 0.239 Uiso 1 1 calc R . .
H94C H 0.7630 0.9114 0.1039 0.239 Uiso 1 1 calc R . .
C95 C 0.6086(7) 0.9372(6) 0.0593(6) 0.114(4) Uani 1 1 d . . .
H95A H 0.6304 0.9046 0.0437 0.137 Uiso 1 1 calc R . .
H95B H 0.5666 0.9198 0.0583 0.137 Uiso 1 1 calc R . .
C96 C 0.5955(10) 0.9941(7) 0.0173(7) 0.208(11) Uani 1 1 d . . .
H96A H 0.5696 0.9807 -0.0220 0.311 Uiso 1 1 calc R . .
H96B H 0.6364 1.0113 0.0166 0.311 Uiso 1 1 calc R . .
H96C H 0.5721 1.0263 0.0309 0.311 Uiso 1 1 calc R . .
C97 C 0.2239(9) 0.5419(8) 0.1056(7) 0.157(7) Uani 1 1 d . . .
H97A H 0.2519 0.5585 0.1435 0.188 Uiso 1 1 calc R . .
H97B H 0.1975 0.5771 0.0837 0.188 Uiso 1 1 calc R . .
C98 C 0.2709(13) 0.5152(14) 0.0678(14) 0.33(2) Uani 1 1 d . . .
H98A H 0.2974 0.5495 0.0616 0.501 Uiso 1 1 calc R . .
H98B H 0.2437 0.4989 0.0300 0.501 Uiso 1 1 calc R . .
H98C H 0.2988 0.4816 0.0899 0.501 Uiso 1 1 calc R . .
C99 C 0.1326(7) 0.4682(6) 0.0600(7) 0.117(5) Uani 1 1 d . . .
H99A H 0.1018 0.4399 0.0694 0.140 Uiso 1 1 calc R . .
H99B H 0.1570 0.4427 0.0404 0.140 Uiso 1 1 calc R . .
C100 C 0.0940(8) 0.5180(8) 0.0165(7) 0.165(7) Uani 1 1 d . . .
H10E H 0.0654 0.4973 -0.0185 0.247 Uiso 1 1 calc R . .
H10F H 0.1237 0.5456 0.0056 0.247 Uiso 1 1 calc R . .
H10G H 0.0683 0.5428 0.0346 0.247 Uiso 1 1 calc R . .
C101 C 0.2140(9) 0.4344(7) 0.1491(7) 0.154(6) Uani 1 1 d . . .
H10A H 0.2382 0.4149 0.1258 0.185 Uiso 1 1 calc R . .
H10B H 0.1812 0.4038 0.1517 0.185 Uiso 1 1 calc R . .
C102 C 0.2618(14) 0.4469(9) 0.2124(7) 0.301(19) Uani 1 1 d . . .
H10H H 0.2818 0.4074 0.2297 0.452 Uiso 1 1 calc R . .
H10I H 0.2381 0.4649 0.2364 0.452 Uiso 1 1 calc R . .
H10J H 0.2952 0.4763 0.2104 0.452 Uiso 1 1 calc R . .
C103 C 0.1433(11) 0.5284(7) 0.1512(7) 0.161(7) Uani 1 1 d . . .
H10C H 0.1217 0.5651 0.1281 0.193 Uiso 1 1 calc R . .
H10D H 0.1750 0.5443 0.1878 0.193 Uiso 1 1 calc R . .
C104 C 0.0915(16) 0.4878(12) 0.1670(12) 0.297(17) Uani 1 1 d . . .
H10K H 0.0703 0.5136 0.1887 0.446 Uiso 1 1 calc R . .
H10L H 0.1126 0.4521 0.1911 0.446 Uiso 1 1 calc R . .
H10M H 0.0593 0.4726 0.1311 0.446 Uiso 1 1 calc R . .
O18 O 0.0550(13) 0.0711(13) 0.4453(12) 0.094(9) Uiso 0.25 1 d PD . .
C105 C 0.1374(14) 0.0302(15) 0.5415(10) 0.055(5) Uiso 0.25 1 d PD . .
H10O H 0.1378 0.0745 0.5524 0.083 Uiso 0.25 1 calc PR . .
H10P H 0.1807 0.0175 0.5433 0.083 Uiso 0.25 1 calc PR . .
H10Q H 0.1234 0.0046 0.5686 0.083 Uiso 0.25 1 calc PR . .
C106 C 0.0906(11) 0.0210(12) 0.4793(10) 0.055(5) Uiso 0.25 1 d PD . .
C107 C 0.0938(15) -0.0454(10) 0.4672(14) 0.055(5) Uiso 0.25 1 d PD . .
H10S H 0.0652 -0.0545 0.4276 0.083 Uiso 0.25 1 calc PR . .
H10T H 0.0804 -0.0699 0.4953 0.083 Uiso 0.25 1 calc PR . .
H10U H 0.1381 -0.0565 0.4706 0.083 Uiso 0.25 1 calc PR . .


_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O9 2.211(5) . ?
Dy1 O1 2.212(5) . ?
Dy1 O13 2.229(5) . ?
Dy1 O5 2.269(5) . ?
Dy1 O6 2.586(5) . ?
Dy1 O14 2.622(5) . ?
Dy1 N1 2.662(6) . ?
Dy1 N5 2.679(6) . ?
Dy2 O7 2.221(6) . ?
Dy2 O15 2.224(6) . ?
Dy2 O11 2.223(5) . ?
Dy2 O3 2.257(5) . ?
Dy2 O4 2.596(6) . ?
Dy2 O12 2.632(5) . ?
Dy2 N4 2.651(6) . ?
Dy2 N8 2.657(7) . ?
N1 C8 1.294(9) . ?
N1 C9 1.429(10) . ?
N2 C15 1.280(9) . ?
N2 C12 1.428(10) . ?
N3 C30 1.270(9) . ?
N3 C31 1.421(9) . ?
N4 C37 1.287(10) . ?
N4 C34 1.427(9) . ?
N5 C52 1.303(9) . ?
N5 C53 1.442(9) . ?
N6 C59 1.250(9) . ?
N6 C56 1.427(9) . ?
N7 C74 1.261(10) . ?
N7 C75 1.417(10) . ?
N8 C81 1.289(10) . ?
N8 C78 1.436(10) . ?
N9 C91 1.434(14) . ?
N9 C89 1.492(13) . ?
N9 C93 1.518(13) . ?
N9 C95 1.542(14) . ?
N10 C99 1.487(14) . ?
N10 C103 1.502(18) . ?
N10 C97 1.489(18) . ?
N10 C101 1.506(15) . ?
O1 C1 1.290(9) . ?
O2 C2 1.350(11) . ?
O2 C7 1.435(14) . ?
O3 C16 1.317(8) . ?
O4 C21 1.373(9) . ?
O4 C22 1.415(10) . ?
O5 C23 1.310(8) . ?
O6 C24 1.390(9) . ?
O6 C29 1.408(10) . ?
O7 C38 1.289(10) . ?
O8 C43 1.380(12) . ?
O8 C44 1.429(15) . ?
O9 C45 1.282(10) . ?
O10 C46 1.385(11) . ?
O10 C51 1.426(12) . ?
O11 C60 1.305(8) . ?
O12 C65 1.379(9) . ?
O12 C66 1.432(9) . ?
O13 C67 1.321(9) . ?
O14 C68 1.382(9) . ?
O14 C73 1.410(9) . ?
O15 C82 1.293(11) . ?
O16 C87 1.374(12) . ?
O16 C88 1.419(11) . ?
C1 C2 1.433(12) . ?
C1 C6 1.407(12) . ?
C2 C3 1.351(13) . ?
C3 C4 1.346(16) . ?
C4 C5 1.370(15) . ?
C5 C6 1.405(13) . ?
C6 C8 1.434(12) . ?
C9 C14 1.390(11) . ?
C9 C10 1.374(11) . ?
C10 C11 1.384(11) . ?
C11 C12 1.377(10) . ?
C12 C13 1.379(11) . ?
C13 C14 1.378(11) . ?
C15 C17 1.446(11) . ?
C16 C17 1.413(10) . ?
C16 C21 1.427(11) . ?
C17 C18 1.395(11) . ?
C18 C19 1.358(12) . ?
C19 C20 1.388(12) . ?
C20 C21 1.359(11) . ?
C23 C28 1.410(10) . ?
C23 C24 1.408(10) . ?
C24 C25 1.371(11) . ?
C25 C26 1.383(12) . ?
C26 C27 1.356(11) . ?
C27 C28 1.401(11) . ?
C28 C30 1.440(10) . ?
C31 C32 1.392(10) . ?
C31 C36 1.382(10) . ?
C32 C33 1.379(10) . ?
C33 C34 1.370(10) . ?
C34 C35 1.383(10) . ?
C35 C36 1.384(11) . ?
C37 C39 1.461(12) . ?
C38 C39 1.393(13) . ?
C38 C43 1.427(12) . ?
C39 C40 1.425(13) . ?
C40 C41 1.359(15) . ?
C41 C42 1.377(17) . ?
C42 C43 1.346(14) . ?
C45 C50 1.415(12) . ?
C45 C46 1.422(11) . ?
C46 C47 1.400(13) . ?
C47 C48 1.364(13) . ?
C48 C49 1.378(13) . ?
C49 C50 1.409(12) . ?
C50 C52 1.431(11) . ?
C53 C58 1.379(10) . ?
C53 C54 1.390(10) . ?
C54 C55 1.367(10) . ?
C55 C56 1.376(11) . ?
C56 C57 1.411(10) . ?
C57 C58 1.371(10) . ?
C59 C61 1.446(10) . ?
C60 C61 1.402(10) . ?
C60 C65 1.433(10) . ?
C61 C62 1.400(11) . ?
C62 C63 1.370(11) . ?
C63 C64 1.391(12) . ?
C64 C65 1.401(10) . ?
C67 C72 1.394(11) . ?
C67 C68 1.409(11) . ?
C68 C69 1.381(11) . ?
C69 C70 1.407(12) . ?
C70 C71 1.354(11) . ?
C71 C72 1.409(11) . ?
C72 C74 1.451(11) . ?
C75 C80 1.374(11) . ?
C75 C76 1.374(11) . ?
C76 C77 1.368(12) . ?
C77 C78 1.391(11) . ?
C78 C79 1.379(11) . ?
C79 C80 1.391(11) . ?
C81 C83 1.434(12) . ?
C82 C83 1.405(13) . ?
C82 C87 1.431(13) . ?
C83 C84 1.407(13) . ?
C84 C85 1.370(14) . ?
C85 C86 1.389(15) . ?
C86 C87 1.345(14) . ?
C89 C90 1.512(16) . ?
C91 C92 1.59(2) . ?
C93 C94 1.520(16) . ?
C95 C96 1.520(18) . ?
C97 C98 1.66(3) . ?
C99 C100 1.511(18) . ?
C101 C102 1.54(2) . ?
C103 C104 1.55(3) . ?
O18 C106 1.39(4) . ?
C105 C106 1.505(19) . ?
C106 C107 1.426(19) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O9 Dy1 O1 85.4(2) . . ?
O9 Dy1 O13 104.8(2) . . ?
O1 Dy1 O13 137.43(19) . . ?
O9 Dy1 O5 135.23(19) . . ?
O1 Dy1 O5 101.99(19) . . ?
O13 Dy1 O5 98.90(17) . . ?
O9 Dy1 O6 77.74(19) . . ?
O1 Dy1 O6 72.04(19) . . ?
O13 Dy1 O6 150.19(18) . . ?
O5 Dy1 O6 63.51(17) . . ?
O9 Dy1 O14 72.43(19) . . ?
O1 Dy1 O14 80.97(18) . . ?
O13 Dy1 O14 64.03(17) . . ?
O5 Dy1 O14 152.09(17) . . ?
O6 Dy1 O14 140.99(16) . . ?
O9 Dy1 N1 138.67(19) . . ?
O1 Dy1 N1 70.8(2) . . ?
O13 Dy1 N1 75.17(19) . . ?
O5 Dy1 N1 83.82(18) . . ?
O6 Dy1 N1 122.81(19) . . ?
O14 Dy1 N1 70.84(18) . . ?
O9 Dy1 N5 71.24(19) . . ?
O1 Dy1 N5 143.33(19) . . ?
O13 Dy1 N5 77.30(18) . . ?
O5 Dy1 N5 77.83(18) . . ?
O6 Dy1 N5 75.53(18) . . ?
O14 Dy1 N5 116.32(18) . . ?
N1 Dy1 N5 143.91(19) . . ?
O7 Dy2 O15 85.2(2) . . ?
O7 Dy2 O11 137.23(19) . . ?
O15 Dy2 O11 101.2(2) . . ?
O7 Dy2 O3 102.6(2) . . ?
O15 Dy2 O3 137.2(2) . . ?
O11 Dy2 O3 100.64(18) . . ?
O7 Dy2 O4 71.6(2) . . ?
O15 Dy2 O4 80.0(2) . . ?
O11 Dy2 O4 151.08(19) . . ?
O3 Dy2 O4 63.60(17) . . ?
O7 Dy2 O12 78.07(19) . . ?
O15 Dy2 O12 72.9(2) . . ?
O11 Dy2 O12 64.17(17) . . ?
O3 Dy2 O12 149.83(18) . . ?
O4 Dy2 O12 140.63(17) . . ?
O7 Dy2 N4 71.1(2) . . ?
O15 Dy2 N4 139.6(2) . . ?
O11 Dy2 N4 77.66(19) . . ?
O3 Dy2 N4 81.12(18) . . ?
O4 Dy2 N4 120.13(19) . . ?
O12 Dy2 N4 70.47(19) . . ?
O7 Dy2 N8 140.3(2) . . ?
O15 Dy2 N8 71.0(2) . . ?
O11 Dy2 N8 79.8(2) . . ?
O3 Dy2 N8 77.3(2) . . ?
O4 Dy2 N8 73.2(2) . . ?
O12 Dy2 N8 121.6(2) . . ?
N4 Dy2 N8 145.1(2) . . ?
C8 N1 C9 115.9(7) . . ?
C8 N1 Dy1 124.2(5) . . ?
C9 N1 Dy1 117.9(5) . . ?
C15 N2 C12 120.7(7) . . ?
C30 N3 C31 120.6(6) . . ?
C37 N4 C34 113.5(7) . . ?
C37 N4 Dy2 125.4(5) . . ?
C34 N4 Dy2 119.4(5) . . ?
C52 N5 C53 115.3(6) . . ?
C52 N5 Dy1 125.7(5) . . ?
C53 N5 Dy1 118.9(5) . . ?
C59 N6 C56 122.3(7) . . ?
C74 N7 C75 121.4(7) . . ?
C81 N8 C78 114.5(7) . . ?
C81 N8 Dy2 125.9(6) . . ?
C78 N8 Dy2 119.2(5) . . ?
C91 N9 C89 114.6(9) . . ?
C91 N9 C93 119.1(11) . . ?
C89 N9 C93 104.4(8) . . ?
C91 N9 C95 104.6(9) . . ?
C89 N9 C95 110.8(9) . . ?
C93 N9 C95 102.7(9) . . ?
C99 N10 C103 110.5(11) . . ?
C99 N10 C97 111.2(10) . . ?
C103 N10 C97 103.8(12) . . ?
C99 N10 C101 104.9(10) . . ?
C103 N10 C101 112.4(11) . . ?
C97 N10 C101 114.3(12) . . ?
C1 O1 Dy1 145.2(5) . . ?
C2 O2 C7 120.5(10) . . ?
C16 O3 Dy2 125.6(5) . . ?
C21 O4 C22 118.0(7) . . ?
C21 O4 Dy2 114.8(4) . . ?
C22 O4 Dy2 125.9(5) . . ?
C23 O5 Dy1 123.6(4) . . ?
C24 O6 C29 118.6(6) . . ?
C24 O6 Dy1 113.8(4) . . ?
C29 O6 Dy1 126.9(5) . . ?
C38 O7 Dy2 143.8(5) . . ?
C43 O8 C44 113.9(9) . . ?
C45 O9 Dy1 146.7(5) . . ?
C46 O10 C51 115.2(7) . . ?
C60 O11 Dy2 127.5(5) . . ?
C65 O12 C66 119.5(6) . . ?
C65 O12 Dy2 113.3(4) . . ?
C66 O12 Dy2 127.3(5) . . ?
C67 O13 Dy1 128.3(5) . . ?
C68 O14 C73 118.9(6) . . ?
C68 O14 Dy1 114.6(4) . . ?
C73 O14 Dy1 126.4(5) . . ?
C82 O15 Dy2 146.2(6) . . ?
C87 O16 C88 116.8(9) . . ?
O1 C1 C2 119.8(8) . . ?
O1 C1 C6 122.5(8) . . ?
C2 C1 C6 117.7(8) . . ?
O2 C2 C3 125.1(9) . . ?
O2 C2 C1 115.2(8) . . ?
C3 C2 C1 119.6(10) . . ?
C4 C3 C2 123.1(10) . . ?
C3 C4 C5 119.2(10) . . ?
C4 C5 C6 121.3(11) . . ?
C1 C6 C5 118.9(9) . . ?
C1 C6 C8 123.8(8) . . ?
C5 C6 C8 117.1(9) . . ?
N1 C8 C6 128.4(8) . . ?
C14 C9 C10 117.9(8) . . ?
C14 C9 N1 119.4(7) . . ?
C10 C9 N1 122.7(7) . . ?
C11 C10 C9 121.1(7) . . ?
C10 C11 C12 121.0(7) . . ?
C13 C12 C11 118.1(8) . . ?
C13 C12 N2 125.3(7) . . ?
C11 C12 N2 116.6(7) . . ?
C12 C13 C14 121.1(8) . . ?
C9 C14 C13 120.8(7) . . ?
N2 C15 C17 122.1(7) . . ?
O3 C16 C17 124.3(7) . . ?
O3 C16 C21 118.8(7) . . ?
C17 C16 C21 116.9(7) . . ?
C18 C17 C16 119.8(7) . . ?
C18 C17 C15 121.7(7) . . ?
C16 C17 C15 118.3(7) . . ?
C19 C18 C17 121.0(8) . . ?
C20 C19 C18 120.9(8) . . ?
C21 C20 C19 119.5(8) . . ?
C20 C21 O4 126.3(8) . . ?
C20 C21 C16 122.0(8) . . ?
O4 C21 C16 111.8(7) . . ?
O5 C23 C28 123.0(7) . . ?
O5 C23 C24 119.6(7) . . ?
C28 C23 C24 117.4(7) . . ?
C25 C24 O6 126.6(7) . . ?
C25 C24 C23 122.0(7) . . ?
O6 C24 C23 111.5(6) . . ?
C24 C25 C26 119.6(8) . . ?
C27 C26 C25 120.1(8) . . ?
C26 C27 C28 121.6(8) . . ?
C27 C28 C23 119.1(7) . . ?
C27 C28 C30 121.2(7) . . ?
C23 C28 C30 119.6(7) . . ?
N3 C30 C28 124.3(7) . . ?
C32 C31 C36 118.3(7) . . ?
C32 C31 N3 115.5(7) . . ?
C36 C31 N3 126.0(7) . . ?
C33 C32 C31 120.1(7) . . ?
C34 C33 C32 122.0(7) . . ?
C33 C34 C35 117.8(7) . . ?
C33 C34 N4 122.9(7) . . ?
C35 C34 N4 119.2(7) . . ?
C36 C35 C34 121.2(7) . . ?
C35 C36 C31 120.6(7) . . ?
N4 C37 C39 127.9(8) . . ?
O7 C38 C39 123.0(8) . . ?
O7 C38 C43 120.4(9) . . ?
C39 C38 C43 116.6(9) . . ?
C38 C39 C40 120.4(9) . . ?
C38 C39 C37 124.0(8) . . ?
C40 C39 C37 115.5(9) . . ?
C41 C40 C39 120.0(11) . . ?
C40 C41 C42 120.0(12) . . ?
C43 C42 C41 121.2(10) . . ?
C42 C43 O8 118.5(9) . . ?
C42 C43 C38 121.8(10) . . ?
O8 C43 C38 119.5(9) . . ?
O9 C45 C50 123.2(7) . . ?
O9 C45 C46 120.0(8) . . ?
C50 C45 C46 116.8(8) . . ?
C47 C46 O10 118.5(8) . . ?
C47 C46 C45 120.4(9) . . ?
O10 C46 C45 121.0(8) . . ?
C48 C47 C46 121.8(9) . . ?
C47 C48 C49 119.5(9) . . ?
C50 C49 C48 120.7(9) . . ?
C49 C50 C45 120.9(8) . . ?
C49 C50 C52 115.1(8) . . ?
C45 C50 C52 124.0(7) . . ?
N5 C52 C50 128.8(7) . . ?
C58 C53 C54 118.7(7) . . ?
C58 C53 N5 119.6(7) . . ?
C54 C53 N5 121.7(7) . . ?
C55 C54 C53 120.5(7) . . ?
C54 C55 C56 121.8(7) . . ?
C55 C56 C57 117.5(7) . . ?
C55 C56 N6 118.0(7) . . ?
C57 C56 N6 124.4(7) . . ?
C58 C57 C56 120.7(7) . . ?
C53 C58 C57 120.9(7) . . ?
N6 C59 C61 124.5(7) . . ?
O11 C60 C61 124.6(7) . . ?
O11 C60 C65 119.1(7) . . ?
C61 C60 C65 116.3(7) . . ?
C62 C61 C60 119.6(7) . . ?
C62 C61 C59 121.7(7) . . ?
C60 C61 C59 118.5(7) . . ?
C63 C62 C61 122.8(8) . . ?
C64 C63 C62 120.1(8) . . ?
C65 C64 C63 117.7(8) . . ?
C64 C65 O12 124.0(7) . . ?
C64 C65 C60 123.4(8) . . ?
O12 C65 C60 112.6(6) . . ?
O13 C67 C72 123.0(7) . . ?
O13 C67 C68 119.0(7) . . ?
C72 C67 C68 118.0(7) . . ?
C69 C68 O14 124.9(8) . . ?
C69 C68 C67 122.0(8) . . ?
O14 C68 C67 113.1(7) . . ?
C68 C69 C70 119.0(8) . . ?
C71 C70 C69 119.5(8) . . ?
C70 C71 C72 122.2(8) . . ?
C67 C72 C71 119.2(7) . . ?
C67 C72 C74 119.8(7) . . ?
C71 C72 C74 121.0(8) . . ?
N7 C74 C72 123.4(7) . . ?
C80 C75 C76 118.2(8) . . ?
C80 C75 N7 124.9(7) . . ?
C76 C75 N7 116.8(7) . . ?
C77 C76 C75 120.5(8) . . ?
C76 C77 C78 122.1(8) . . ?
C79 C78 C77 117.4(8) . . ?
C79 C78 N8 119.1(7) . . ?
C77 C78 N8 123.5(8) . . ?
C78 C79 C80 120.2(8) . . ?
C75 C80 C79 121.5(8) . . ?
N8 C81 C83 128.9(9) . . ?
O15 C82 C83 122.3(8) . . ?
O15 C82 C87 119.8(10) . . ?
C83 C82 C87 117.9(10) . . ?
C82 C83 C84 119.1(9) . . ?
C82 C83 C81 124.2(8) . . ?
C84 C83 C81 116.7(10) . . ?
C85 C84 C83 121.4(11) . . ?
C84 C85 C86 119.2(11) . . ?
C87 C86 C85 121.5(10) . . ?
C86 C87 O16 126.3(10) . . ?
C86 C87 C82 120.9(11) . . ?
O16 C87 C82 112.7(9) . . ?
N9 C89 C90 113.3(10) . . ?
N9 C91 C92 108.3(12) . . ?
N9 C93 C94 114.8(11) . . ?
C96 C95 N9 117.6(10) . . ?
N10 C97 C98 114.3(14) . . ?
N10 C99 C100 116.0(11) . . ?
N10 C101 C102 114.9(12) . . ?
N10 C103 C104 114.1(13) . . ?
O18 C106 C107 132.2(18) . . ?
O18 C106 C105 122.6(17) . . ?
C107 C106 C105 105(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O9 Dy1 N1 C8 -36.5(8) . . . . ?
O1 Dy1 N1 C8 21.8(6) . . . . ?
O13 Dy1 N1 C8 -132.2(7) . . . . ?
O5 Dy1 N1 C8 126.8(7) . . . . ?
O6 Dy1 N1 C8 74.0(7) . . . . ?
O14 Dy1 N1 C8 -65.0(6) . . . . ?
N5 Dy1 N1 C8 -173.7(6) . . . . ?
O9 Dy1 N1 C9 126.5(5) . . . . ?
O1 Dy1 N1 C9 -175.1(5) . . . . ?
O13 Dy1 N1 C9 30.8(5) . . . . ?
O5 Dy1 N1 C9 -70.1(5) . . . . ?
O6 Dy1 N1 C9 -123.0(5) . . . . ?
O14 Dy1 N1 C9 98.0(5) . . . . ?
N5 Dy1 N1 C9 -10.6(7) . . . . ?
O7 Dy2 N4 C37 17.9(6) . . . . ?
O15 Dy2 N4 C37 -39.6(8) . . . . ?
O11 Dy2 N4 C37 -132.5(7) . . . . ?
O3 Dy2 N4 C37 124.5(7) . . . . ?
O4 Dy2 N4 C37 72.2(7) . . . . ?
O12 Dy2 N4 C37 -65.8(7) . . . . ?
N8 Dy2 N4 C37 176.6(6) . . . . ?
O7 Dy2 N4 C34 -177.7(6) . . . . ?
O15 Dy2 N4 C34 124.9(5) . . . . ?
O11 Dy2 N4 C34 32.0(5) . . . . ?
O3 Dy2 N4 C34 -71.1(5) . . . . ?
O4 Dy2 N4 C34 -123.4(5) . . . . ?
O12 Dy2 N4 C34 98.7(5) . . . . ?
N8 Dy2 N4 C34 -19.0(7) . . . . ?
O9 Dy1 N5 C52 -1.9(6) . . . . ?
O1 Dy1 N5 C52 -55.3(7) . . . . ?
O13 Dy1 N5 C52 108.8(6) . . . . ?
O5 Dy1 N5 C52 -149.1(6) . . . . ?
O6 Dy1 N5 C52 -83.6(6) . . . . ?
O14 Dy1 N5 C52 56.5(6) . . . . ?
N1 Dy1 N5 C52 149.8(5) . . . . ?
O9 Dy1 N5 C53 176.6(5) . . . . ?
O1 Dy1 N5 C53 123.2(5) . . . . ?
O13 Dy1 N5 C53 -72.8(5) . . . . ?
O5 Dy1 N5 C53 29.4(5) . . . . ?
O6 Dy1 N5 C53 94.9(5) . . . . ?
O14 Dy1 N5 C53 -125.0(5) . . . . ?
N1 Dy1 N5 C53 -31.7(6) . . . . ?
O7 Dy2 N8 C81 -45.6(8) . . . . ?
O15 Dy2 N8 C81 10.8(7) . . . . ?
O11 Dy2 N8 C81 116.5(7) . . . . ?
O3 Dy2 N8 C81 -140.0(7) . . . . ?
O4 Dy2 N8 C81 -74.1(7) . . . . ?
O12 Dy2 N8 C81 65.6(7) . . . . ?
N4 Dy2 N8 C81 166.9(6) . . . . ?
O7 Dy2 N8 C78 126.2(6) . . . . ?
O15 Dy2 N8 C78 -177.4(6) . . . . ?
O11 Dy2 N8 C78 -71.7(6) . . . . ?
O3 Dy2 N8 C78 31.8(5) . . . . ?
O4 Dy2 N8 C78 97.7(6) . . . . ?
O12 Dy2 N8 C78 -122.6(5) . . . . ?
N4 Dy2 N8 C78 -21.3(7) . . . . ?
O9 Dy1 O1 C1 124.1(9) . . . . ?
O13 Dy1 O1 C1 17.2(10) . . . . ?
O5 Dy1 O1 C1 -100.5(9) . . . . ?
O6 Dy1 O1 C1 -157.3(9) . . . . ?
O14 Dy1 O1 C1 51.2(9) . . . . ?
N1 Dy1 O1 C1 -21.5(8) . . . . ?
N5 Dy1 O1 C1 173.8(8) . . . . ?
O7 Dy2 O3 C16 -82.2(6) . . . . ?
O15 Dy2 O3 C16 14.4(7) . . . . ?
O11 Dy2 O3 C16 134.0(6) . . . . ?
O4 Dy2 O3 C16 -20.3(5) . . . . ?
O12 Dy2 O3 C16 -170.0(5) . . . . ?
N4 Dy2 O3 C16 -150.4(6) . . . . ?
N8 Dy2 O3 C16 57.1(6) . . . . ?
O7 Dy2 O4 C21 134.0(6) . . . . ?
O15 Dy2 O4 C21 -137.8(6) . . . . ?
O11 Dy2 O4 C21 -42.7(7) . . . . ?
O3 Dy2 O4 C21 19.1(5) . . . . ?
O12 Dy2 O4 C21 175.5(5) . . . . ?
N4 Dy2 O4 C21 79.9(6) . . . . ?
N8 Dy2 O4 C21 -64.8(5) . . . . ?
O7 Dy2 O4 C22 -59.6(8) . . . . ?
O15 Dy2 O4 C22 28.6(8) . . . . ?
O11 Dy2 O4 C22 123.7(8) . . . . ?
O3 Dy2 O4 C22 -174.5(8) . . . . ?
O12 Dy2 O4 C22 -18.0(9) . . . . ?
N4 Dy2 O4 C22 -113.6(8) . . . . ?
N8 Dy2 O4 C22 101.7(8) . . . . ?
O9 Dy1 O5 C23 8.2(6) . . . . ?
O1 Dy1 O5 C23 -87.5(5) . . . . ?
O13 Dy1 O5 C23 129.9(5) . . . . ?
O6 Dy1 O5 C23 -24.7(5) . . . . ?
O14 Dy1 O5 C23 179.2(5) . . . . ?
N1 Dy1 O5 C23 -156.3(5) . . . . ?
N5 Dy1 O5 C23 55.0(5) . . . . ?
O9 Dy1 O6 C24 -134.4(5) . . . . ?
O1 Dy1 O6 C24 136.4(5) . . . . ?
O13 Dy1 O6 C24 -36.0(7) . . . . ?
O5 Dy1 O6 C24 22.5(5) . . . . ?
O14 Dy1 O6 C24 -175.1(4) . . . . ?
N1 Dy1 O6 C24 84.8(5) . . . . ?
N5 Dy1 O6 C24 -60.9(5) . . . . ?
O9 Dy1 O6 C29 36.2(7) . . . . ?
O1 Dy1 O6 C29 -52.9(7) . . . . ?
O13 Dy1 O6 C29 134.6(7) . . . . ?
O5 Dy1 O6 C29 -166.8(8) . . . . ?
O14 Dy1 O6 C29 -4.4(9) . . . . ?
N1 Dy1 O6 C29 -104.5(7) . . . . ?
N5 Dy1 O6 C29 109.7(8) . . . . ?
O15 Dy2 O7 C38 120.8(9) . . . . ?
O11 Dy2 O7 C38 19.4(11) . . . . ?
O3 Dy2 O7 C38 -101.8(9) . . . . ?
O4 Dy2 O7 C38 -158.2(10) . . . . ?
O12 Dy2 O7 C38 47.3(9) . . . . ?
N4 Dy2 O7 C38 -25.9(9) . . . . ?
N8 Dy2 O7 C38 173.0(8) . . . . ?
O1 Dy1 O9 C45 159.3(10) . . . . ?
O13 Dy1 O9 C45 -62.7(10) . . . . ?
O5 Dy1 O9 C45 56.8(10) . . . . ?
O6 Dy1 O9 C45 86.7(10) . . . . ?
O14 Dy1 O9 C45 -118.8(10) . . . . ?
N1 Dy1 O9 C45 -147.0(9) . . . . ?
N5 Dy1 O9 C45 8.0(9) . . . . ?
O7 Dy2 O11 C60 14.3(7) . . . . ?
O15 Dy2 O11 C60 -80.8(6) . . . . ?
O3 Dy2 O11 C60 136.2(6) . . . . ?
O4 Dy2 O11 C60 -170.3(5) . . . . ?
O12 Dy2 O11 C60 -16.2(6) . . . . ?
N4 Dy2 O11 C60 57.9(6) . . . . ?
N8 Dy2 O11 C60 -149.0(6) . . . . ?
O7 Dy2 O12 C65 -144.8(5) . . . . ?
O15 Dy2 O12 C65 126.6(5) . . . . ?
O11 Dy2 O12 C65 14.6(5) . . . . ?
O3 Dy2 O12 C65 -50.3(7) . . . . ?
O4 Dy2 O12 C65 175.2(4) . . . . ?
N4 Dy2 O12 C65 -70.8(5) . . . . ?
N8 Dy2 O12 C65 72.7(5) . . . . ?
O7 Dy2 O12 C66 35.4(7) . . . . ?
O15 Dy2 O12 C66 -53.2(7) . . . . ?
O11 Dy2 O12 C66 -165.2(8) . . . . ?
O3 Dy2 O12 C66 129.9(7) . . . . ?
O4 Dy2 O12 C66 -4.7(8) . . . . ?
N4 Dy2 O12 C66 109.4(7) . . . . ?
N8 Dy2 O12 C66 -107.1(7) . . . . ?
O9 Dy1 O13 C67 -71.4(6) . . . . ?
O1 Dy1 O13 C67 28.2(7) . . . . ?
O5 Dy1 O13 C67 146.9(6) . . . . ?
O6 Dy1 O13 C67 -162.5(5) . . . . ?
O14 Dy1 O13 C67 -9.8(5) . . . . ?
N1 Dy1 O13 C67 65.8(6) . . . . ?
N5 Dy1 O13 C67 -137.8(6) . . . . ?
O9 Dy1 O14 C68 124.3(5) . . . . ?
O1 Dy1 O14 C68 -147.7(5) . . . . ?
O13 Dy1 O14 C68 7.4(4) . . . . ?
O5 Dy1 O14 C68 -49.1(7) . . . . ?
O6 Dy1 O14 C68 166.1(4) . . . . ?
N1 Dy1 O14 C68 -75.0(5) . . . . ?
N5 Dy1 O14 C68 66.5(5) . . . . ?
O9 Dy1 O14 C73 -51.8(7) . . . . ?
O1 Dy1 O14 C73 36.3(7) . . . . ?
O13 Dy1 O14 C73 -168.7(7) . . . . ?
O5 Dy1 O14 C73 134.9(7) . . . . ?
O6 Dy1 O14 C73 -9.9(8) . . . . ?
N1 Dy1 O14 C73 108.9(7) . . . . ?
N5 Dy1 O14 C73 -109.6(7) . . . . ?
O7 Dy2 O15 C82 135.2(11) . . . . ?
O11 Dy2 O15 C82 -87.6(11) . . . . ?
O3 Dy2 O15 C82 31.9(12) . . . . ?
O4 Dy2 O15 C82 63.0(10) . . . . ?
O12 Dy2 O15 C82 -145.8(11) . . . . ?
N4 Dy2 O15 C82 -171.6(9) . . . . ?
N8 Dy2 O15 C82 -12.6(10) . . . . ?
Dy1 O1 C1 C2 -168.8(6) . . . . ?
Dy1 O1 C1 C6 11.7(14) . . . . ?
C7 O2 C2 C3 19.5(16) . . . . ?
C7 O2 C2 C1 -159.4(10) . . . . ?
O1 C1 C2 O2 -3.7(12) . . . . ?
C6 C1 C2 O2 175.8(8) . . . . ?
O1 C1 C2 C3 177.3(9) . . . . ?
C6 C1 C2 C3 -3.2(13) . . . . ?
O2 C2 C3 C4 -178.6(11) . . . . ?
C1 C2 C3 C4 0.2(17) . . . . ?
C2 C3 C4 C5 2(2) . . . . ?
C3 C4 C5 C6 -2(2) . . . . ?
O1 C1 C6 C5 -176.9(9) . . . . ?
C2 C1 C6 C5 3.6(13) . . . . ?
O1 C1 C6 C8 8.8(13) . . . . ?
C2 C1 C6 C8 -170.7(8) . . . . ?
C4 C5 C6 C1 -1.2(17) . . . . ?
C4 C5 C6 C8 173.5(11) . . . . ?
C9 N1 C8 C6 177.6(8) . . . . ?
Dy1 N1 C8 C6 -19.0(12) . . . . ?
C1 C6 C8 N1 -0.6(15) . . . . ?
C5 C6 C8 N1 -175.0(10) . . . . ?
C8 N1 C9 C14 -141.1(8) . . . . ?
Dy1 N1 C9 C14 54.4(9) . . . . ?
C8 N1 C9 C10 39.9(11) . . . . ?
Dy1 N1 C9 C10 -124.5(7) . . . . ?
C14 C9 C10 C11 0.4(13) . . . . ?
N1 C9 C10 C11 179.3(7) . . . . ?
C9 C10 C11 C12 -0.9(13) . . . . ?
C10 C11 C12 C13 0.5(13) . . . . ?
C10 C11 C12 N2 -177.9(8) . . . . ?
C15 N2 C12 C13 -13.7(13) . . . . ?
C15 N2 C12 C11 164.5(8) . . . . ?
C11 C12 C13 C14 0.3(13) . . . . ?
N2 C12 C13 C14 178.5(8) . . . . ?
C10 C9 C14 C13 0.4(13) . . . . ?
N1 C9 C14 C13 -178.6(8) . . . . ?
C12 C13 C14 C9 -0.8(14) . . . . ?
C12 N2 C15 C17 -176.1(7) . . . . ?
Dy2 O3 C16 C17 -160.3(6) . . . . ?
Dy2 O3 C16 C21 19.7(10) . . . . ?
O3 C16 C17 C18 179.0(7) . . . . ?
C21 C16 C17 C18 -1.0(11) . . . . ?
O3 C16 C17 C15 4.5(11) . . . . ?
C21 C16 C17 C15 -175.4(7) . . . . ?
N2 C15 C17 C18 14.8(12) . . . . ?
N2 C15 C17 C16 -170.8(7) . . . . ?
C16 C17 C18 C19 1.2(13) . . . . ?
C15 C17 C18 C19 175.5(8) . . . . ?
C17 C18 C19 C20 -0.1(15) . . . . ?
C18 C19 C20 C21 -1.2(15) . . . . ?
C19 C20 C21 O4 179.6(9) . . . . ?
C19 C20 C21 C16 1.4(14) . . . . ?
C22 O4 C21 C20 -3.0(14) . . . . ?
Dy2 O4 C21 C20 164.6(8) . . . . ?
C22 O4 C21 C16 175.4(8) . . . . ?
Dy2 O4 C21 C16 -17.0(9) . . . . ?
O3 C16 C21 C20 179.7(8) . . . . ?
C17 C16 C21 C20 -0.3(12) . . . . ?
O3 C16 C21 O4 1.3(11) . . . . ?
C17 C16 C21 O4 -178.8(7) . . . . ?
Dy1 O5 C23 C28 -155.7(5) . . . . ?
Dy1 O5 C23 C24 25.0(9) . . . . ?
C29 O6 C24 C25 -11.9(13) . . . . ?
Dy1 O6 C24 C25 159.6(7) . . . . ?
C29 O6 C24 C23 169.1(8) . . . . ?
Dy1 O6 C24 C23 -19.4(8) . . . . ?
O5 C23 C24 C25 -179.3(8) . . . . ?
C28 C23 C24 C25 1.4(12) . . . . ?
O5 C23 C24 O6 -0.2(10) . . . . ?
C28 C23 C24 O6 -179.6(6) . . . . ?
O6 C24 C25 C26 -177.6(8) . . . . ?
C23 C24 C25 C26 1.2(14) . . . . ?
C24 C25 C26 C27 -2.9(15) . . . . ?
C25 C26 C27 C28 2.0(14) . . . . ?
C26 C27 C28 C23 0.7(12) . . . . ?
C26 C27 C28 C30 177.8(8) . . . . ?
O5 C23 C28 C27 178.4(7) . . . . ?
C24 C23 C28 C27 -2.3(11) . . . . ?
O5 C23 C28 C30 1.2(11) . . . . ?
C24 C23 C28 C30 -179.5(7) . . . . ?
C31 N3 C30 C28 -174.5(7) . . . . ?
C27 C28 C30 N3 10.2(12) . . . . ?
C23 C28 C30 N3 -172.6(8) . . . . ?
C30 N3 C31 C32 169.3(7) . . . . ?
C30 N3 C31 C36 -5.9(13) . . . . ?
C36 C31 C32 C33 0.2(12) . . . . ?
N3 C31 C32 C33 -175.4(7) . . . . ?
C31 C32 C33 C34 -0.6(12) . . . . ?
C32 C33 C34 C35 1.2(12) . . . . ?
C32 C33 C34 N4 178.1(7) . . . . ?
C37 N4 C34 C33 46.1(11) . . . . ?
Dy2 N4 C34 C33 -120.1(7) . . . . ?
C37 N4 C34 C35 -137.1(8) . . . . ?
Dy2 N4 C34 C35 56.7(9) . . . . ?
C33 C34 C35 C36 -1.5(13) . . . . ?
N4 C34 C35 C36 -178.5(8) . . . . ?
C34 C35 C36 C31 1.2(14) . . . . ?
C32 C31 C36 C35 -0.5(13) . . . . ?
N3 C31 C36 C35 174.6(8) . . . . ?
C34 N4 C37 C39 -177.6(8) . . . . ?
Dy2 N4 C37 C39 -12.4(13) . . . . ?
Dy2 O7 C38 C39 22.3(15) . . . . ?
Dy2 O7 C38 C43 -158.9(7) . . . . ?
O7 C38 C39 C40 178.1(10) . . . . ?
C43 C38 C39 C40 -0.7(15) . . . . ?
O7 C38 C39 C37 1.0(15) . . . . ?
C43 C38 C39 C37 -177.8(9) . . . . ?
N4 C37 C39 C38 -1.5(16) . . . . ?
N4 C37 C39 C40 -178.7(10) . . . . ?
C38 C39 C40 C41 0.2(19) . . . . ?
C37 C39 C40 C41 177.5(13) . . . . ?
C39 C40 C41 C42 1(2) . . . . ?
C40 C41 C42 C43 -2(2) . . . . ?
C41 C42 C43 O8 -173.6(13) . . . . ?
C41 C42 C43 C38 1(2) . . . . ?
C44 O8 C43 C42 -111.7(12) . . . . ?
C44 O8 C43 C38 73.2(12) . . . . ?
O7 C38 C43 C42 -178.9(10) . . . . ?
C39 C38 C43 C42 0.0(15) . . . . ?
O7 C38 C43 O8 -4.0(14) . . . . ?
C39 C38 C43 O8 174.9(9) . . . . ?
Dy1 O9 C45 C50 -9.1(15) . . . . ?
Dy1 O9 C45 C46 169.5(7) . . . . ?
C51 O10 C46 C47 -119.9(9) . . . . ?
C51 O10 C46 C45 64.7(11) . . . . ?
O9 C45 C46 C47 -176.6(8) . . . . ?
C50 C45 C46 C47 2.1(12) . . . . ?
O9 C45 C46 O10 -1.2(13) . . . . ?
C50 C45 C46 O10 177.5(8) . . . . ?
O10 C46 C47 C48 -177.0(10) . . . . ?
C45 C46 C47 C48 -1.6(15) . . . . ?
C46 C47 C48 C49 0.2(17) . . . . ?
C47 C48 C49 C50 0.6(16) . . . . ?
C48 C49 C50 C45 0.0(14) . . . . ?
C48 C49 C50 C52 176.4(9) . . . . ?
O9 C45 C50 C49 177.3(8) . . . . ?
C46 C45 C50 C49 -1.4(12) . . . . ?
O9 C45 C50 C52 1.3(13) . . . . ?
C46 C45 C50 C52 -177.4(8) . . . . ?
C53 N5 C52 C50 -179.9(7) . . . . ?
Dy1 N5 C52 C50 -1.4(12) . . . . ?
C49 C50 C52 N5 -173.5(8) . . . . ?
C45 C50 C52 N5 2.8(14) . . . . ?
C52 N5 C53 C58 -135.7(8) . . . . ?
Dy1 N5 C53 C58 45.7(9) . . . . ?
C52 N5 C53 C54 45.8(10) . . . . ?
Dy1 N5 C53 C54 -132.8(6) . . . . ?
C58 C53 C54 C55 1.0(12) . . . . ?
N5 C53 C54 C55 179.5(7) . . . . ?
C53 C54 C55 C56 -0.1(13) . . . . ?
C54 C55 C56 C57 -1.0(12) . . . . ?
C54 C55 C56 N6 -178.1(7) . . . . ?
C59 N6 C56 C55 -169.5(8) . . . . ?
C59 N6 C56 C57 13.6(12) . . . . ?
C55 C56 C57 C58 1.2(12) . . . . ?
N6 C56 C57 C58 178.1(7) . . . . ?
C54 C53 C58 C57 -0.8(12) . . . . ?
N5 C53 C58 C57 -179.3(7) . . . . ?
C56 C57 C58 C53 -0.4(12) . . . . ?
C56 N6 C59 C61 -172.9(7) . . . . ?
Dy2 O11 C60 C61 -162.6(6) . . . . ?
Dy2 O11 C60 C65 15.9(10) . . . . ?
O11 C60 C61 C62 -179.3(7) . . . . ?
C65 C60 C61 C62 2.2(11) . . . . ?
O11 C60 C61 C59 5.5(12) . . . . ?
C65 C60 C61 C59 -173.0(7) . . . . ?
N6 C59 C61 C62 -3.3(13) . . . . ?
N6 C59 C61 C60 171.9(8) . . . . ?
C60 C61 C62 C63 -2.7(13) . . . . ?
C59 C61 C62 C63 172.4(8) . . . . ?
C61 C62 C63 C64 1.5(13) . . . . ?
C62 C63 C64 C65 0.1(13) . . . . ?
C63 C64 C65 O12 179.1(8) . . . . ?
C63 C64 C65 C60 -0.5(12) . . . . ?
C66 O12 C65 C64 -12.7(12) . . . . ?
Dy2 O12 C65 C64 167.4(6) . . . . ?
C66 O12 C65 C60 166.9(8) . . . . ?
Dy2 O12 C65 C60 -12.9(8) . . . . ?
O11 C60 C65 C64 -179.3(7) . . . . ?
C61 C60 C65 C64 -0.7(11) . . . . ?
O11 C60 C65 O12 1.0(10) . . . . ?
C61 C60 C65 O12 179.6(7) . . . . ?
Dy1 O13 C67 C72 -168.7(5) . . . . ?
Dy1 O13 C67 C68 11.1(10) . . . . ?
C73 O14 C68 C69 -7.3(11) . . . . ?
Dy1 O14 C68 C69 176.3(6) . . . . ?
C73 O14 C68 C67 171.1(7) . . . . ?
Dy1 O14 C68 C67 -5.3(8) . . . . ?
O13 C67 C68 C69 176.3(7) . . . . ?
C72 C67 C68 C69 -3.8(11) . . . . ?
O13 C67 C68 O14 -2.1(10) . . . . ?
C72 C67 C68 O14 177.7(7) . . . . ?
O14 C68 C69 C70 -179.3(7) . . . . ?
C67 C68 C69 C70 2.4(12) . . . . ?
C68 C69 C70 C71 -0.6(13) . . . . ?
C69 C70 C71 C72 0.3(13) . . . . ?
O13 C67 C72 C71 -176.7(7) . . . . ?
C68 C67 C72 C71 3.4(11) . . . . ?
O13 C67 C72 C74 4.2(12) . . . . ?
C68 C67 C72 C74 -175.6(7) . . . . ?
C70 C71 C72 C67 -1.8(12) . . . . ?
C70 C71 C72 C74 177.2(8) . . . . ?
C75 N7 C74 C72 -175.2(7) . . . . ?
C67 C72 C74 N7 -173.3(8) . . . . ?
C71 C72 C74 N7 7.7(13) . . . . ?
C74 N7 C75 C80 -20.5(13) . . . . ?
C74 N7 C75 C76 161.0(8) . . . . ?
C80 C75 C76 C77 2.2(13) . . . . ?
N7 C75 C76 C77 -179.3(8) . . . . ?
C75 C76 C77 C78 -1.1(14) . . . . ?
C76 C77 C78 C79 0.5(14) . . . . ?
C76 C77 C78 N8 179.8(8) . . . . ?
C81 N8 C78 C79 -132.5(9) . . . . ?
Dy2 N8 C78 C79 54.8(9) . . . . ?
C81 N8 C78 C77 48.1(11) . . . . ?
Dy2 N8 C78 C77 -124.6(8) . . . . ?
C77 C78 C79 C80 -1.0(13) . . . . ?
N8 C78 C79 C80 179.6(8) . . . . ?
C76 C75 C80 C79 -2.7(13) . . . . ?
N7 C75 C80 C79 178.8(8) . . . . ?
C78 C79 C80 C75 2.2(14) . . . . ?
C78 N8 C81 C83 179.2(9) . . . . ?
Dy2 N8 C81 C83 -8.6(13) . . . . ?
Dy2 O15 C82 C83 8.4(16) . . . . ?
Dy2 O15 C82 C87 -171.9(7) . . . . ?
O15 C82 C83 C84 -177.6(9) . . . . ?
C87 C82 C83 C84 2.7(13) . . . . ?
O15 C82 C83 C81 3.5(14) . . . . ?
C87 C82 C83 C81 -176.2(9) . . . . ?
N8 C81 C83 C82 -1.0(16) . . . . ?
N8 C81 C83 C84 -179.9(9) . . . . ?
C82 C83 C84 C85 -2.2(15) . . . . ?
C81 C83 C84 C85 176.8(10) . . . . ?
C83 C84 C85 C86 -0.3(17) . . . . ?
C84 C85 C86 C87 2.3(18) . . . . ?
C85 C86 C87 O16 -177.4(11) . . . . ?
C85 C86 C87 C82 -1.8(17) . . . . ?
C88 O16 C87 C86 -4.9(16) . . . . ?
C88 O16 C87 C82 179.1(10) . . . . ?
O15 C82 C87 C86 179.5(9) . . . . ?
C83 C82 C87 C86 -0.8(14) . . . . ?
O15 C82 C87 O16 -4.3(13) . . . . ?
C83 C82 C87 O16 175.4(9) . . . . ?
C91 N9 C89 C90 -49.6(19) . . . . ?
C93 N9 C89 C90 178.3(15) . . . . ?
C95 N9 C89 C90 68.4(17) . . . . ?
C89 N9 C91 C92 -69.5(18) . . . . ?
C93 N9 C91 C92 55.0(17) . . . . ?
C95 N9 C91 C92 168.9(15) . . . . ?
C91 N9 C93 C94 58.2(15) . . . . ?
C89 N9 C93 C94 -172.4(12) . . . . ?
C95 N9 C93 C94 -56.7(13) . . . . ?
C91 N9 C95 C96 -174.0(15) . . . . ?
C89 N9 C95 C96 62.0(16) . . . . ?
C93 N9 C95 C96 -49.0(16) . . . . ?
C99 N10 C97 C98 -62(2) . . . . ?
C103 N10 C97 C98 179.7(17) . . . . ?
C101 N10 C97 C98 57(2) . . . . ?
C103 N10 C99 C100 62.5(16) . . . . ?
C97 N10 C99 C100 -52.1(17) . . . . ?
C101 N10 C99 C100 -176.1(14) . . . . ?
C99 N10 C101 C102 -175.3(17) . . . . ?
C103 N10 C101 C102 -55(2) . . . . ?
C97 N10 C101 C102 63(2) . . . . ?
C99 N10 C103 C104 59(2) . . . . ?
C97 N10 C103 C104 178.2(18) . . . . ?
C101 N10 C103 C104 -58(2) . . . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        21.49
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         1.249
_refine_diff_density_min         -0.876
_refine_diff_density_rms         0.097


data_mm053_5
_database_code_depnum_ccdc_archive 'CCDC 818518'
#TrackingRef 'web_deposit_cif_file_0_FatemahHabib_1300815031.cif'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C129.50 H133.50 Dy2 N10.50 O17.50'
_chemical_formula_weight         2441.97

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.3544(8)
_cell_length_b                   18.9741(10)
_cell_length_c                   23.0490(12)
_cell_angle_alpha                86.019(3)
_cell_angle_beta                 81.988(3)
_cell_angle_gamma                79.315(2)
_cell_volume                     6102.5(6)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    4738
_cell_measurement_theta_min      2.19
_cell_measurement_theta_max      21.78

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.04
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.329
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2512
_exptl_absorpt_coefficient_mu    1.283
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8408
_exptl_absorpt_correction_T_max  0.9505
_exptl_absorpt_process_details   'SADABS, Bruker (2003)'

_exptl_special_details           
;
Data collection is performed with four batch runs at phi = 0.00 deg
(600 frames), at phi = 90.00 deg (600 frames), at phi = 180.00 deg
(600 frames), and at phi = 270.00 deg (600 frames).
A fifth batch run is collected at phi = 0.00 deg (50 frames) to monitor
crystal and diffractometer stability. Frame width = 0.30 deg in omega.
Data is merged, corrected for decay (if any), and treated with multi-scan
absorption corrections (if required). All symmetry-equivalent reflections
are merged for centrosymmetric data.
Friedel pairs are not merged for noncentrosymmetric data.
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            14668
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.1097
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         1.44
_diffrn_reflns_theta_max         22.04
_reflns_number_total             14762
_reflns_number_gt                10091
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'APEX II, Bruker (2009)'
_computing_cell_refinement       'APEX II, Bruker (2009)'
_computing_data_reduction        'XPREP, Bruker (2009)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'SHELXTL, Bruker (2004)'
_computing_publication_material  'SHELXTL, Bruker (2004)'

_refine_special_details          
;
Refinement of F² against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F², conventional R-factors R are based
on F, with F set to zero for negative F². The threshold expression of
F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F² are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0552P)²+55.3154P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         14762
_refine_ls_number_parameters     1434
_refine_ls_number_restraints     944
_refine_ls_R_factor_all          0.1355
_refine_ls_R_factor_gt           0.0805
_refine_ls_wR_factor_ref         0.1881
_refine_ls_wR_factor_gt          0.1588
_refine_ls_goodness_of_fit_ref   1.074
_refine_ls_restrained_S_all      1.043
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.33884(6) 0.56125(4) 0.31943(3) 0.0385(2) Uani 1 1 d . . .
Dy2 Dy 0.90922(6) 1.14690(4) 0.20597(3) 0.0366(2) Uani 1 1 d . . .
O1 O 0.1856(7) 0.5565(6) 0.3303(5) 0.043(3) Uani 1 1 d . . .
O2 O 0.0496(10) 0.4813(8) 0.3619(7) 0.088(5) Uani 1 1 d . . .
O3 O 0.8065(7) 1.1214(5) 0.1488(4) 0.039(3) Uani 1 1 d . . .
O4 O 0.9362(8) 1.1908(6) 0.0934(4) 0.049(3) Uani 1 1 d . . .
O5 O 0.4435(8) 0.5777(5) 0.2390(4) 0.042(3) Uani 1 1 d . . .
O6 O 0.3081(8) 0.5114(6) 0.2224(5) 0.048(3) Uani 1 1 d . . .
O7 O 1.0637(7) 1.1518(6) 0.1904(5) 0.049(3) Uani 1 1 d . . .
O8 O 1.1961(15) 1.2376(11) 0.1775(8) 0.124(7) Uani 1 1 d . . .
O9 O 0.3694(8) 0.4434(5) 0.3287(5) 0.047(3) Uani 1 1 d . . .
O10 O 0.3263(12) 0.3130(7) 0.3216(6) 0.086(5) Uani 1 1 d . . .
O11 O 0.9077(7) 1.0652(5) 0.2818(4) 0.043(3) Uani 1 1 d . . .
O12 O 0.9612(8) 1.1847(5) 0.2995(4) 0.041(3) Uani 1 1 d . . .
O13 O 0.3397(8) 0.6527(5) 0.3772(4) 0.044(3) Uani 1 1 d . . .
O14 O 0.2784(8) 0.5404(5) 0.4316(4) 0.047(3) Uani 1 1 d . . .
O15 O 0.8776(8) 1.2663(5) 0.1972(5) 0.047(3) Uani 1 1 d . . .
O16 O 0.9278(12) 1.3904(7) 0.1606(6) 0.094(5) Uani 1 1 d . . .
N1 N 0.2468(10) 0.6711(6) 0.2597(5) 0.038(3) Uani 1 1 d . . .
N2 N 0.6306(9) 1.0278(8) 0.0650(6) 0.050(4) Uani 1 1 d . . .
N3 N 0.6234(11) 0.6535(8) 0.1045(6) 0.054(4) Uani 1 1 d . . .
N4 N 0.9980(9) 1.0348(7) 0.1474(5) 0.037(3) Uani 1 1 d . . .
N5 N 0.4929(8) 0.5254(6) 0.3678(5) 0.033(3) Uani 1 1 d . . .
N6 N 0.8336(11) 0.9241(8) 0.4175(6) 0.059(4) Uani 1 1 d . . .
N7 N 0.3592(9) 0.8322(7) 0.4594(6) 0.047(4) Uani 1 1 d . . .
N8 N 0.7508(8) 1.1917(7) 0.2745(5) 0.036(3) Uani 1 1 d . . .
N9 N 0.2116(11) 0.9881(9) 0.3055(7) 0.073(4) Uani 1 1 d . . .
N10 N 0.5815(16) 0.3108(11) 0.1261(9) 0.107(7) Uani 1 1 d . . .
C1 C 0.1071(11) 0.5769(8) 0.3098(7) 0.041(4) Uani 1 1 d U . .
C2 C 0.0303(13) 0.5382(10) 0.3258(9) 0.058(4) Uani 1 1 d U . .
C3 C -0.0555(13) 0.5604(10) 0.3057(9) 0.066(5) Uani 1 1 d U . .
H3A H -0.1043 0.5343 0.3173 0.080 Uiso 1 1 calc R . .
C4 C -0.0726(14) 0.6211(10) 0.2684(10) 0.075(5) Uani 1 1 d U . .
H4A H -0.1324 0.6355 0.2559 0.090 Uiso 1 1 calc R . .
C5 C -0.0003(13) 0.6598(10) 0.2500(9) 0.068(5) Uani 1 1 d U . .
H5A H -0.0107 0.7000 0.2246 0.081 Uiso 1 1 calc R . .
C6 C 0.0884(12) 0.6376(9) 0.2699(7) 0.050(4) Uani 1 1 d U . .
C7 C -0.008(2) 0.4356(16) 0.3704(14) 0.168(15) Uani 1 1 d . . .
H7A H 0.0152 0.3974 0.3971 0.252 Uiso 1 1 calc R . .
H7B H -0.0128 0.4161 0.3338 0.252 Uiso 1 1 calc R . .
H7C H -0.0705 0.4593 0.3868 0.252 Uiso 1 1 calc R . .
C8 C 0.1620(13) 0.6806(8) 0.2497(7) 0.047(4) Uani 1 1 d U . .
H8A H 0.1430 0.7208 0.2258 0.057 Uiso 1 1 calc R . .
C9 C 0.3049(11) 0.7196(8) 0.2306(7) 0.039(4) Uani 1 1 d U . .
C10 C 0.3074(11) 0.7373(9) 0.1718(7) 0.046(4) Uani 1 1 d U . .
H10A H 0.2711 0.7173 0.1492 0.055 Uiso 1 1 calc R . .
C11 C 0.3654(12) 0.7860(9) 0.1464(7) 0.051(4) Uani 1 1 d U . .
H11U H 0.3683 0.7966 0.1062 0.061 Uiso 1 1 calc R . .
C12 C 0.4191(11) 0.8192(8) 0.1789(7) 0.039(3) Uani 1 1 d U . .
C13 C 0.4197(12) 0.7967(7) 0.2368(7) 0.039(4) Uani 1 1 d U . .
H13G H 0.4584 0.8147 0.2591 0.046 Uiso 1 1 calc R . .
C14 C 0.3638(12) 0.7477(8) 0.2628(7) 0.042(4) Uani 1 1 d U . .
H14A H 0.3657 0.7334 0.3022 0.051 Uiso 1 1 calc R . .
C15 C 0.4730(12) 0.8752(8) 0.1522(7) 0.041(3) Uani 1 1 d U . .
C16 C 0.4428(13) 0.9198(11) 0.1052(8) 0.069(5) Uani 1 1 d U . .
H16A H 0.3863 0.9155 0.0915 0.083 Uiso 1 1 calc R . .
C17 C 0.4941(14) 0.9692(11) 0.0791(8) 0.072(5) Uani 1 1 d U . .
H17A H 0.4722 0.9973 0.0474 0.086 Uiso 1 1 calc R . .
C18 C 0.5780(11) 0.9796(8) 0.0980(7) 0.040(4) Uani 1 1 d U . .
C19 C 0.6051(12) 0.9366(9) 0.1456(7) 0.051(4) Uani 1 1 d U . .
H19A H 0.6592 0.9432 0.1611 0.061 Uiso 1 1 calc R . .
C20 C 0.5568(11) 0.8852(9) 0.1708(7) 0.052(4) Uani 1 1 d U . .
H20A H 0.5805 0.8559 0.2014 0.062 Uiso 1 1 calc R . .
C21 C 0.6885(12) 1.0535(8) 0.0892(7) 0.042(4) Uani 1 1 d U . .
H21A H 0.6901 1.0430 0.1291 0.051 Uiso 1 1 calc R . .
C22 C 0.8133(11) 1.1285(7) 0.0923(7) 0.036(3) Uani 1 1 d U . .
C23 C 0.7547(11) 1.0993(8) 0.0591(7) 0.043(3) Uani 1 1 d U . .
C24 C 0.7603(12) 1.1126(8) -0.0024(7) 0.048(4) Uani 1 1 d U . .
H24A H 0.7201 1.0940 -0.0233 0.058 Uiso 1 1 calc R . .
C25 C 0.8246(12) 1.1529(8) -0.0317(7) 0.051(4) Uani 1 1 d U . .
H25A H 0.8279 1.1618 -0.0721 0.061 Uiso 1 1 calc R . .
C26 C 0.8841(12) 1.1797(9) 0.0004(7) 0.051(4) Uani 1 1 d U . .
H26A H 0.9281 1.2063 -0.0191 0.061 Uiso 1 1 calc R . .
C27 C 0.8802(11) 1.1684(8) 0.0583(7) 0.039(3) Uani 1 1 d U . .
C28 C 0.9857(13) 1.2485(9) 0.0695(8) 0.060(5) Uani 1 1 d . . .
H28A H 0.9859 1.2529 0.0277 0.091 Uiso 1 1 calc R . .
H28B H 1.0504 1.2381 0.0784 0.091 Uiso 1 1 calc R . .
H28C H 0.9537 1.2927 0.0865 0.091 Uiso 1 1 calc R . .
C29 C 0.4354(10) 0.5676(8) 0.1845(7) 0.034(3) Uani 1 1 d U . .
C30 C 0.3627(11) 0.5287(8) 0.1736(7) 0.041(4) Uani 1 1 d U . .
C31 C 0.3552(13) 0.5113(9) 0.1186(7) 0.055(4) Uani 1 1 d U . .
H31A H 0.3082 0.4858 0.1124 0.066 Uiso 1 1 calc R . .
C32 C 0.4195(12) 0.5321(9) 0.0705(8) 0.055(4) Uani 1 1 d U . .
H32A H 0.4150 0.5205 0.0325 0.066 Uiso 1 1 calc R . .
C33 C 0.4872(12) 0.5691(9) 0.0807(7) 0.053(4) Uani 1 1 d U . .
H33A H 0.5294 0.5821 0.0492 0.063 Uiso 1 1 calc R . .
C34 C 0.4963(11) 0.5885(8) 0.1368(7) 0.038(3) Uani 1 1 d U . .
C35 C 0.2442(13) 0.4603(9) 0.2198(8) 0.058(5) Uani 1 1 d . . .
H35A H 0.2440 0.4498 0.1797 0.087 Uiso 1 1 calc R . .
H35B H 0.1806 0.4808 0.2364 0.087 Uiso 1 1 calc R . .
H35C H 0.2660 0.4169 0.2416 0.087 Uiso 1 1 calc R . .
C36 C 0.5615(12) 0.6334(8) 0.1457(7) 0.044(4) Uani 1 1 d U . .
H36A H 0.5596 0.6491 0.1832 0.053 Uiso 1 1 calc R . .
C37 C 0.6827(12) 0.7026(9) 0.1143(7) 0.048(4) Uani 1 1 d U . .
C38 C 0.7028(14) 0.7520(10) 0.0689(8) 0.063(5) Uani 1 1 d U . .
H38A H 0.6776 0.7514 0.0339 0.075 Uiso 1 1 calc R . .
C39 C 0.7589(14) 0.8018(9) 0.0746(7) 0.059(5) Uani 1 1 d U . .
H39A H 0.7719 0.8337 0.0433 0.071 Uiso 1 1 calc R . .
C40 C 0.7958(11) 0.8051(8) 0.1254(6) 0.037(3) Uani 1 1 d U . .
C41 C 0.7765(12) 0.7561(8) 0.1702(7) 0.046(4) Uani 1 1 d U . .
H41A H 0.8020 0.7570 0.2050 0.055 Uiso 1 1 calc R . .
C42 C 0.7197(12) 0.7047(8) 0.1653(7) 0.048(4) Uani 1 1 d U . .
H42A H 0.7074 0.6724 0.1965 0.058 Uiso 1 1 calc R . .
C43 C 0.8506(11) 0.8630(8) 0.1312(7) 0.039(3) Uani 1 1 d U . .
C44 C 0.8934(11) 0.8973(9) 0.0822(7) 0.046(4) Uani 1 1 d U . .
H44A H 0.8893 0.8828 0.0451 0.055 Uiso 1 1 calc R . .
C45 C 0.9412(13) 0.9518(8) 0.0873(7) 0.048(4) Uani 1 1 d U . .
H45A H 0.9692 0.9732 0.0534 0.058 Uiso 1 1 calc R . .
C46 C 0.9496(11) 0.9767(8) 0.1415(7) 0.041(4) Uani 1 1 d U . .
C47 C 0.9059(11) 0.9456(9) 0.1898(7) 0.048(4) Uani 1 1 d U . .
H47A H 0.9086 0.9619 0.2266 0.057 Uiso 1 1 calc R . .
C48 C 0.8571(12) 0.8899(9) 0.1856(7) 0.049(4) Uani 1 1 d U . .
H48A H 0.8279 0.8698 0.2197 0.059 Uiso 1 1 calc R . .
C49 C 1.0781(12) 1.0334(8) 0.1142(7) 0.039(4) Uani 1 1 d U . .
H49A H 1.0962 0.9948 0.0898 0.047 Uiso 1 1 calc R . .
C50 C 1.1328(11) 1.1394(8) 0.1495(8) 0.044(4) Uani 1 1 d U . .
C51 C 1.1440(12) 1.0830(8) 0.1094(7) 0.046(4) Uani 1 1 d U . .
C52 C 1.2263(12) 1.0707(9) 0.0650(7) 0.055(4) Uani 1 1 d U . .
H52A H 1.2345 1.0325 0.0406 0.066 Uiso 1 1 calc R . .
C53 C 1.2913(14) 1.1148(11) 0.0591(9) 0.073(5) Uani 1 1 d U . .
H53A H 1.3446 1.1060 0.0309 0.087 Uiso 1 1 calc R . .
C54 C 1.2799(14) 1.1728(12) 0.0942(9) 0.077(5) Uani 1 1 d U . .
H54A H 1.3228 1.2046 0.0878 0.092 Uiso 1 1 calc R . .
C55 C 1.2059(13) 1.1829(10) 0.1379(9) 0.061(4) Uani 1 1 d U . .
C56 C 1.193(4) 1.3036(19) 0.1606(17) 0.23(2) Uani 1 1 d . . .
H56A H 1.1911 1.3317 0.1940 0.345 Uiso 1 1 calc R . .
H56B H 1.1367 1.3202 0.1419 0.345 Uiso 1 1 calc R . .
H56C H 1.2487 1.3084 0.1334 0.345 Uiso 1 1 calc R . .
C57 C 0.4103(11) 0.3915(8) 0.3601(7) 0.041(3) Uani 1 1 d U . .
C58 C 0.3898(13) 0.3197(9) 0.3579(8) 0.056(4) Uani 1 1 d U . .
C59 C 0.4341(14) 0.2638(9) 0.3907(8) 0.064(4) Uani 1 1 d U . .
H59A H 0.4174 0.2189 0.3898 0.076 Uiso 1 1 calc R . .
C60 C 0.5041(14) 0.2717(9) 0.4259(7) 0.057(4) Uani 1 1 d U . .
H60A H 0.5341 0.2325 0.4470 0.069 Uiso 1 1 calc R . .
C61 C 0.5267(11) 0.3373(8) 0.4282(7) 0.046(4) Uani 1 1 d U . .
H61A H 0.5724 0.3434 0.4514 0.055 Uiso 1 1 calc R . .
C62 C 0.4806(11) 0.3983(8) 0.3951(6) 0.039(3) Uani 1 1 d U . .
C63 C 0.270(3) 0.268(3) 0.3258(19) 0.30(3) Uani 1 1 d . . .
H63A H 0.2305 0.2781 0.2947 0.445 Uiso 1 1 calc R . .
H63B H 0.2298 0.2723 0.3629 0.445 Uiso 1 1 calc R . .
H63C H 0.3060 0.2204 0.3230 0.445 Uiso 1 1 calc R . .
C64 C 0.5199(11) 0.4645(8) 0.3956(7) 0.043(4) Uani 1 1 d U . .
H64A H 0.5691 0.4628 0.4183 0.052 Uiso 1 1 calc R . .
C65 C 0.5472(10) 0.5799(8) 0.3762(6) 0.037(3) Uani 1 1 d U . .
C66 C 0.5664(12) 0.5928(8) 0.4307(7) 0.046(4) Uani 1 1 d U . .
H66A H 0.5453 0.5661 0.4637 0.055 Uiso 1 1 calc R . .
C67 C 0.6192(12) 0.6478(9) 0.4358(7) 0.051(4) Uani 1 1 d U . .
H67A H 0.6349 0.6552 0.4725 0.061 Uiso 1 1 calc R . .
C68 C 0.6476(11) 0.6897(8) 0.3895(7) 0.040(3) Uani 1 1 d U . .
C69 C 0.6244(11) 0.6772(9) 0.3336(7) 0.044(4) Uani 1 1 d U . .
H69A H 0.6430 0.7048 0.3006 0.053 Uiso 1 1 calc R . .
C70 C 0.5739(11) 0.6233(8) 0.3293(7) 0.040(3) Uani 1 1 d U . .
H70A H 0.5572 0.6161 0.2929 0.048 Uiso 1 1 calc R . .
C71 C 0.6982(11) 0.7493(9) 0.3963(7) 0.042(4) Uani 1 1 d U . .
C72 C 0.6799(13) 0.7872(9) 0.4482(7) 0.054(4) Uani 1 1 d U . .
H72A H 0.6372 0.7740 0.4794 0.065 Uiso 1 1 calc R . .
C73 C 0.7256(14) 0.8443(9) 0.4526(8) 0.061(5) Uani 1 1 d U . .
H73A H 0.7127 0.8684 0.4874 0.073 Uiso 1 1 calc R . .
C74 C 0.7877(13) 0.8669(9) 0.4093(8) 0.055(4) Uani 1 1 d U . .
C75 C 0.8074(13) 0.8294(9) 0.3573(8) 0.053(4) Uani 1 1 d U . .
H75A H 0.8498 0.8434 0.3262 0.064 Uiso 1 1 calc R . .
C76 C 0.7633(12) 0.7716(9) 0.3528(7) 0.051(4) Uani 1 1 d U . .
H76A H 0.7785 0.7464 0.3186 0.061 Uiso 1 1 calc R . .
C77 C 0.8487(11) 0.9706(8) 0.3747(6) 0.038(4) Uani 1 1 d U . .
H77A H 0.8338 0.9642 0.3377 0.045 Uiso 1 1 calc R . .
C78 C 0.9124(10) 1.0788(8) 0.3380(6) 0.036(3) Uani 1 1 d U . .
C79 C 0.8891(11) 1.0331(8) 0.3852(6) 0.040(3) Uani 1 1 d U . .
C80 C 0.9029(14) 1.0484(9) 0.4407(7) 0.057(4) Uani 1 1 d U . .
H80A H 0.8884 1.0173 0.4723 0.069 Uiso 1 1 calc R . .
C81 C 0.9376(15) 1.1089(9) 0.4500(7) 0.068(5) Uani 1 1 d U . .
H81A H 0.9491 1.1176 0.4874 0.082 Uiso 1 1 calc R . .
C82 C 0.9554(13) 1.1567(9) 0.4036(6) 0.050(4) Uani 1 1 d U . .
H82A H 0.9756 1.1989 0.4102 0.060 Uiso 1 1 calc R . .
C83 C 0.9438(12) 1.1427(8) 0.3492(6) 0.042(4) Uani 1 1 d U . .
C84 C 1.0062(13) 1.2438(9) 0.3060(8) 0.059(5) Uani 1 1 d . . .
H84A H 1.0165 1.2450 0.3462 0.089 Uiso 1 1 calc R . .
H84B H 0.9660 1.2876 0.2950 0.089 Uiso 1 1 calc R . .
H84C H 1.0665 1.2387 0.2813 0.089 Uiso 1 1 calc R . .
C85 C 0.3039(10) 0.6605(8) 0.4321(7) 0.035(3) Uani 1 1 d U . .
C86 C 0.2685(11) 0.6007(9) 0.4639(7) 0.041(3) Uani 1 1 d U . .
C87 C 0.2241(13) 0.6075(10) 0.5200(7) 0.060(5) Uani 1 1 d U . .
H87A H 0.2008 0.5689 0.5403 0.072 Uiso 1 1 calc R . .
C88 C 0.2138(13) 0.6719(11) 0.5466(8) 0.064(5) Uani 1 1 d U . .
H88A H 0.1797 0.6776 0.5838 0.077 Uiso 1 1 calc R . .
C89 C 0.2533(12) 0.7275(9) 0.5188(7) 0.052(4) Uani 1 1 d U . .
H89A H 0.2480 0.7698 0.5381 0.063 Uiso 1 1 calc R . .
C90 C 0.3012(10) 0.7217(8) 0.4625(6) 0.038(3) Uani 1 1 d U . .
C91 C 0.2275(13) 0.4852(9) 0.4534(8) 0.067(6) Uani 1 1 d . . .
H91A H 0.2126 0.4874 0.4952 0.100 Uiso 1 1 calc R . .
H91B H 0.2659 0.4395 0.4438 0.100 Uiso 1 1 calc R . .
H91C H 0.1693 0.4913 0.4360 0.100 Uiso 1 1 calc R . .
C92 C 0.3520(12) 0.7754(9) 0.4344(7) 0.045(4) Uani 1 1 d U . .
H92A H 0.3815 0.7689 0.3961 0.054 Uiso 1 1 calc R . .
C93 C 0.4160(11) 0.8818(8) 0.4290(7) 0.039(4) Uani 1 1 d U . .
C94 C 0.4026(11) 0.9494(8) 0.4496(7) 0.041(3) Uani 1 1 d U . .
H94A H 0.3568 0.9618 0.4817 0.050 Uiso 1 1 calc R . .
C95 C 0.4552(12) 0.9990(8) 0.4240(7) 0.044(4) Uani 1 1 d U . .
H95A H 0.4431 1.0448 0.4385 0.053 Uiso 1 1 calc R . .
C96 C 0.5264(11) 0.9833(8) 0.3766(7) 0.039(3) Uani 1 1 d U . .
C97 C 0.5392(10) 0.9145(8) 0.3573(7) 0.040(4) Uani 1 1 d U . .
H97A H 0.5862 0.9013 0.3260 0.048 Uiso 1 1 calc R . .
C98 C 0.4857(11) 0.8648(9) 0.3823(8) 0.049(4) Uani 1 1 d U . .
H98A H 0.4966 0.8192 0.3675 0.059 Uiso 1 1 calc R . .
C99 C 0.5865(12) 1.0371(8) 0.3500(7) 0.043(3) Uani 1 1 d U . .
C100 C 0.6133(12) 1.0832(8) 0.3855(7) 0.044(4) Uani 1 1 d U . .
H10B H 0.5934 1.0813 0.4257 0.053 Uiso 1 1 calc R . .
C101 C 0.6697(11) 1.1324(8) 0.3618(7) 0.041(4) Uani 1 1 d U . .
H10C H 0.6897 1.1619 0.3863 0.049 Uiso 1 1 calc R . .
C102 C 0.6969(11) 1.1382(8) 0.3017(7) 0.035(3) Uani 1 1 d U . .
C103 C 0.6724(12) 1.0893(8) 0.2676(7) 0.047(4) Uani 1 1 d U . .
H10D H 0.6937 1.0896 0.2276 0.056 Uiso 1 1 calc R . .
C104 C 0.6177(12) 1.0411(9) 0.2913(7) 0.049(4) Uani 1 1 d U . .
H10E H 0.6010 1.0097 0.2670 0.059 Uiso 1 1 calc R . .
C105 C 0.7275(12) 1.2543(8) 0.2965(7) 0.047(4) Uani 1 1 d U . .
H10F H 0.6798 1.2591 0.3284 0.056 Uiso 1 1 calc R . .
C107 C 0.7679(12) 1.3182(9) 0.2767(7) 0.050(4) Uani 1 1 d U . .
C106 C 0.8352(12) 1.3205(8) 0.2275(7) 0.040(4) Uani 1 1 d U . .
C108 C 0.7274(13) 1.3820(9) 0.3066(9) 0.069(5) Uani 1 1 d U . .
H10G H 0.6830 1.3791 0.3398 0.083 Uiso 1 1 calc R . .
C109 C 0.7497(14) 1.4440(10) 0.2893(9) 0.076(6) Uani 1 1 d U . .
H10H H 0.7219 1.4849 0.3097 0.092 Uiso 1 1 calc R . .
C110 C 0.8152(14) 1.4479(10) 0.2405(9) 0.072(5) Uani 1 1 d U . .
H11V H 0.8304 1.4923 0.2271 0.087 Uiso 1 1 calc R . .
C111 C 0.8588(14) 1.3882(9) 0.2109(8) 0.058(4) Uani 1 1 d U . .
C112 C 0.963(2) 1.4535(13) 0.1436(13) 0.164(15) Uani 1 1 d . . .
H11R H 1.0090 1.4457 0.1090 0.246 Uiso 1 1 calc R . .
H11S H 0.9937 1.4669 0.1746 0.246 Uiso 1 1 calc R . .
H11T H 0.9116 1.4912 0.1354 0.246 Uiso 1 1 calc R . .
C113 C 0.2144(15) 0.9240(12) 0.3494(10) 0.092(7) Uani 1 1 d U . .
H11A H 0.2546 0.9307 0.3784 0.110 Uiso 1 1 calc R . .
H11B H 0.2456 0.8814 0.3287 0.110 Uiso 1 1 calc R . .
C114 C 0.122(2) 0.9093(17) 0.3814(12) 0.149(11) Uani 1 1 d U . .
H11I H 0.1333 0.8673 0.4068 0.224 Uiso 1 1 calc R . .
H11J H 0.0810 0.9017 0.3536 0.224 Uiso 1 1 calc R . .
H11K H 0.0913 0.9496 0.4042 0.224 Uiso 1 1 calc R . .
C115 C 0.1489(13) 0.9807(11) 0.2590(9) 0.078(6) Uani 1 1 d U . .
H11C H 0.0841 0.9810 0.2780 0.094 Uiso 1 1 calc R . .
H11D H 0.1475 1.0224 0.2321 0.094 Uiso 1 1 calc R . .
C116 C 0.1796(17) 0.9150(13) 0.2245(10) 0.110(8) Uani 1 1 d U . .
H11L H 0.1364 0.9148 0.1963 0.165 Uiso 1 1 calc R . .
H11M H 0.1794 0.8732 0.2504 0.165 Uiso 1 1 calc R . .
H11N H 0.2430 0.9147 0.2045 0.165 Uiso 1 1 calc R . .
C117 C 0.3126(16) 0.9892(11) 0.2770(11) 0.090(7) Uani 1 1 d U . .
H11E H 0.3361 0.9440 0.2581 0.108 Uiso 1 1 calc R . .
H11F H 0.3516 0.9909 0.3078 0.108 Uiso 1 1 calc R . .
C118 C 0.3294(19) 1.0505(13) 0.2312(13) 0.127(10) Uani 1 1 d U . .
H11O H 0.3959 1.0441 0.2157 0.190 Uiso 1 1 calc R . .
H11P H 0.3108 1.0958 0.2495 0.190 Uiso 1 1 calc R . .
H11Q H 0.2919 1.0498 0.1999 0.190 Uiso 1 1 calc R . .
C119 C 0.1686(18) 1.0572(13) 0.3348(13) 0.120(10) Uani 1 1 d U . .
H11G H 0.1030 1.0546 0.3508 0.144 Uiso 1 1 calc R . .
H11H H 0.1665 1.0959 0.3050 0.144 Uiso 1 1 calc R . .
C120 C 0.219(2) 1.0769(15) 0.3839(14) 0.156(13) Uani 1 1 d U . .
H12I H 0.1837 1.1202 0.4009 0.235 Uiso 1 1 calc R . .
H12J H 0.2824 1.0841 0.3682 0.235 Uiso 1 1 calc R . .
H12K H 0.2232 1.0386 0.4135 0.235 Uiso 1 1 calc R . .
C121 C 0.583(2) 0.2372(15) 0.1568(13) 0.122(9) Uani 1 1 d U . .
H12A H 0.6206 0.2019 0.1304 0.147 Uiso 1 1 calc R . .
H12B H 0.6162 0.2357 0.1909 0.147 Uiso 1 1 calc R . .
C122 C 0.487(2) 0.2140(18) 0.1770(19) 0.201(16) Uani 1 1 d U . .
H12L H 0.4973 0.1664 0.1948 0.302 Uiso 1 1 calc R . .
H12M H 0.4529 0.2144 0.1439 0.302 Uiso 1 1 calc R . .
H12N H 0.4498 0.2466 0.2051 0.302 Uiso 1 1 calc R . .
C123 C 0.5151(18) 0.3694(15) 0.1636(12) 0.124(10) Uani 1 1 d U . .
H12C H 0.5116 0.4151 0.1417 0.149 Uiso 1 1 calc R . .
H12D H 0.4513 0.3580 0.1706 0.149 Uiso 1 1 calc R . .
C124 C 0.549(2) 0.3766(17) 0.2222(12) 0.168(14) Uani 1 1 d U . .
H12O H 0.5069 0.4152 0.2425 0.253 Uiso 1 1 calc R . .
H12P H 0.6125 0.3865 0.2158 0.253 Uiso 1 1 calc R . .
H12Q H 0.5477 0.3326 0.2454 0.253 Uiso 1 1 calc R . .
C125 C 0.679(2) 0.321(2) 0.1155(14) 0.167(15) Uani 1 1 d U . .
H12E H 0.7159 0.2840 0.0902 0.201 Uiso 1 1 calc R . .
H12F H 0.7056 0.3151 0.1525 0.201 Uiso 1 1 calc R . .
C126 C 0.532(2) 0.3184(16) 0.0712(11) 0.166(14) Uani 1 1 d U . .
H12G H 0.4657 0.3144 0.0821 0.199 Uiso 1 1 calc R . .
H12H H 0.5345 0.3657 0.0527 0.199 Uiso 1 1 calc R . .
C127 C 0.577(3) 0.263(2) 0.0283(15) 0.27(2) Uani 1 1 d U . .
H12R H 0.5422 0.2690 -0.0048 0.402 Uiso 1 1 calc R . .
H12S H 0.5765 0.2163 0.0465 0.402 Uiso 1 1 calc R . .
H12T H 0.6421 0.2688 0.0154 0.402 Uiso 1 1 calc R . .
C128 C 0.693(3) 0.399(3) 0.085(2) 0.26(2) Uani 1 1 d U . .
H12U H 0.7596 0.4025 0.0800 0.386 Uiso 1 1 calc R . .
H12V H 0.6579 0.4361 0.1103 0.386 Uiso 1 1 calc R . .
H12W H 0.6695 0.4048 0.0480 0.386 Uiso 1 1 calc R . .
O17 O 0.1092(18) 0.2604(13) 0.4453(11) 0.064(7) Uiso 0.50 1 d P . .
C129 C 0.066(3) 0.2556(19) 0.4843(15) 0.098(15) Uiso 0.50 1 d PD . .
H12X H 0.0393 0.2140 0.4893 0.117 Uiso 0.50 1 calc PR . .
N11 N 0.0390(14) 0.3033(10) 0.5324(8) 0.025(5) Uiso 0.50 1 d PD . .
C130 C 0.078(3) 0.3695(15) 0.5327(17) 0.075(12) Uiso 0.50 1 d PD . .
H13A H 0.1188 0.3751 0.4967 0.113 Uiso 0.50 1 calc PR . .
H13B H 0.1132 0.3672 0.5652 0.113 Uiso 0.50 1 calc PR . .
H13C H 0.0259 0.4098 0.5362 0.113 Uiso 0.50 1 calc PR . .
C131 C -0.027(3) 0.286(2) 0.5842(14) 0.099(15) Uiso 0.50 1 d PD . .
H13D H -0.0416 0.2391 0.5810 0.148 Uiso 0.50 1 calc PR . .
H13E H -0.0854 0.3208 0.5862 0.148 Uiso 0.50 1 calc PR . .
H13F H 0.0018 0.2869 0.6191 0.148 Uiso 0.50 1 calc PR . .
O18 O 0.042(2) 0.6094(17) 0.0604(15) 0.117(11) Uiso 0.50 1 d P . .
H18A H 0.0758 0.5818 0.0283 0.176 Uiso 0.50 1 d PR . .
H18B H -0.0266 0.6251 0.0550 0.176 Uiso 0.50 1 d PR . .
O19 O 0.711(2) 0.6017(14) 0.9847(12) 0.084(8) Uiso 0.50 1 d P . .
H19B H 0.6869 0.5834 0.9531 0.126 Uiso 0.50 1 d PR . .
H19C H 0.7644 0.5656 0.9986 0.126 Uiso 0.50 1 d PR . .


_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.197(10) . ?
Dy1 O9 2.198(10) . ?
Dy1 O13 2.262(9) . ?
Dy1 O5 2.261(10) . ?
Dy1 N5 2.573(12) . ?
Dy1 O6 2.611(10) . ?
Dy1 O14 2.637(10) . ?
Dy1 N1 2.660(11) . ?
Dy2 O15 2.227(10) . ?
Dy2 O7 2.214(10) . ?
Dy2 O11 2.254(10) . ?
Dy2 O3 2.246(10) . ?
Dy2 O12 2.565(9) . ?
Dy2 N4 2.625(13) . ?
Dy2 N8 2.619(12) . ?
Dy2 O4 2.667(10) . ?
O1 C1 1.266(17) . ?
O2 C2 1.33(2) . ?
O2 C7 1.30(3) . ?
O3 C22 1.290(17) . ?
O4 C27 1.356(17) . ?
O4 C28 1.450(18) . ?
O5 C29 1.308(17) . ?
O6 C30 1.336(17) . ?
O6 C35 1.462(17) . ?
O7 C50 1.269(19) . ?
O8 C56 1.28(4) . ?
O8 C55 1.40(2) . ?
O9 C57 1.282(18) . ?
O10 C63 1.27(3) . ?
O10 C58 1.35(2) . ?
O11 C78 1.354(17) . ?
O12 C83 1.372(17) . ?
O12 C84 1.419(16) . ?
O13 C85 1.307(16) . ?
O14 C86 1.382(18) . ?
O14 C91 1.411(17) . ?
O15 C106 1.290(17) . ?
O16 C112 1.40(2) . ?
O16 C111 1.42(2) . ?
N1 C8 1.248(19) . ?
N1 C9 1.426(19) . ?
N2 C21 1.247(19) . ?
N2 C18 1.409(19) . ?
N3 C36 1.295(19) . ?
N3 C37 1.42(2) . ?
N4 C49 1.286(19) . ?
N4 C46 1.430(18) . ?
N5 C64 1.303(18) . ?
N5 C65 1.442(18) . ?
N6 C77 1.300(18) . ?
N6 C74 1.40(2) . ?
N7 C92 1.284(18) . ?
N7 C93 1.442(19) . ?
N8 C105 1.291(18) . ?
N8 C102 1.445(18) . ?
N9 C119 1.51(2) . ?
N9 C113 1.53(2) . ?
N9 C117 1.51(3) . ?
N9 C115 1.52(2) . ?
N10 C125 1.44(4) . ?
N10 C126 1.52(3) . ?
N10 C121 1.52(3) . ?
N10 C123 1.55(3) . ?
C1 C2 1.43(2) . ?
C1 C6 1.43(2) . ?
C2 C3 1.36(2) . ?
C3 C4 1.39(3) . ?
C4 C5 1.38(2) . ?
C5 C6 1.40(2) . ?
C6 C8 1.46(2) . ?
C9 C10 1.37(2) . ?
C9 C14 1.39(2) . ?
C10 C11 1.40(2) . ?
C11 C12 1.40(2) . ?
C12 C13 1.37(2) . ?
C12 C15 1.48(2) . ?
C13 C14 1.39(2) . ?
C15 C20 1.38(2) . ?
C15 C16 1.39(2) . ?
C16 C17 1.36(2) . ?
C17 C18 1.39(2) . ?
C18 C19 1.38(2) . ?
C19 C20 1.35(2) . ?
C21 C23 1.48(2) . ?
C22 C23 1.42(2) . ?
C22 C27 1.44(2) . ?
C23 C24 1.42(2) . ?
C24 C25 1.38(2) . ?
C25 C26 1.39(2) . ?
C26 C27 1.33(2) . ?
C29 C34 1.39(2) . ?
C29 C30 1.44(2) . ?
C30 C31 1.35(2) . ?
C31 C32 1.42(2) . ?
C32 C33 1.35(2) . ?
C33 C34 1.40(2) . ?
C34 C36 1.42(2) . ?
C37 C42 1.36(2) . ?
C37 C38 1.39(2) . ?
C38 C39 1.37(2) . ?
C39 C40 1.36(2) . ?
C40 C41 1.37(2) . ?
C40 C43 1.49(2) . ?
C41 C42 1.40(2) . ?
C43 C48 1.41(2) . ?
C43 C44 1.39(2) . ?
C44 C45 1.36(2) . ?
C45 C46 1.39(2) . ?
C46 C47 1.35(2) . ?
C47 C48 1.39(2) . ?
C49 C51 1.44(2) . ?
C50 C51 1.43(2) . ?
C50 C55 1.44(2) . ?
C51 C52 1.45(2) . ?
C52 C53 1.35(2) . ?
C53 C54 1.38(3) . ?
C54 C55 1.35(3) . ?
C57 C62 1.41(2) . ?
C57 C58 1.45(2) . ?
C58 C59 1.37(2) . ?
C59 C60 1.41(2) . ?
C60 C61 1.35(2) . ?
C61 C62 1.45(2) . ?
C62 C64 1.47(2) . ?
C65 C66 1.37(2) . ?
C65 C70 1.37(2) . ?
C66 C67 1.42(2) . ?
C67 C68 1.35(2) . ?
C68 C69 1.42(2) . ?
C68 C71 1.48(2) . ?
C69 C70 1.37(2) . ?
C71 C76 1.37(2) . ?
C71 C72 1.41(2) . ?
C72 C73 1.38(2) . ?
C73 C74 1.34(2) . ?
C74 C75 1.41(2) . ?
C75 C76 1.38(2) . ?
C77 C79 1.46(2) . ?
C78 C79 1.39(2) . ?
C78 C83 1.419(19) . ?
C79 C80 1.38(2) . ?
C80 C81 1.37(2) . ?
C81 C82 1.38(2) . ?
C82 C83 1.338(19) . ?
C85 C90 1.39(2) . ?
C85 C86 1.44(2) . ?
C86 C87 1.36(2) . ?
C87 C88 1.38(2) . ?
C88 C89 1.37(2) . ?
C89 C90 1.38(2) . ?
C90 C92 1.43(2) . ?
C93 C98 1.38(2) . ?
C93 C94 1.37(2) . ?
C94 C95 1.37(2) . ?
C95 C96 1.39(2) . ?
C96 C97 1.38(2) . ?
C96 C99 1.50(2) . ?
C97 C98 1.37(2) . ?
C99 C100 1.38(2) . ?
C99 C104 1.37(2) . ?
C100 C101 1.38(2) . ?
C101 C102 1.39(2) . ?
C102 C103 1.38(2) . ?
C103 C104 1.35(2) . ?
C105 C107 1.46(2) . ?
C107 C108 1.42(2) . ?
C107 C106 1.39(2) . ?
C106 C111 1.40(2) . ?
C108 C109 1.30(2) . ?
C109 C110 1.37(2) . ?
C110 C111 1.37(2) . ?
C113 C114 1.49(3) . ?
C115 C116 1.49(3) . ?
C117 C118 1.54(3) . ?
C119 C120 1.53(3) . ?
C121 C122 1.53(4) . ?
C123 C124 1.52(3) . ?
C125 C128 1.62(5) . ?
C126 C127 1.48(3) . ?
O17 C129 1.03(3) . ?
C129 N11 1.446(19) . ?
N11 C130 1.464(18) . ?
N11 C131 1.479(18) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 O9 88.8(4) . . ?
O1 Dy1 O13 101.0(4) . . ?
O9 Dy1 O13 135.6(4) . . ?
O1 Dy1 O5 131.8(4) . . ?
O9 Dy1 O5 99.4(4) . . ?
O13 Dy1 O5 105.2(4) . . ?
O1 Dy1 N5 143.9(4) . . ?
O9 Dy1 N5 72.4(4) . . ?
O13 Dy1 N5 74.8(4) . . ?
O5 Dy1 N5 82.5(4) . . ?
O1 Dy1 O6 74.2(4) . . ?
O9 Dy1 O6 72.4(4) . . ?
O13 Dy1 O6 151.9(4) . . ?
O5 Dy1 O6 63.7(3) . . ?
N5 Dy1 O6 125.3(4) . . ?
O1 Dy1 O14 70.7(4) . . ?
O9 Dy1 O14 79.0(4) . . ?
O13 Dy1 O14 64.4(3) . . ?
O5 Dy1 O14 157.5(4) . . ?
N5 Dy1 O14 75.6(4) . . ?
O6 Dy1 O14 134.7(3) . . ?
O1 Dy1 N1 70.3(4) . . ?
O9 Dy1 N1 143.4(4) . . ?
O13 Dy1 N1 79.2(4) . . ?
O5 Dy1 N1 75.8(4) . . ?
N5 Dy1 N1 140.2(4) . . ?
O6 Dy1 N1 73.1(4) . . ?
O14 Dy1 N1 118.8(4) . . ?
O15 Dy2 O7 88.8(4) . . ?
O15 Dy2 O11 134.9(4) . . ?
O7 Dy2 O11 100.0(4) . . ?
O15 Dy2 O3 99.4(4) . . ?
O7 Dy2 O3 133.1(4) . . ?
O11 Dy2 O3 105.7(4) . . ?
O15 Dy2 O12 77.1(4) . . ?
O7 Dy2 O12 70.7(4) . . ?
O11 Dy2 O12 65.0(3) . . ?
O3 Dy2 O12 156.2(3) . . ?
O15 Dy2 N4 141.0(4) . . ?
O7 Dy2 N4 71.7(4) . . ?
O11 Dy2 N4 82.7(4) . . ?
O3 Dy2 N4 73.4(4) . . ?
O12 Dy2 N4 123.9(4) . . ?
O15 Dy2 N8 71.9(4) . . ?
O7 Dy2 N8 143.0(4) . . ?
O11 Dy2 N8 75.1(4) . . ?
O3 Dy2 N8 82.2(4) . . ?
O12 Dy2 N8 74.3(4) . . ?
N4 Dy2 N8 141.1(4) . . ?
O15 Dy2 O4 69.7(3) . . ?
O7 Dy2 O4 76.7(4) . . ?
O11 Dy2 O4 155.3(3) . . ?
O3 Dy2 O4 63.7(3) . . ?
O12 Dy2 O4 133.3(3) . . ?
N4 Dy2 O4 73.0(3) . . ?
N8 Dy2 O4 122.2(4) . . ?
C1 O1 Dy1 145.8(10) . . ?
C2 O2 C7 119.2(19) . . ?
C22 O3 Dy2 126.9(10) . . ?
C27 O4 C28 116.4(12) . . ?
C27 O4 Dy2 115.4(9) . . ?
C28 O4 Dy2 126.3(9) . . ?
C29 O5 Dy1 127.4(9) . . ?
C30 O6 C35 119.3(12) . . ?
C30 O6 Dy1 116.3(8) . . ?
C35 O6 Dy1 124.1(9) . . ?
C50 O7 Dy2 138.2(10) . . ?
C56 O8 C55 122(2) . . ?
C57 O9 Dy1 142.1(10) . . ?
C63 O10 C58 128(2) . . ?
C78 O11 Dy2 124.9(9) . . ?
C83 O12 C84 115.9(11) . . ?
C83 O12 Dy2 116.1(8) . . ?
C84 O12 Dy2 127.9(9) . . ?
C85 O13 Dy1 128.6(9) . . ?
C86 O14 C91 119.0(13) . . ?
C86 O14 Dy1 113.7(8) . . ?
C91 O14 Dy1 123.3(10) . . ?
C106 O15 Dy2 139.7(9) . . ?
C112 O16 C111 120.2(17) . . ?
C8 N1 C9 117.1(13) . . ?
C8 N1 Dy1 127.3(11) . . ?
C9 N1 Dy1 115.2(9) . . ?
C21 N2 C18 118.6(14) . . ?
C36 N3 C37 121.9(14) . . ?
C49 N4 C46 115.4(13) . . ?
C49 N4 Dy2 123.4(10) . . ?
C46 N4 Dy2 120.1(9) . . ?
C64 N5 C65 113.5(13) . . ?
C64 N5 Dy1 126.0(10) . . ?
C65 N5 Dy1 119.2(9) . . ?
C77 N6 C74 120.2(14) . . ?
C92 N7 C93 119.7(14) . . ?
C105 N8 C102 115.6(13) . . ?
C105 N8 Dy2 125.0(10) . . ?
C102 N8 Dy2 117.5(9) . . ?
C119 N9 C113 111.2(19) . . ?
C119 N9 C117 111.4(18) . . ?
C113 N9 C117 107.7(15) . . ?
C119 N9 C115 106.5(15) . . ?
C113 N9 C115 110.2(16) . . ?
C117 N9 C115 109.7(16) . . ?
C125 N10 C126 114(3) . . ?
C125 N10 C121 106(2) . . ?
C126 N10 C121 112(2) . . ?
C125 N10 C123 113(2) . . ?
C126 N10 C123 100.7(17) . . ?
C121 N10 C123 111(2) . . ?
O1 C1 C2 120.1(15) . . ?
O1 C1 C6 124.4(14) . . ?
C2 C1 C6 115.5(15) . . ?
O2 C2 C3 124.2(17) . . ?
O2 C2 C1 114.7(16) . . ?
C3 C2 C1 121.1(17) . . ?
C2 C3 C4 122.1(18) . . ?
C3 C4 C5 119.7(18) . . ?
C6 C5 C4 119.1(18) . . ?
C5 C6 C1 122.4(16) . . ?
C5 C6 C8 117.0(16) . . ?
C1 C6 C8 120.5(15) . . ?
N1 C8 C6 129.4(15) . . ?
C10 C9 N1 122.2(14) . . ?
C10 C9 C14 119.0(15) . . ?
N1 C9 C14 118.7(14) . . ?
C9 C10 C11 119.1(15) . . ?
C12 C11 C10 122.7(15) . . ?
C11 C12 C13 116.5(15) . . ?
C11 C12 C15 121.8(14) . . ?
C13 C12 C15 121.7(14) . . ?
C12 C13 C14 121.6(15) . . ?
C9 C14 C13 120.7(15) . . ?
C20 C15 C16 116.2(15) . . ?
C20 C15 C12 122.5(15) . . ?
C16 C15 C12 121.3(15) . . ?
C17 C16 C15 121.4(17) . . ?
C16 C17 C18 122.4(17) . . ?
C19 C18 N2 126.3(15) . . ?
C19 C18 C17 115.3(15) . . ?
N2 C18 C17 118.2(14) . . ?
C18 C19 C20 123.1(16) . . ?
C15 C20 C19 121.5(16) . . ?
N2 C21 C23 124.8(16) . . ?
O3 C22 C23 122.8(14) . . ?
O3 C22 C27 122.2(14) . . ?
C23 C22 C27 115.0(14) . . ?
C22 C23 C24 120.8(15) . . ?
C22 C23 C21 119.3(14) . . ?
C24 C23 C21 119.9(15) . . ?
C25 C24 C23 120.9(16) . . ?
C26 C25 C24 118.5(15) . . ?
C27 C26 C25 122.1(16) . . ?
C26 C27 O4 126.6(15) . . ?
C26 C27 C22 122.8(15) . . ?
O4 C27 C22 110.6(13) . . ?
O5 C29 C34 123.6(13) . . ?
O5 C29 C30 118.1(14) . . ?
C34 C29 C30 118.1(14) . . ?
O6 C30 C31 125.5(14) . . ?
O6 C30 C29 113.2(13) . . ?
C31 C30 C29 121.3(15) . . ?
C30 C31 C32 119.6(15) . . ?
C33 C32 C31 119.0(16) . . ?
C32 C33 C34 122.7(17) . . ?
C29 C34 C36 119.1(14) . . ?
C29 C34 C33 119.2(14) . . ?
C36 C34 C33 121.6(15) . . ?
N3 C36 C34 123.7(15) . . ?
C42 C37 C38 118.5(15) . . ?
C42 C37 N3 124.1(15) . . ?
C38 C37 N3 117.4(15) . . ?
C39 C38 C37 121.5(16) . . ?
C40 C39 C38 120.9(16) . . ?
C39 C40 C41 117.7(14) . . ?
C39 C40 C43 119.2(14) . . ?
C41 C40 C43 123.1(14) . . ?
C42 C41 C40 122.4(15) . . ?
C37 C42 C41 119.1(15) . . ?
C48 C43 C44 115.7(14) . . ?
C48 C43 C40 122.8(14) . . ?
C44 C43 C40 121.3(14) . . ?
C45 C44 C43 121.5(15) . . ?
C46 C45 C44 122.4(15) . . ?
C45 C46 C47 117.2(14) . . ?
C45 C46 N4 122.8(14) . . ?
C47 C46 N4 119.9(14) . . ?
C48 C47 C46 121.4(15) . . ?
C47 C48 C43 121.8(15) . . ?
N4 C49 C51 129.3(15) . . ?
O7 C50 C51 124.0(14) . . ?
O7 C50 C55 122.5(16) . . ?
C51 C50 C55 113.5(17) . . ?
C50 C51 C49 121.7(15) . . ?
C50 C51 C52 120.8(15) . . ?
C49 C51 C52 117.3(15) . . ?
C53 C52 C51 120.0(18) . . ?
C52 C53 C54 121.2(19) . . ?
C55 C54 C53 119.4(18) . . ?
O8 C55 C54 121.2(17) . . ?
O8 C55 C50 113.9(17) . . ?
C54 C55 C50 124.9(19) . . ?
O9 C57 C62 123.7(14) . . ?
O9 C57 C58 120.3(16) . . ?
C62 C57 C58 115.9(16) . . ?
O10 C58 C59 123.8(16) . . ?
O10 C58 C57 115.4(16) . . ?
C59 C58 C57 120.7(18) . . ?
C58 C59 C60 122.6(17) . . ?
C61 C60 C59 118.5(17) . . ?
C60 C61 C62 120.9(16) . . ?
C57 C62 C61 121.3(14) . . ?
C57 C62 C64 122.9(14) . . ?
C61 C62 C64 115.4(15) . . ?
N5 C64 C62 126.9(15) . . ?
C66 C65 C70 119.0(15) . . ?
C66 C65 N5 121.7(13) . . ?
C70 C65 N5 119.2(13) . . ?
C65 C66 C67 118.6(15) . . ?
C68 C67 C66 122.5(16) . . ?
C67 C68 C69 118.2(15) . . ?
C67 C68 C71 121.6(15) . . ?
C69 C68 C71 120.2(14) . . ?
C70 C69 C68 118.6(15) . . ?
C65 C70 C69 123.0(15) . . ?
C76 C71 C72 116.4(15) . . ?
C76 C71 C68 122.6(15) . . ?
C72 C71 C68 121.0(14) . . ?
C73 C72 C71 119.7(16) . . ?
C72 C73 C74 123.6(17) . . ?
N6 C74 C73 120.4(16) . . ?
N6 C74 C75 122.0(16) . . ?
C73 C74 C75 117.5(16) . . ?
C76 C75 C74 119.3(17) . . ?
C71 C76 C75 123.4(16) . . ?
N6 C77 C79 119.7(14) . . ?
O11 C78 C79 123.2(13) . . ?
O11 C78 C83 118.4(13) . . ?
C79 C78 C83 118.4(13) . . ?
C80 C79 C78 119.4(14) . . ?
C80 C79 C77 121.8(14) . . ?
C78 C79 C77 118.8(13) . . ?
C79 C80 C81 121.0(15) . . ?
C82 C81 C80 119.6(15) . . ?
C83 C82 C81 120.5(14) . . ?
C82 C83 O12 126.1(13) . . ?
C82 C83 C78 120.9(14) . . ?
O12 C83 C78 113.0(12) . . ?
O13 C85 C90 124.2(14) . . ?
O13 C85 C86 117.9(13) . . ?
C90 C85 C86 117.9(14) . . ?
O14 C86 C87 125.0(15) . . ?
O14 C86 C85 114.5(13) . . ?
C87 C86 C85 120.4(15) . . ?
C86 C87 C88 119.6(16) . . ?
C89 C88 C87 120.8(16) . . ?
C90 C89 C88 120.9(16) . . ?
C89 C90 C85 119.7(15) . . ?
C89 C90 C92 122.5(15) . . ?
C85 C90 C92 117.7(14) . . ?
N7 C92 C90 123.3(15) . . ?
C98 C93 C94 117.9(15) . . ?
C98 C93 N7 124.3(14) . . ?
C94 C93 N7 117.8(14) . . ?
C93 C94 C95 121.3(15) . . ?
C96 C95 C94 122.1(15) . . ?
C95 C96 C97 115.3(15) . . ?
C95 C96 C99 121.9(14) . . ?
C97 C96 C99 122.7(14) . . ?
C98 C97 C96 122.8(15) . . ?
C97 C98 C93 120.6(15) . . ?
C100 C99 C104 118.3(16) . . ?
C100 C99 C96 119.7(14) . . ?
C104 C99 C96 122.1(14) . . ?
C101 C100 C99 120.3(15) . . ?
C100 C101 C102 120.7(15) . . ?
C103 C102 C101 117.5(15) . . ?
C103 C102 N8 119.8(14) . . ?
C101 C102 N8 122.7(14) . . ?
C104 C103 C102 121.1(16) . . ?
C103 C104 C99 121.9(16) . . ?
N8 C105 C107 127.2(16) . . ?
C108 C107 C106 120.0(15) . . ?
C108 C107 C105 116.6(15) . . ?
C106 C107 C105 123.0(15) . . ?
O15 C106 C111 118.6(15) . . ?
O15 C106 C107 125.7(14) . . ?
C111 C106 C107 115.7(15) . . ?
C109 C108 C107 122.7(19) . . ?
C108 C109 C110 118.4(19) . . ?
C111 C110 C109 121.7(18) . . ?
C110 C111 C106 121.5(18) . . ?
C110 C111 O16 123.0(16) . . ?
C106 C111 O16 115.5(15) . . ?
N9 C113 C114 117.8(18) . . ?
C116 C115 N9 115.0(15) . . ?
N9 C117 C118 117.9(18) . . ?
N9 C119 C120 116.7(18) . . ?
C122 C121 N10 117(2) . . ?
C124 C123 N10 113.2(19) . . ?
N10 C125 C128 114(3) . . ?
C127 C126 N10 113(2) . . ?
N11 C129 O17 130(3) . . ?
C129 N11 C130 121.9(18) . . ?
C129 N11 C131 120.7(18) . . ?
C130 N11 C131 117(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O9 Dy1 O1 C1 -129.7(18) . . . . ?
O13 Dy1 O1 C1 93.9(18) . . . . ?
O5 Dy1 O1 C1 -28(2) . . . . ?
N5 Dy1 O1 C1 173.2(16) . . . . ?
O6 Dy1 O1 C1 -57.6(18) . . . . ?
O14 Dy1 O1 C1 151.6(19) . . . . ?
N1 Dy1 O1 C1 19.7(18) . . . . ?
O15 Dy2 O3 C22 71.8(11) . . . . ?
O7 Dy2 O3 C22 -25.4(13) . . . . ?
O11 Dy2 O3 C22 -146.0(11) . . . . ?
O12 Dy2 O3 C22 151.0(10) . . . . ?
N4 Dy2 O3 C22 -68.8(11) . . . . ?
N8 Dy2 O3 C22 141.9(11) . . . . ?
O4 Dy2 O3 C22 10.1(10) . . . . ?
O15 Dy2 O4 C27 -118.8(11) . . . . ?
O7 Dy2 O4 C27 147.4(10) . . . . ?
O11 Dy2 O4 C27 62.5(14) . . . . ?
O3 Dy2 O4 C27 -6.7(9) . . . . ?
O12 Dy2 O4 C27 -166.3(9) . . . . ?
N4 Dy2 O4 C27 72.8(10) . . . . ?
N8 Dy2 O4 C27 -67.4(11) . . . . ?
O15 Dy2 O4 C28 45.0(12) . . . . ?
O7 Dy2 O4 C28 -48.7(12) . . . . ?
O11 Dy2 O4 C28 -133.6(12) . . . . ?
O3 Dy2 O4 C28 157.2(13) . . . . ?
O12 Dy2 O4 C28 -2.4(14) . . . . ?
N4 Dy2 O4 C28 -123.3(12) . . . . ?
N8 Dy2 O4 C28 96.5(12) . . . . ?
O1 Dy1 O5 C29 -20.7(13) . . . . ?
O9 Dy1 O5 C29 76.1(12) . . . . ?
O13 Dy1 O5 C29 -141.2(11) . . . . ?
N5 Dy1 O5 C29 146.8(12) . . . . ?
O6 Dy1 O5 C29 11.1(11) . . . . ?
O14 Dy1 O5 C29 159.9(10) . . . . ?
N1 Dy1 O5 C29 -66.8(11) . . . . ?
O1 Dy1 O6 C30 148.1(11) . . . . ?
O9 Dy1 O6 C30 -118.1(11) . . . . ?
O13 Dy1 O6 C30 64.3(14) . . . . ?
O5 Dy1 O6 C30 -7.8(10) . . . . ?
N5 Dy1 O6 C30 -65.9(11) . . . . ?
O14 Dy1 O6 C30 -171.6(9) . . . . ?
N1 Dy1 O6 C30 74.3(11) . . . . ?
O1 Dy1 O6 C35 -39.3(12) . . . . ?
O9 Dy1 O6 C35 54.5(12) . . . . ?
O13 Dy1 O6 C35 -123.0(12) . . . . ?
O5 Dy1 O6 C35 164.8(13) . . . . ?
N5 Dy1 O6 C35 106.8(12) . . . . ?
O14 Dy1 O6 C35 1.0(14) . . . . ?
N1 Dy1 O6 C35 -113.0(13) . . . . ?
O15 Dy2 O7 C50 -105.9(16) . . . . ?
O11 Dy2 O7 C50 118.5(16) . . . . ?
O3 Dy2 O7 C50 -4.2(18) . . . . ?
O12 Dy2 O7 C50 177.4(17) . . . . ?
N4 Dy2 O7 C50 39.8(16) . . . . ?
N8 Dy2 O7 C50 -163.0(14) . . . . ?
O4 Dy2 O7 C50 -36.5(16) . . . . ?
O1 Dy1 O9 C57 -121.4(17) . . . . ?
O13 Dy1 O9 C57 -17.0(19) . . . . ?
O5 Dy1 O9 C57 106.3(17) . . . . ?
N5 Dy1 O9 C57 27.3(16) . . . . ?
O6 Dy1 O9 C57 164.7(17) . . . . ?
O14 Dy1 O9 C57 -50.9(17) . . . . ?
N1 Dy1 O9 C57 -175.0(15) . . . . ?
O15 Dy2 O11 C78 -20.6(13) . . . . ?
O7 Dy2 O11 C78 77.8(11) . . . . ?
O3 Dy2 O11 C78 -141.9(10) . . . . ?
O12 Dy2 O11 C78 14.7(10) . . . . ?
N4 Dy2 O11 C78 147.6(11) . . . . ?
N8 Dy2 O11 C78 -64.6(11) . . . . ?
O4 Dy2 O11 C78 157.6(10) . . . . ?
O15 Dy2 O12 C83 143.1(11) . . . . ?
O7 Dy2 O12 C83 -123.6(11) . . . . ?
O11 Dy2 O12 C83 -12.0(10) . . . . ?
O3 Dy2 O12 C83 59.2(14) . . . . ?
N4 Dy2 O12 C83 -73.1(11) . . . . ?
N8 Dy2 O12 C83 68.6(10) . . . . ?
O4 Dy2 O12 C83 -171.8(10) . . . . ?
O15 Dy2 O12 C84 -37.1(13) . . . . ?
O7 Dy2 O12 C84 56.2(13) . . . . ?
O11 Dy2 O12 C84 167.8(14) . . . . ?
O3 Dy2 O12 C84 -121.0(13) . . . . ?
N4 Dy2 O12 C84 106.7(13) . . . . ?
N8 Dy2 O12 C84 -111.7(13) . . . . ?
O4 Dy2 O12 C84 8.0(15) . . . . ?
O1 Dy1 O13 C85 53.4(12) . . . . ?
O9 Dy1 O13 C85 -46.2(14) . . . . ?
O5 Dy1 O13 C85 -167.4(12) . . . . ?
N5 Dy1 O13 C85 -89.8(12) . . . . ?
O6 Dy1 O13 C85 130.4(11) . . . . ?
O14 Dy1 O13 C85 -8.7(11) . . . . ?
N1 Dy1 O13 C85 120.7(12) . . . . ?
O1 Dy1 O14 C86 -105.2(10) . . . . ?
O9 Dy1 O14 C86 162.2(10) . . . . ?
O13 Dy1 O14 C86 7.9(9) . . . . ?
O5 Dy1 O14 C86 74.3(13) . . . . ?
N5 Dy1 O14 C86 87.7(10) . . . . ?
O6 Dy1 O14 C86 -146.5(9) . . . . ?
N1 Dy1 O14 C86 -52.1(10) . . . . ?
O1 Dy1 O14 C91 52.0(12) . . . . ?
O9 Dy1 O14 C91 -40.5(12) . . . . ?
O13 Dy1 O14 C91 165.1(13) . . . . ?
O5 Dy1 O14 C91 -128.4(13) . . . . ?
N5 Dy1 O14 C91 -115.0(12) . . . . ?
O6 Dy1 O14 C91 10.8(14) . . . . ?
N1 Dy1 O14 C91 105.2(12) . . . . ?
O7 Dy2 O15 C106 -119.6(17) . . . . ?
O11 Dy2 O15 C106 -16.6(19) . . . . ?
O3 Dy2 O15 C106 106.9(16) . . . . ?
O12 Dy2 O15 C106 -49.2(16) . . . . ?
N4 Dy2 O15 C106 -177.9(14) . . . . ?
N8 Dy2 O15 C106 28.3(16) . . . . ?
O4 Dy2 O15 C106 164.2(17) . . . . ?
O1 Dy1 N1 C8 -9.9(13) . . . . ?
O9 Dy1 N1 C8 48.7(16) . . . . ?
O13 Dy1 N1 C8 -115.8(14) . . . . ?
O5 Dy1 N1 C8 135.3(14) . . . . ?
N5 Dy1 N1 C8 -165.6(12) . . . . ?
O6 Dy1 N1 C8 69.0(13) . . . . ?
O14 Dy1 N1 C8 -63.2(14) . . . . ?
O1 Dy1 N1 C9 177.9(11) . . . . ?
O9 Dy1 N1 C9 -123.5(11) . . . . ?
O13 Dy1 N1 C9 72.0(10) . . . . ?
O5 Dy1 N1 C9 -36.9(10) . . . . ?
N5 Dy1 N1 C9 22.1(13) . . . . ?
O6 Dy1 N1 C9 -103.2(11) . . . . ?
O14 Dy1 N1 C9 124.6(10) . . . . ?
O15 Dy2 N4 C49 38.4(15) . . . . ?
O7 Dy2 N4 C49 -25.3(12) . . . . ?
O11 Dy2 N4 C49 -128.4(12) . . . . ?
O3 Dy2 N4 C49 122.8(12) . . . . ?
O12 Dy2 N4 C49 -75.3(12) . . . . ?
N8 Dy2 N4 C49 176.5(10) . . . . ?
O4 Dy2 N4 C49 55.9(12) . . . . ?
O15 Dy2 N4 C46 -128.9(11) . . . . ?
O7 Dy2 N4 C46 167.5(11) . . . . ?
O11 Dy2 N4 C46 64.4(10) . . . . ?
O3 Dy2 N4 C46 -44.4(10) . . . . ?
O12 Dy2 N4 C46 117.4(10) . . . . ?
N8 Dy2 N4 C46 9.2(13) . . . . ?
O4 Dy2 N4 C46 -111.3(11) . . . . ?
O1 Dy1 N5 C64 40.7(15) . . . . ?
O9 Dy1 N5 C64 -21.0(12) . . . . ?
O13 Dy1 N5 C64 128.6(13) . . . . ?
O5 Dy1 N5 C64 -123.4(13) . . . . ?
O6 Dy1 N5 C64 -73.3(13) . . . . ?
O14 Dy1 N5 C64 61.7(12) . . . . ?
N1 Dy1 N5 C64 179.6(11) . . . . ?
O1 Dy1 N5 C65 -126.0(10) . . . . ?
O9 Dy1 N5 C65 172.2(10) . . . . ?
O13 Dy1 N5 C65 -38.1(9) . . . . ?
O5 Dy1 N5 C65 69.9(10) . . . . ?
O6 Dy1 N5 C65 120.0(9) . . . . ?
O14 Dy1 N5 C65 -105.0(10) . . . . ?
N1 Dy1 N5 C65 12.9(13) . . . . ?
O15 Dy2 N8 C105 -25.0(12) . . . . ?
O7 Dy2 N8 C105 36.9(15) . . . . ?
O11 Dy2 N8 C105 123.8(13) . . . . ?
O3 Dy2 N8 C105 -127.6(12) . . . . ?
O12 Dy2 N8 C105 56.2(12) . . . . ?
N4 Dy2 N8 C105 -178.8(11) . . . . ?
O4 Dy2 N8 C105 -75.5(13) . . . . ?
O15 Dy2 N8 C102 171.2(11) . . . . ?
O7 Dy2 N8 C102 -126.8(10) . . . . ?
O11 Dy2 N8 C102 -39.9(10) . . . . ?
O3 Dy2 N8 C102 68.7(10) . . . . ?
O12 Dy2 N8 C102 -107.5(10) . . . . ?
N4 Dy2 N8 C102 17.5(13) . . . . ?
O4 Dy2 N8 C102 120.8(9) . . . . ?
Dy1 O1 C1 C2 160.1(14) . . . . ?
Dy1 O1 C1 C6 -19(3) . . . . ?
C7 O2 C2 C3 14(4) . . . . ?
C7 O2 C2 C1 -168(2) . . . . ?
O1 C1 C2 O2 -1(3) . . . . ?
C6 C1 C2 O2 178.6(16) . . . . ?
O1 C1 C2 C3 178.1(17) . . . . ?
C6 C1 C2 C3 -3(3) . . . . ?
O2 C2 C3 C4 179.3(19) . . . . ?
C1 C2 C3 C4 1(3) . . . . ?
C2 C3 C4 C5 1(3) . . . . ?
C3 C4 C5 C6 -1(3) . . . . ?
C4 C5 C6 C1 -1(3) . . . . ?
C4 C5 C6 C8 -179.4(18) . . . . ?
O1 C1 C6 C5 -177.8(16) . . . . ?
C2 C1 C6 C5 3(2) . . . . ?
O1 C1 C6 C8 0(3) . . . . ?
C2 C1 C6 C8 -179.0(15) . . . . ?
C9 N1 C8 C6 175.9(16) . . . . ?
Dy1 N1 C8 C6 4(3) . . . . ?
C5 C6 C8 N1 -177.8(18) . . . . ?
C1 C6 C8 N1 4(3) . . . . ?
C8 N1 C9 C10 -47(2) . . . . ?
Dy1 N1 C9 C10 126.0(14) . . . . ?
C8 N1 C9 C14 135.4(16) . . . . ?
Dy1 N1 C9 C14 -51.6(17) . . . . ?
N1 C9 C10 C11 179.3(15) . . . . ?
C14 C9 C10 C11 -3(2) . . . . ?
C9 C10 C11 C12 -2(3) . . . . ?
C10 C11 C12 C13 6(3) . . . . ?
C10 C11 C12 C15 -174.4(15) . . . . ?
C11 C12 C13 C14 -5(2) . . . . ?
C15 C12 C13 C14 175.5(14) . . . . ?
C10 C9 C14 C13 4(2) . . . . ?
N1 C9 C14 C13 -178.2(14) . . . . ?
C12 C13 C14 C9 0(2) . . . . ?
C11 C12 C15 C20 -149.1(17) . . . . ?
C13 C12 C15 C20 30(2) . . . . ?
C11 C12 C15 C16 29(2) . . . . ?
C13 C12 C15 C16 -151.5(17) . . . . ?
C20 C15 C16 C17 1(3) . . . . ?
C12 C15 C16 C17 -177.3(18) . . . . ?
C15 C16 C17 C18 -1(3) . . . . ?
C21 N2 C18 C19 -26(3) . . . . ?
C21 N2 C18 C17 159.4(17) . . . . ?
C16 C17 C18 C19 -1(3) . . . . ?
C16 C17 C18 N2 174.6(19) . . . . ?
N2 C18 C19 C20 -171.7(16) . . . . ?
C17 C18 C19 C20 3(3) . . . . ?
C16 C15 C20 C19 2(3) . . . . ?
C12 C15 C20 C19 179.7(16) . . . . ?
C18 C19 C20 C15 -4(3) . . . . ?
C18 N2 C21 C23 174.2(14) . . . . ?
Dy2 O3 C22 C23 168.4(11) . . . . ?
Dy2 O3 C22 C27 -13(2) . . . . ?
O3 C22 C23 C24 175.7(14) . . . . ?
C27 C22 C23 C24 -3(2) . . . . ?
O3 C22 C23 C21 -5(2) . . . . ?
C27 C22 C23 C21 175.9(13) . . . . ?
N2 C21 C23 C22 176.4(15) . . . . ?
N2 C21 C23 C24 -5(3) . . . . ?
C22 C23 C24 C25 2(2) . . . . ?
C21 C23 C24 C25 -177.3(15) . . . . ?
C23 C24 C25 C26 0(3) . . . . ?
C24 C25 C26 C27 -1(3) . . . . ?
C25 C26 C27 O4 178.4(15) . . . . ?
C25 C26 C27 C22 -1(3) . . . . ?
C28 O4 C27 C26 19(2) . . . . ?
Dy2 O4 C27 C26 -175.8(14) . . . . ?
C28 O4 C27 C22 -162.0(13) . . . . ?
Dy2 O4 C27 C22 3.6(15) . . . . ?
O3 C22 C27 C26 -176.0(15) . . . . ?
C23 C22 C27 C26 3(2) . . . . ?
O3 C22 C27 O4 5(2) . . . . ?
C23 C22 C27 O4 -176.7(13) . . . . ?
Dy1 O5 C29 C34 170.6(11) . . . . ?
Dy1 O5 C29 C30 -13.3(19) . . . . ?
C35 O6 C30 C31 10(2) . . . . ?
Dy1 O6 C30 C31 -176.6(14) . . . . ?
C35 O6 C30 C29 -168.2(14) . . . . ?
Dy1 O6 C30 C29 4.8(16) . . . . ?
O5 C29 C30 O6 4(2) . . . . ?
C34 C29 C30 O6 -179.8(13) . . . . ?
O5 C29 C30 C31 -174.7(15) . . . . ?
C34 C29 C30 C31 2(2) . . . . ?
O6 C30 C31 C32 -178.9(16) . . . . ?
C29 C30 C31 C32 0(3) . . . . ?
C30 C31 C32 C33 0(3) . . . . ?
C31 C32 C33 C34 -1(3) . . . . ?
O5 C29 C34 C36 -11(2) . . . . ?
C30 C29 C34 C36 173.3(14) . . . . ?
O5 C29 C34 C33 173.9(14) . . . . ?
C30 C29 C34 C33 -2(2) . . . . ?
C32 C33 C34 C29 2(3) . . . . ?
C32 C33 C34 C36 -173.6(17) . . . . ?
C37 N3 C36 C34 175.4(15) . . . . ?
C29 C34 C36 N3 177.4(16) . . . . ?
C33 C34 C36 N3 -7(3) . . . . ?
C36 N3 C37 C42 36(3) . . . . ?
C36 N3 C37 C38 -143.1(18) . . . . ?
C42 C37 C38 C39 0(3) . . . . ?
N3 C37 C38 C39 179.6(17) . . . . ?
C37 C38 C39 C40 -1(3) . . . . ?
C38 C39 C40 C41 1(3) . . . . ?
C38 C39 C40 C43 -175.8(17) . . . . ?
C39 C40 C41 C42 -1(3) . . . . ?
C43 C40 C41 C42 175.8(15) . . . . ?
C38 C37 C42 C41 0(3) . . . . ?
N3 C37 C42 C41 -179.3(15) . . . . ?
C40 C41 C42 C37 1(3) . . . . ?
C39 C40 C43 C48 152.8(17) . . . . ?
C41 C40 C43 C48 -24(2) . . . . ?
C39 C40 C43 C44 -23(2) . . . . ?
C41 C40 C43 C44 160.4(16) . . . . ?
C48 C43 C44 C45 2(2) . . . . ?
C40 C43 C44 C45 178.0(15) . . . . ?
C43 C44 C45 C46 0(3) . . . . ?
C44 C45 C46 C47 -2(3) . . . . ?
C44 C45 C46 N4 -178.8(15) . . . . ?
C49 N4 C46 C45 -44(2) . . . . ?
Dy2 N4 C46 C45 124.6(14) . . . . ?
C49 N4 C46 C47 139.2(16) . . . . ?
Dy2 N4 C46 C47 -52.6(18) . . . . ?
C45 C46 C47 C48 2(3) . . . . ?
N4 C46 C47 C48 179.1(15) . . . . ?
C46 C47 C48 C43 0(3) . . . . ?
C44 C43 C48 C47 -2(2) . . . . ?
C40 C43 C48 C47 -177.8(15) . . . . ?
C46 N4 C49 C51 -179.9(15) . . . . ?
Dy2 N4 C49 C51 12(2) . . . . ?
Dy2 O7 C50 C51 -35(3) . . . . ?
Dy2 O7 C50 C55 142.8(14) . . . . ?
O7 C50 C51 C49 -3(3) . . . . ?
C55 C50 C51 C49 179.6(15) . . . . ?
O7 C50 C51 C52 -178.1(15) . . . . ?
C55 C50 C51 C52 4(2) . . . . ?
N4 C49 C51 C50 9(3) . . . . ?
N4 C49 C51 C52 -175.7(15) . . . . ?
C50 C51 C52 C53 -3(2) . . . . ?
C49 C51 C52 C53 -179.0(16) . . . . ?
C51 C52 C53 C54 -1(3) . . . . ?
C52 C53 C54 C55 5(3) . . . . ?
C56 O8 C55 C54 56(4) . . . . ?
C56 O8 C55 C50 -126(3) . . . . ?
C53 C54 C55 O8 175(2) . . . . ?
C53 C54 C55 C50 -4(3) . . . . ?
O7 C50 C55 O8 3(3) . . . . ?
C51 C50 C55 O8 -179.1(16) . . . . ?
O7 C50 C55 C54 -178.6(19) . . . . ?
C51 C50 C55 C54 -1(3) . . . . ?
Dy1 O9 C57 C62 -21(3) . . . . ?
Dy1 O9 C57 C58 163.5(12) . . . . ?
C63 O10 C58 C59 29(5) . . . . ?
C63 O10 C58 C57 -151(4) . . . . ?
O9 C57 C58 O10 0(2) . . . . ?
C62 C57 C58 O10 -176.3(15) . . . . ?
O9 C57 C58 C59 179.1(16) . . . . ?
C62 C57 C58 C59 3(2) . . . . ?
O10 C58 C59 C60 176.4(17) . . . . ?
C57 C58 C59 C60 -3(3) . . . . ?
C58 C59 C60 C61 1(3) . . . . ?
C59 C60 C61 C62 0(2) . . . . ?
O9 C57 C62 C61 -177.9(14) . . . . ?
C58 C57 C62 C61 -2(2) . . . . ?
O9 C57 C62 C64 -5(2) . . . . ?
C58 C57 C62 C64 171.0(14) . . . . ?
C60 C61 C62 C57 1(2) . . . . ?
C60 C61 C62 C64 -172.7(14) . . . . ?
C65 N5 C64 C62 -178.6(13) . . . . ?
Dy1 N5 C64 C62 14(2) . . . . ?
C57 C62 C64 N5 4(2) . . . . ?
C61 C62 C64 N5 177.5(15) . . . . ?
C64 N5 C65 C66 -46(2) . . . . ?
Dy1 N5 C65 C66 122.2(14) . . . . ?
C64 N5 C65 C70 138.8(15) . . . . ?
Dy1 N5 C65 C70 -52.9(16) . . . . ?
C70 C65 C66 C67 -4(2) . . . . ?
N5 C65 C66 C67 -179.3(14) . . . . ?
C65 C66 C67 C68 3(3) . . . . ?
C66 C67 C68 C69 -1(3) . . . . ?
C66 C67 C68 C71 176.6(15) . . . . ?
C67 C68 C69 C70 0(2) . . . . ?
C71 C68 C69 C70 -177.3(14) . . . . ?
C66 C65 C70 C69 4(2) . . . . ?
N5 C65 C70 C69 179.1(14) . . . . ?
C68 C69 C70 C65 -2(2) . . . . ?
C67 C68 C71 C76 150.1(18) . . . . ?
C69 C68 C71 C76 -32(2) . . . . ?
C67 C68 C71 C72 -31(2) . . . . ?
C69 C68 C71 C72 146.3(17) . . . . ?
C76 C71 C72 C73 1(3) . . . . ?
C68 C71 C72 C73 -177.7(16) . . . . ?
C71 C72 C73 C74 0(3) . . . . ?
C77 N6 C74 C73 -142.3(18) . . . . ?
C77 N6 C74 C75 41(3) . . . . ?
C72 C73 C74 N6 -178.2(17) . . . . ?
C72 C73 C74 C75 -1(3) . . . . ?
N6 C74 C75 C76 177.0(16) . . . . ?
C73 C74 C75 C76 0(3) . . . . ?
C72 C71 C76 C75 -2(3) . . . . ?
C68 C71 C76 C75 176.5(16) . . . . ?
C74 C75 C76 C71 2(3) . . . . ?
C74 N6 C77 C79 174.9(15) . . . . ?
Dy2 O11 C78 C79 164.4(11) . . . . ?
Dy2 O11 C78 C83 -16.4(18) . . . . ?
O11 C78 C79 C80 175.1(15) . . . . ?
C83 C78 C79 C80 -4(2) . . . . ?
O11 C78 C79 C77 -6(2) . . . . ?
C83 C78 C79 C77 174.6(14) . . . . ?
N6 C77 C79 C80 -7(2) . . . . ?
N6 C77 C79 C78 174.5(15) . . . . ?
C78 C79 C80 C81 1(3) . . . . ?
C77 C79 C80 C81 -177.5(17) . . . . ?
C79 C80 C81 C82 3(3) . . . . ?
C80 C81 C82 C83 -3(3) . . . . ?
C81 C82 C83 O12 -178.3(17) . . . . ?
C81 C82 C83 C78 0(3) . . . . ?
C84 O12 C83 C82 8(2) . . . . ?
Dy2 O12 C83 C82 -172.4(15) . . . . ?
C84 O12 C83 C78 -170.9(14) . . . . ?
Dy2 O12 C83 C78 8.9(17) . . . . ?
O11 C78 C83 C82 -175.9(15) . . . . ?
C79 C78 C83 C82 3(2) . . . . ?
O11 C78 C83 O12 3(2) . . . . ?
C79 C78 C83 O12 -177.7(14) . . . . ?
Dy1 O13 C85 C90 -174.5(11) . . . . ?
Dy1 O13 C85 C86 8.3(19) . . . . ?
C91 O14 C86 C87 10(2) . . . . ?
Dy1 O14 C86 C87 168.7(14) . . . . ?
C91 O14 C86 C85 -165.6(14) . . . . ?
Dy1 O14 C86 C85 -7.3(15) . . . . ?
O13 C85 C86 O14 1(2) . . . . ?
C90 C85 C86 O14 -176.5(13) . . . . ?
O13 C85 C86 C87 -175.2(15) . . . . ?
C90 C85 C86 C87 7(2) . . . . ?
O14 C86 C87 C88 -176.3(16) . . . . ?
C85 C86 C87 C88 -1(3) . . . . ?
C86 C87 C88 C89 -4(3) . . . . ?
C87 C88 C89 C90 3(3) . . . . ?
C88 C89 C90 C85 4(3) . . . . ?
C88 C89 C90 C92 -173.2(17) . . . . ?
O13 C85 C90 C89 173.7(14) . . . . ?
C86 C85 C90 C89 -9(2) . . . . ?
O13 C85 C90 C92 -9(2) . . . . ?
C86 C85 C90 C92 168.5(14) . . . . ?
C93 N7 C92 C90 176.8(14) . . . . ?
C89 C90 C92 N7 2(3) . . . . ?
C85 C90 C92 N7 -176.0(15) . . . . ?
C92 N7 C93 C98 -20(2) . . . . ?
C92 N7 C93 C94 163.4(15) . . . . ?
C98 C93 C94 C95 1(2) . . . . ?
N7 C93 C94 C95 178.6(14) . . . . ?
C93 C94 C95 C96 -2(2) . . . . ?
C94 C95 C96 C97 1(2) . . . . ?
C94 C95 C96 C99 -177.6(15) . . . . ?
C95 C96 C97 C98 0(2) . . . . ?
C99 C96 C97 C98 178.7(15) . . . . ?
C96 C97 C98 C93 -1(3) . . . . ?
C94 C93 C98 C97 0(2) . . . . ?
N7 C93 C98 C97 -177.4(15) . . . . ?
C95 C96 C99 C100 36(2) . . . . ?
C97 C96 C99 C100 -142.0(16) . . . . ?
C95 C96 C99 C104 -145.4(17) . . . . ?
C97 C96 C99 C104 37(2) . . . . ?
C104 C99 C100 C101 0(2) . . . . ?
C96 C99 C100 C101 179.1(15) . . . . ?
C99 C100 C101 C102 3(3) . . . . ?
C100 C101 C102 C103 -5(2) . . . . ?
C100 C101 C102 N8 176.0(14) . . . . ?
C105 N8 C102 C103 142.4(15) . . . . ?
Dy2 N8 C102 C103 -52.3(17) . . . . ?
C105 N8 C102 C101 -39(2) . . . . ?
Dy2 N8 C102 C101 126.3(13) . . . . ?
C101 C102 C103 C104 5(2) . . . . ?
N8 C102 C103 C104 -176.5(15) . . . . ?
C102 C103 C104 C99 -2(3) . . . . ?
C100 C99 C104 C103 -1(3) . . . . ?
C96 C99 C104 C103 -179.6(16) . . . . ?
C102 N8 C105 C107 -178.1(15) . . . . ?
Dy2 N8 C105 C107 18(2) . . . . ?
N8 C105 C107 C108 177.4(17) . . . . ?
N8 C105 C107 C106 4(3) . . . . ?
Dy2 O15 C106 C111 159.6(13) . . . . ?
Dy2 O15 C106 C107 -19(3) . . . . ?
C108 C107 C106 O15 179.3(17) . . . . ?
C105 C107 C106 O15 -8(3) . . . . ?
C108 C107 C106 C111 0(2) . . . . ?
C105 C107 C106 C111 173.2(16) . . . . ?
C106 C107 C108 C109 1(3) . . . . ?
C105 C107 C108 C109 -172(2) . . . . ?
C107 C108 C109 C110 0(3) . . . . ?
C108 C109 C110 C111 -2(3) . . . . ?
C109 C110 C111 C106 3(3) . . . . ?
C109 C110 C111 O16 -179(2) . . . . ?
O15 C106 C111 C110 178.8(17) . . . . ?
C107 C106 C111 C110 -2(3) . . . . ?
O15 C106 C111 O16 1(2) . . . . ?
C107 C106 C111 O16 179.9(16) . . . . ?
C112 O16 C111 C110 8(3) . . . . ?
C112 O16 C111 C106 -174(2) . . . . ?
C119 N9 C113 C114 61(3) . . . . ?
C117 N9 C113 C114 -177(2) . . . . ?
C115 N9 C113 C114 -57(3) . . . . ?
C119 N9 C115 C116 180(2) . . . . ?
C113 N9 C115 C116 -59(2) . . . . ?
C117 N9 C115 C116 59(2) . . . . ?
C119 N9 C117 C118 -56(3) . . . . ?
C113 N9 C117 C118 -179(2) . . . . ?
C115 N9 C117 C118 61(2) . . . . ?
C113 N9 C119 C120 60(3) . . . . ?
C117 N9 C119 C120 -61(3) . . . . ?
C115 N9 C119 C120 180(2) . . . . ?
C125 N10 C121 C122 176(3) . . . . ?
C126 N10 C121 C122 -59(4) . . . . ?
C123 N10 C121 C122 53(3) . . . . ?
C125 N10 C123 C124 -56(4) . . . . ?
C126 N10 C123 C124 -178(3) . . . . ?
C121 N10 C123 C124 63(3) . . . . ?
C126 N10 C125 C128 59(4) . . . . ?
C121 N10 C125 C128 -177(3) . . . . ?
C123 N10 C125 C128 -56(4) . . . . ?
C125 N10 C126 C127 63(4) . . . . ?
C121 N10 C126 C127 -57(4) . . . . ?
C123 N10 C126 C127 -175(3) . . . . ?
O17 C129 N11 C130 -3(7) . . . . ?
O17 C129 N11 C131 179(5) . . . . ?

_diffrn_measured_fraction_theta_max 0.981
_diffrn_reflns_theta_full        22.04
_diffrn_measured_fraction_theta_full 0.981
_refine_diff_density_max         0.580
_refine_diff_density_min         -0.483
_refine_diff_density_rms         0.158

# Attachment 'web_deposit_cif_file_1_FatemahHabib_1300815031.cif'

data_mm050
_database_code_depnum_ccdc_archive 'CCDC 818519'
#TrackingRef 'web_deposit_cif_file_1_FatemahHabib_1300815031.cif'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C144.50 H165 Dy2 N10 O19.50'
_chemical_formula_weight         2678.87

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.7840(15)
_cell_length_b                   22.870(3)
_cell_length_c                   52.230(6)
_cell_angle_alpha                90.00
_cell_angle_beta                 95.811(6)
_cell_angle_gamma                90.00
_cell_volume                     14003(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    200(2)
_cell_measurement_reflns_used    9426
_cell_measurement_theta_min      2.19
_cell_measurement_theta_max      28.25

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.271
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             5560
_exptl_absorpt_coefficient_mu    1.125
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7662
_exptl_absorpt_correction_T_max  0.8231
_exptl_absorpt_process_details   'SADABS, Bruker (2003)'

_exptl_special_details           
;
Data collection is performed with three batch runs at phi = 0.00 deg
(650 frames), at phi = 120.00 deg (650 frames), and at phi = 240.00 deg
(650 frames).
Frame width = 0.30 deg in omega.
Data is merged, corrected for decay (if any), and treated with multi-scan
absorption corrections (if required). All symmetry-equivalent reflections
are merged for centrosymmetric data.
Friedel pairs are not merged for noncentrosymmetric data.
;

_diffrn_ambient_temperature      200(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            78362
_diffrn_reflns_av_R_equivalents  0.0500
_diffrn_reflns_av_sigmaI/netI    0.0443
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_l_min       -54
_diffrn_reflns_limit_l_max       50
_diffrn_reflns_theta_min         1.19
_diffrn_reflns_theta_max         21.97
_reflns_number_total             16998
_reflns_number_gt                14873
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'APEX II, Bruker (2009)'
_computing_cell_refinement       'APEX II, Bruker (2009)'
_computing_data_reduction        'XPREP, Bruker (2009)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'SHELXTL, Bruker (2004)'
_computing_publication_material  'SHELXTL, Bruker (2004)'

_refine_special_details          
;
Refinement of F² against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F², conventional R-factors R are based
on F, with F set to zero for negative F². The threshold expression of
F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F² are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0804P)²+192.8070P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         16998
_refine_ls_number_parameters     1569
_refine_ls_number_restraints     13
_refine_ls_R_factor_all          0.0877
_refine_ls_R_factor_gt           0.0763
_refine_ls_wR_factor_ref         0.1963
_refine_ls_wR_factor_gt          0.1893
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_restrained_S_all      1.040
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.23437(4) 0.23271(2) 0.234370(9) 0.03230(17) Uani 1 1 d . . .
Dy2 Dy 0.51854(4) 0.24840(2) 0.526707(9) 0.03145(16) Uani 1 1 d . . .
N1 N 0.1587(7) 0.0680(4) 0.32736(16) 0.035(2) Uani 1 1 d . . .
N2 N 0.4079(7) 0.1511(4) 0.51293(15) 0.032(2) Uani 1 1 d . . .
N3 N 0.0611(8) 0.2736(4) 0.25725(16) 0.037(2) Uani 1 1 d . . .
N4 N 0.1345(8) 0.3380(4) 0.44462(18) 0.046(2) Uani 1 1 d . . .
N5 N 0.4839(8) 0.4091(4) 0.31603(17) 0.042(2) Uani 1 1 d . . .
N6 N 0.6128(7) 0.3445(4) 0.50998(15) 0.032(2) Uani 1 1 d . . .
N7 N 0.4422(7) 0.1922(4) 0.24538(14) 0.035(2) Uani 1 1 d . . .
N8 N 0.7537(8) 0.1575(4) 0.43199(16) 0.039(2) Uani 1 1 d . . .
N9 N 0.5290(8) 0.2646(5) 0.0310(2) 0.058(3) Uani 1 1 d . . .
N10 N 0.3283(8) 0.9839(4) 0.25026(19) 0.048(2) Uani 1 1 d . . .
O1 O 0.2075(6) 0.1596(3) 0.26221(12) 0.0334(16) Uani 1 1 d . . .
O2 O 0.0601(6) 0.1680(3) 0.22221(13) 0.0410(18) Uani 1 1 d . . .
O3 O 0.4229(7) 0.2193(3) 0.55847(13) 0.047(2) Uani 1 1 d . . .
O4 O 0.3546(9) 0.2333(5) 0.60685(17) 0.074(3) Uani 1 1 d . . .
O5 O 0.1314(7) 0.2899(3) 0.20650(14) 0.0476(19) Uani 1 1 d . . .
O6 O 0.1004(8) 0.3477(4) 0.16288(14) 0.057(2) Uani 1 1 d . . .
O7 O 0.3666(6) 0.2853(3) 0.50310(12) 0.0334(16) Uani 1 1 d . . .
O8 O 0.4272(6) 0.3449(3) 0.54431(14) 0.0449(19) Uani 1 1 d . . .
O9 O 0.3170(6) 0.3043(3) 0.25958(13) 0.0349(17) Uani 1 1 d . . .
O10 O 0.3731(7) 0.2981(3) 0.21330(12) 0.0442(19) Uani 1 1 d . . .
O11 O 0.6543(7) 0.2778(3) 0.55541(13) 0.048(2) Uani 1 1 d . . .
O12 O 0.7600(8) 0.2668(4) 0.60177(13) 0.059(2) Uani 1 1 d . . .
O13 O 0.2761(7) 0.1784(3) 0.20172(14) 0.051(2) Uani 1 1 d . . .
O14 O 0.2104(9) 0.1164(4) 0.16026(16) 0.073(3) Uani 1 1 d . . .
O15 O 0.6260(6) 0.2124(3) 0.49770(12) 0.0334(16) Uani 1 1 d . . .
O16 O 0.6442(6) 0.1562(3) 0.54072(12) 0.0388(18) Uani 1 1 d . . .
C1 C 0.1104(8) 0.1318(4) 0.2633(2) 0.034(3) Uani 1 1 d . . .
C2 C 0.0259(9) 0.1342(5) 0.24161(19) 0.037(3) Uani 1 1 d . . .
C3 C -0.0757(10) 0.1065(5) 0.2418(2) 0.048(3) Uani 1 1 d . . .
H3A H -0.1317 0.1096 0.2274 0.057 Uiso 1 1 calc R . .
C4 C -0.0975(10) 0.0736(6) 0.2631(2) 0.056(3) Uani 1 1 d . . .
H4A H -0.1677 0.0532 0.2631 0.067 Uiso 1 1 calc R . .
C5 C -0.0199(10) 0.0705(5) 0.2840(2) 0.045(3) Uani 1 1 d . . .
H5A H -0.0375 0.0486 0.2985 0.055 Uiso 1 1 calc R . .
C6 C 0.0858(9) 0.0987(4) 0.2847(2) 0.034(2) Uani 1 1 d . . .
C7 C -0.0059(11) 0.1661(6) 0.1975(2) 0.061(4) Uani 1 1 d . . .
H7A H -0.0678 0.1377 0.1980 0.092 Uiso 1 1 calc R . .
H7B H 0.0433 0.1545 0.1844 0.092 Uiso 1 1 calc R . .
H7C H -0.0381 0.2049 0.1934 0.092 Uiso 1 1 calc R . .
C8 C 0.1702(9) 0.0970(4) 0.30699(19) 0.033(2) Uani 1 1 d . . .
H8A H 0.2383 0.1189 0.3063 0.040 Uiso 1 1 calc R . .
C9 C 0.2474(8) 0.0703(4) 0.34838(19) 0.032(2) Uani 1 1 d . . .
C10 C 0.3319(9) 0.1126(5) 0.3521(2) 0.043(3) Uani 1 1 d . . .
H10C H 0.3326 0.1436 0.3400 0.052 Uiso 1 1 calc R . .
C11 C 0.4148(10) 0.1111(5) 0.3727(2) 0.049(3) Uani 1 1 d . . .
H11D H 0.4724 0.1404 0.3743 0.058 Uiso 1 1 calc R . .
C12 C 0.4148(9) 0.0680(5) 0.3908(2) 0.036(3) Uani 1 1 d . . .
C13 C 0.3280(10) 0.0277(5) 0.3882(2) 0.046(3) Uani 1 1 d . . .
H13A H 0.3246 -0.0017 0.4009 0.055 Uiso 1 1 calc R . .
C14 C 0.2451(10) 0.0291(5) 0.3673(2) 0.046(3) Uani 1 1 d . . .
H14A H 0.1856 0.0009 0.3661 0.055 Uiso 1 1 calc R . .
C15 C 0.5050(9) 0.0657(5) 0.4136(2) 0.041(3) Uani 1 1 d . . .
H15A H 0.5709 0.0895 0.4094 0.049 Uiso 1 1 calc R . .
H15B H 0.5316 0.0248 0.4158 0.049 Uiso 1 1 calc R . .
C16 C 0.4684(9) 0.0870(4) 0.4392(2) 0.034(2) Uani 1 1 d . . .
C17 C 0.4285(9) 0.1431(5) 0.4426(2) 0.042(3) Uani 1 1 d . . .
H17A H 0.4168 0.1682 0.4280 0.050 Uiso 1 1 calc R . .
C18 C 0.4052(8) 0.1638(4) 0.46609(18) 0.032(2) Uani 1 1 d . . .
H18A H 0.3774 0.2025 0.4677 0.039 Uiso 1 1 calc R . .
C19 C 0.4226(7) 0.1275(4) 0.48785(17) 0.025(2) Uani 1 1 d . . .
C20 C 0.4585(10) 0.0713(5) 0.4846(2) 0.040(3) Uani 1 1 d . . .
H20A H 0.4685 0.0460 0.4991 0.048 Uiso 1 1 calc R . .
C21 C 0.4806(10) 0.0505(4) 0.4609(2) 0.042(3) Uani 1 1 d . . .
H21A H 0.5044 0.0112 0.4591 0.051 Uiso 1 1 calc R . .
C22 C 0.3581(9) 0.1165(5) 0.5272(2) 0.039(3) Uani 1 1 d . . .
H22A H 0.3318 0.0808 0.5194 0.047 Uiso 1 1 calc R . .
C23 C 0.3688(9) 0.1765(5) 0.56805(19) 0.039(3) Uani 1 1 d . . .
C24 C 0.3359(9) 0.1248(5) 0.5542(2) 0.039(3) Uani 1 1 d . . .
C25 C 0.2793(10) 0.0800(6) 0.5661(2) 0.056(3) Uani 1 1 d . . .
H25A H 0.2604 0.0449 0.5570 0.067 Uiso 1 1 calc R . .
C26 C 0.2503(12) 0.0862(7) 0.5912(3) 0.071(4) Uani 1 1 d . . .
H26A H 0.2112 0.0558 0.5991 0.086 Uiso 1 1 calc R . .
C27 C 0.2797(11) 0.1373(7) 0.6043(3) 0.067(4) Uani 1 1 d . . .
H27A H 0.2603 0.1417 0.6214 0.081 Uiso 1 1 calc R . .
C28 C 0.3359(10) 0.1818(6) 0.5935(2) 0.051(3) Uani 1 1 d . . .
C29 C 0.4627(15) 0.2486(7) 0.6153(3) 0.090(5) Uani 1 1 d . . .
H29A H 0.4622 0.2860 0.6244 0.135 Uiso 1 1 calc R . .
H29B H 0.5076 0.2524 0.6006 0.135 Uiso 1 1 calc R . .
H29C H 0.4967 0.2184 0.6270 0.135 Uiso 1 1 calc R . .
C30 C 0.0387(10) 0.3209(5) 0.2031(2) 0.041(3) Uani 1 1 d . . .
C31 C 0.0162(12) 0.3527(5) 0.1788(2) 0.051(3) Uani 1 1 d . . .
C32 C -0.0817(13) 0.3845(6) 0.1744(3) 0.064(4) Uani 1 1 d . . .
H32A H -0.0963 0.4045 0.1585 0.077 Uiso 1 1 calc R . .
C33 C -0.1618(13) 0.3890(6) 0.1924(3) 0.070(4) Uani 1 1 d . . .
H33A H -0.2300 0.4108 0.1886 0.084 Uiso 1 1 calc R . .
C34 C -0.1387(11) 0.3609(6) 0.2157(3) 0.062(4) Uani 1 1 d . . .
H34A H -0.1912 0.3649 0.2282 0.074 Uiso 1 1 calc R . .
C35 C -0.0417(10) 0.3268(5) 0.2215(2) 0.045(3) Uani 1 1 d . . .
C36 C 0.0955(15) 0.3875(7) 0.1418(3) 0.083(5) Uani 1 1 d . . .
H36A H 0.1599 0.3803 0.1317 0.124 Uiso 1 1 calc R . .
H36B H 0.0994 0.4277 0.1484 0.124 Uiso 1 1 calc R . .
H36C H 0.0238 0.3819 0.1309 0.124 Uiso 1 1 calc R . .
C37 C -0.0255(9) 0.3029(5) 0.2469(2) 0.042(3) Uani 1 1 d . . .
H37A H -0.0855 0.3093 0.2575 0.050 Uiso 1 1 calc R . .
C38 C 0.0510(9) 0.2535(4) 0.28313(19) 0.036(3) Uani 1 1 d . . .
C39 C 0.1443(9) 0.2595(4) 0.30190(19) 0.033(2) Uani 1 1 d . . .
H39A H 0.2121 0.2780 0.2977 0.040 Uiso 1 1 calc R . .
C40 C 0.1379(9) 0.2386(4) 0.32631(19) 0.035(2) Uani 1 1 d . . .
H40A H 0.2015 0.2430 0.3389 0.041 Uiso 1 1 calc R . .
C41 C 0.0386(9) 0.2109(4) 0.3331(2) 0.037(3) Uani 1 1 d . . .
C42 C -0.0525(9) 0.2063(5) 0.3145(2) 0.037(3) Uani 1 1 d . . .
H42A H -0.1210 0.1883 0.3187 0.044 Uiso 1 1 calc R . .
C43 C -0.0460(8) 0.2275(4) 0.2897(2) 0.036(3) Uani 1 1 d . . .
H43A H -0.1100 0.2238 0.2772 0.043 Uiso 1 1 calc R . .
C44 C 0.0358(9) 0.1827(5) 0.35883(17) 0.037(3) Uani 1 1 d . . .
H44A H 0.0906 0.1498 0.3602 0.044 Uiso 1 1 calc R . .
H44B H -0.0413 0.1662 0.3599 0.044 Uiso 1 1 calc R . .
C45 C 0.0640(8) 0.2229(4) 0.38168(19) 0.033(2) Uani 1 1 d . . .
C46 C 0.1741(9) 0.2253(6) 0.3945(2) 0.048(3) Uani 1 1 d . . .
H46A H 0.2325 0.2011 0.3890 0.058 Uiso 1 1 calc R . .
C47 C 0.1983(9) 0.2627(6) 0.4151(2) 0.052(3) Uani 1 1 d . . .
H47A H 0.2734 0.2640 0.4236 0.062 Uiso 1 1 calc R . .
C48 C 0.1146(9) 0.2982(5) 0.42361(19) 0.038(3) Uani 1 1 d . . .
C49 C 0.0076(9) 0.2972(5) 0.4104(2) 0.047(3) Uani 1 1 d . . .
H49A H -0.0500 0.3225 0.4155 0.056 Uiso 1 1 calc R . .
C50 C -0.0166(10) 0.2598(5) 0.3900(2) 0.050(3) Uani 1 1 d . . .
H50A H -0.0915 0.2595 0.3813 0.060 Uiso 1 1 calc R . .
C51 C 0.2079(9) 0.3235(5) 0.4631(2) 0.039(3) Uani 1 1 d . . .
H51A H 0.2449 0.2867 0.4621 0.047 Uiso 1 1 calc R . .
C52 C 0.3195(9) 0.3367(5) 0.50462(19) 0.035(3) Uani 1 1 d . . .
C53 C 0.2388(10) 0.3596(5) 0.4858(2) 0.045(3) Uani 1 1 d . . .
C54 C 0.1937(13) 0.4157(6) 0.4885(3) 0.067(4) Uani 1 1 d . . .
H54A H 0.1415 0.4313 0.4753 0.080 Uiso 1 1 calc R . .
C55 C 0.2238(15) 0.4477(6) 0.5100(3) 0.087(5) Uani 1 1 d . . .
H55A H 0.1913 0.4854 0.5117 0.105 Uiso 1 1 calc R . .
C56 C 0.3025(12) 0.4259(6) 0.5296(3) 0.062(4) Uani 1 1 d . . .
H56A H 0.3244 0.4489 0.5444 0.074 Uiso 1 1 calc R . .
C57 C 0.3471(10) 0.3717(5) 0.5273(2) 0.045(3) Uani 1 1 d . . .
C58 C 0.4581(11) 0.3738(6) 0.5685(2) 0.060(4) Uani 1 1 d . . .
H58A H 0.4099 0.4084 0.5698 0.090 Uiso 1 1 calc R . .
H58B H 0.5383 0.3858 0.5695 0.090 Uiso 1 1 calc R . .
H58C H 0.4472 0.3470 0.5827 0.090 Uiso 1 1 calc R . .
C59 C 0.4023(9) 0.3361(4) 0.25419(19) 0.035(3) Uani 1 1 d . . .
C60 C 0.4373(9) 0.3365(4) 0.2291(2) 0.036(3) Uani 1 1 d . . .
C61 C 0.5231(11) 0.3714(5) 0.2214(2) 0.052(3) Uani 1 1 d . . .
H61A H 0.5429 0.3705 0.2042 0.062 Uiso 1 1 calc R . .
C62 C 0.5798(11) 0.4085(5) 0.2400(2) 0.059(4) Uani 1 1 d . . .
H62A H 0.6397 0.4329 0.2354 0.071 Uiso 1 1 calc R . .
C63 C 0.5499(10) 0.4097(5) 0.2643(2) 0.053(3) Uani 1 1 d . . .
H63A H 0.5882 0.4360 0.2763 0.063 Uiso 1 1 calc R . .
C64 C 0.4636(9) 0.3732(4) 0.2725(2) 0.036(3) Uani 1 1 d . . .
C65 C 0.3789(13) 0.3011(6) 0.1863(2) 0.067(4) Uani 1 1 d . . .
H65A H 0.4385 0.3288 0.1826 0.100 Uiso 1 1 calc R . .
H65B H 0.3052 0.3141 0.1778 0.100 Uiso 1 1 calc R . .
H65C H 0.3970 0.2623 0.1798 0.100 Uiso 1 1 calc R . .
C66 C 0.4364(10) 0.3746(5) 0.2989(2) 0.041(3) Uani 1 1 d . . .
H66A H 0.3801 0.3482 0.3039 0.050 Uiso 1 1 calc R . .
C67 C 0.4493(9) 0.4086(4) 0.3410(2) 0.038(3) Uani 1 1 d . . .
C68 C 0.3559(15) 0.3799(8) 0.3487(3) 0.097(6) Uani 1 1 d . . .
H68A H 0.3117 0.3556 0.3368 0.117 Uiso 1 1 calc R . .
C69 C 0.3249(14) 0.3859(7) 0.3738(2) 0.084(5) Uani 1 1 d . . .
H69A H 0.2584 0.3665 0.3783 0.100 Uiso 1 1 calc R . .
C70 C 0.3878(10) 0.4189(5) 0.3920(2) 0.043(3) Uani 1 1 d . . .
C71 C 0.4808(11) 0.4462(6) 0.3840(3) 0.063(4) Uani 1 1 d . . .
H71A H 0.5271 0.4695 0.3959 0.075 Uiso 1 1 calc R . .
C72 C 0.5101(11) 0.4412(5) 0.3592(2) 0.057(3) Uani 1 1 d . . .
H72A H 0.5756 0.4614 0.3547 0.068 Uiso 1 1 calc R . .
C73 C 0.3495(10) 0.4284(5) 0.4186(2) 0.049(3) Uani 1 1 d . . .
H73A H 0.3348 0.4706 0.4207 0.059 Uiso 1 1 calc R . .
H73B H 0.2764 0.4076 0.4195 0.059 Uiso 1 1 calc R . .
C74 C 0.4313(10) 0.4086(5) 0.4406(2) 0.044(3) Uani 1 1 d . . .
C75 C 0.4742(9) 0.3518(5) 0.4427(2) 0.038(3) Uani 1 1 d . . .
H75A H 0.4591 0.3262 0.4285 0.046 Uiso 1 1 calc R . .
C76 C 0.5373(9) 0.3309(4) 0.46449(19) 0.035(3) Uani 1 1 d . . .
H76A H 0.5660 0.2920 0.4649 0.042 Uiso 1 1 calc R . .
C77 C 0.5594(9) 0.3677(4) 0.48635(17) 0.033(2) Uani 1 1 d . . .
C78 C 0.5232(11) 0.4246(5) 0.4841(2) 0.046(3) Uani 1 1 d . . .
H78A H 0.5422 0.4509 0.4979 0.055 Uiso 1 1 calc R . .
C79 C 0.4590(11) 0.4451(5) 0.4618(2) 0.047(3) Uani 1 1 d . . .
H79A H 0.4339 0.4846 0.4611 0.057 Uiso 1 1 calc R . .
C80 C 0.6879(9) 0.3761(5) 0.5221(2) 0.042(3) Uani 1 1 d . . .
H80A H 0.7079 0.4105 0.5133 0.050 Uiso 1 1 calc R . .
C81 C 0.7278(9) 0.3189(5) 0.5624(2) 0.040(3) Uani 1 1 d . . .
C82 C 0.7480(9) 0.3674(5) 0.54738(19) 0.040(3) Uani 1 1 d . . .
C83 C 0.8290(11) 0.4097(6) 0.5567(3) 0.063(4) Uani 1 1 d . . .
H83A H 0.8442 0.4423 0.5464 0.075 Uiso 1 1 calc R . .
C84 C 0.8857(12) 0.4035(7) 0.5808(3) 0.075(4) Uani 1 1 d . . .
H84A H 0.9395 0.4325 0.5869 0.091 Uiso 1 1 calc R . .
C85 C 0.8664(11) 0.3554(6) 0.5966(2) 0.065(4) Uani 1 1 d . . .
H85A H 0.9070 0.3517 0.6132 0.078 Uiso 1 1 calc R . .
C86 C 0.7885(10) 0.3144(5) 0.58770(19) 0.042(3) Uani 1 1 d . . .
C87 C 0.8071(16) 0.2608(7) 0.6273(3) 0.096(5) Uani 1 1 d . . .
H87A H 0.7788 0.2247 0.6345 0.144 Uiso 1 1 calc R . .
H87B H 0.7850 0.2944 0.6373 0.144 Uiso 1 1 calc R . .
H87C H 0.8904 0.2591 0.6279 0.144 Uiso 1 1 calc R . .
C88 C 0.3527(12) 0.1429(5) 0.1937(2) 0.050(3) Uani 1 1 d . . .
C89 C 0.3202(14) 0.1078(6) 0.1709(2) 0.062(4) Uani 1 1 d . . .
C90 C 0.3984(17) 0.0699(7) 0.1622(3) 0.082(5) Uani 1 1 d . . .
H90A H 0.3762 0.0470 0.1474 0.099 Uiso 1 1 calc R . .
C91 C 0.5064(17) 0.0640(7) 0.1740(3) 0.084(5) Uani 1 1 d . . .
H91A H 0.5591 0.0383 0.1672 0.101 Uiso 1 1 calc R . .
C92 C 0.5370(14) 0.0956(6) 0.1954(3) 0.078(4) Uani 1 1 d . . .
H92A H 0.6119 0.0912 0.2038 0.093 Uiso 1 1 calc R . .
C93 C 0.4622(11) 0.1345(5) 0.2059(2) 0.048(3) Uani 1 1 d . . .
C94 C 0.1664(16) 0.0766(8) 0.1409(3) 0.104(6) Uani 1 1 d . . .
H94A H 0.0874 0.0870 0.1350 0.156 Uiso 1 1 calc R . .
H94B H 0.1689 0.0368 0.1479 0.156 Uiso 1 1 calc R . .
H94C H 0.2127 0.0785 0.1263 0.156 Uiso 1 1 calc R . .
C95 C 0.4998(10) 0.1619(5) 0.2306(2) 0.042(3) Uani 1 1 d . . .
H95A H 0.5780 0.1565 0.2365 0.050 Uiso 1 1 calc R . .
C96 C 0.5028(8) 0.2130(4) 0.26836(17) 0.028(2) Uani 1 1 d . . .
C97 C 0.4518(9) 0.2077(4) 0.2910(2) 0.038(3) Uani 1 1 d . . .
H97A H 0.3802 0.1886 0.2910 0.045 Uiso 1 1 calc R . .
C98 C 0.5058(9) 0.2306(5) 0.3137(2) 0.040(3) Uani 1 1 d . . .
H98A H 0.4702 0.2266 0.3292 0.048 Uiso 1 1 calc R . .
C99 C 0.6119(9) 0.2596(4) 0.3146(2) 0.040(3) Uani 1 1 d . . .
C100 C 0.6606(9) 0.2638(5) 0.2919(2) 0.043(3) Uani 1 1 d . . .
H10D H 0.7317 0.2833 0.2917 0.052 Uiso 1 1 calc R . .
C101 C 0.6074(9) 0.2400(4) 0.2693(2) 0.037(3) Uani 1 1 d . . .
H10E H 0.6444 0.2426 0.2540 0.045 Uiso 1 1 calc R . .
C102 C 0.6652(11) 0.2895(5) 0.3384(2) 0.048(3) Uani 1 1 d . . .
H10A H 0.6194 0.3247 0.3413 0.057 Uiso 1 1 calc R . .
H10B H 0.7422 0.3029 0.3351 0.057 Uiso 1 1 calc R . .
C103 C 0.6768(9) 0.2540(4) 0.3630(2) 0.035(2) Uani 1 1 d . . .
C104 C 0.6692(9) 0.2802(5) 0.3863(2) 0.046(3) Uani 1 1 d . . .
H10F H 0.6463 0.3200 0.3867 0.055 Uiso 1 1 calc R . .
C105 C 0.6936(10) 0.2508(5) 0.4093(2) 0.047(3) Uani 1 1 d . . .
H10G H 0.6901 0.2710 0.4251 0.056 Uiso 1 1 calc R . .
C106 C 0.7233(9) 0.1920(5) 0.40955(19) 0.035(3) Uani 1 1 d . . .
C107 C 0.7316(8) 0.1651(4) 0.38625(19) 0.031(2) Uani 1 1 d . . .
H10H H 0.7546 0.1254 0.3858 0.037 Uiso 1 1 calc R . .
C108 C 0.7068(8) 0.1954(5) 0.3633(2) 0.035(3) Uani 1 1 d . . .
H10I H 0.7105 0.1754 0.3475 0.042 Uiso 1 1 calc R . .
C109 C 0.7094(8) 0.1710(4) 0.4524(2) 0.034(2) Uani 1 1 d . . .
H10J H 0.6592 0.2036 0.4518 0.040 Uiso 1 1 calc R . .
C110 C 0.6816(8) 0.1626(4) 0.49850(17) 0.026(2) Uani 1 1 d . . .
C111 C 0.7306(9) 0.1399(5) 0.4764(2) 0.037(3) Uani 1 1 d . . .
C112 C 0.7901(10) 0.0866(5) 0.4784(2) 0.054(3) Uani 1 1 d . . .
H11E H 0.8203 0.0708 0.4637 0.065 Uiso 1 1 calc R . .
C113 C 0.8049(12) 0.0571(6) 0.5015(2) 0.062(4) Uani 1 1 d . . .
H11F H 0.8479 0.0219 0.5028 0.074 Uiso 1 1 calc R . .
C114 C 0.7562(11) 0.0791(5) 0.5233(2) 0.052(3) Uani 1 1 d . . .
H11G H 0.7657 0.0583 0.5391 0.063 Uiso 1 1 calc R . .
C115 C 0.6963(9) 0.1299(5) 0.52165(19) 0.035(3) Uani 1 1 d . . .
C116 C 0.6527(10) 0.1280(6) 0.5655(2) 0.053(3) Uani 1 1 d . . .
H11A H 0.7051 0.0947 0.5655 0.080 Uiso 1 1 calc R . .
H11B H 0.5772 0.1141 0.5690 0.080 Uiso 1 1 calc R . .
H11C H 0.6815 0.1559 0.5788 0.080 Uiso 1 1 calc R . .
C117 C 0.6218(11) 0.2752(7) 0.0143(3) 0.072(4) Uani 1 1 d . . .
H11H H 0.6312 0.2396 0.0039 0.086 Uiso 1 1 calc R . .
H11I H 0.6938 0.2813 0.0254 0.086 Uiso 1 1 calc R . .
C118 C 0.6042(11) 0.3267(8) -0.0039(3) 0.088(5) Uani 1 1 d . . .
H11L H 0.6681 0.3291 -0.0144 0.132 Uiso 1 1 calc R . .
H11M H 0.6001 0.3628 0.0061 0.132 Uiso 1 1 calc R . .
H11N H 0.5328 0.3215 -0.0150 0.132 Uiso 1 1 calc R . .
C119 C 0.4109(10) 0.2618(7) 0.0168(3) 0.075(4) Uani 1 1 d . . .
H11J H 0.3911 0.3009 0.0096 0.090 Uiso 1 1 calc R . .
H11K H 0.3559 0.2524 0.0293 0.090 Uiso 1 1 calc R . .
C120 C 0.3968(12) 0.2174(8) -0.0048(3) 0.083(5) Uani 1 1 d . . .
H12S H 0.3186 0.2190 -0.0132 0.124 Uiso 1 1 calc R . .
H12T H 0.4123 0.1781 0.0022 0.124 Uiso 1 1 calc R . .
H12U H 0.4504 0.2262 -0.0174 0.124 Uiso 1 1 calc R . .
C121 C 0.5515(11) 0.2070(6) 0.0453(3) 0.067(4) Uani 1 1 d . . .
H12A H 0.5566 0.1755 0.0324 0.081 Uiso 1 1 calc R . .
H12B H 0.4851 0.1983 0.0548 0.081 Uiso 1 1 calc R . .
C122 C 0.6589(11) 0.2050(7) 0.0642(3) 0.070(4) Uani 1 1 d . . .
H12V H 0.6658 0.1662 0.0723 0.105 Uiso 1 1 calc R . .
H12W H 0.6539 0.2348 0.0775 0.105 Uiso 1 1 calc R . .
H12X H 0.7258 0.2125 0.0550 0.105 Uiso 1 1 calc R . .
C123 C 0.5308(12) 0.3159(7) 0.0501(3) 0.070(4) Uani 1 1 d . . .
H12C H 0.6099 0.3208 0.0582 0.085 Uiso 1 1 calc R . .
H12D H 0.5098 0.3520 0.0403 0.085 Uiso 1 1 calc R . .
C124 C 0.4526(14) 0.3101(8) 0.0715(3) 0.090(5) Uani 1 1 d . . .
H17D H 0.4604 0.3448 0.0825 0.135 Uiso 1 1 calc R . .
H17B H 0.4738 0.2752 0.0818 0.135 Uiso 1 1 calc R . .
H17C H 0.3734 0.3065 0.0639 0.135 Uiso 1 1 calc R . .
C125 C 0.332(2) 0.9234(10) 0.2383(6) 0.058(7) Uani 0.50 1 d P A 1
H12E H 0.3746 0.8973 0.2511 0.070 Uiso 0.50 1 calc PR A 1
H12F H 0.2531 0.9085 0.2355 0.070 Uiso 0.50 1 calc PR A 1
C128 C 0.299(2) 1.0306(10) 0.2331(5) 0.048(6) Uani 0.50 1 d P A 1
H12G H 0.3614 1.0353 0.2219 0.057 Uiso 0.50 1 calc PR A 1
H12H H 0.2961 1.0669 0.2433 0.057 Uiso 0.50 1 calc PR A 1
C131 C 0.242(2) 0.9793(10) 0.2712(4) 0.044(6) Uani 0.50 1 d P A 1
H13B H 0.2286 1.0194 0.2774 0.053 Uiso 0.50 1 calc PR A 1
H13C H 0.1691 0.9647 0.2627 0.053 Uiso 0.50 1 calc PR A 1
C134 C 0.447(2) 0.9951(11) 0.2656(5) 0.055(7) Uani 0.50 1 d P A 1
H13D H 0.4581 0.9637 0.2787 0.066 Uiso 0.50 1 calc PR A 1
H13E H 0.5048 0.9884 0.2534 0.066 Uiso 0.50 1 calc PR A 1
C126 C 0.405(2) 0.9676(14) 0.2289(6) 0.076(9) Uani 0.50 1 d P A 2
H12I H 0.4029 1.0010 0.2168 0.092 Uiso 0.50 1 calc PR A 2
H12J H 0.4840 0.9646 0.2371 0.092 Uiso 0.50 1 calc PR A 2
C129 C 0.204(2) 0.9944(10) 0.2397(5) 0.051(6) Uani 0.50 1 d P A 2
H12K H 0.1658 0.9559 0.2374 0.061 Uiso 0.50 1 calc PR A 2
H12L H 0.1661 1.0162 0.2528 0.061 Uiso 0.50 1 calc PR A 2
C132 C 0.334(3) 0.9384(11) 0.2697(6) 0.075(9) Uani 0.50 1 d P A 2
H13F H 0.4161 0.9329 0.2758 0.090 Uiso 0.50 1 calc PR A 2
H13G H 0.3082 0.9017 0.2610 0.090 Uiso 0.50 1 calc PR A 2
C135 C 0.375(2) 1.0432(10) 0.2613(6) 0.069(8) Uani 0.50 1 d P A 2
H13H H 0.3847 1.0690 0.2465 0.083 Uiso 0.50 1 calc PR A 2
H13I H 0.3139 1.0609 0.2706 0.083 Uiso 0.50 1 calc PR A 2
C127 C 0.383(2) 0.9177(7) 0.2144(4) 0.127(8) Uani 1 1 d . . .
H12M H 0.3806 0.8767 0.2090 0.191 Uiso 0.50 1 calc PR A 1
H12N H 0.4621 0.9312 0.2168 0.191 Uiso 0.50 1 calc PR A 1
H12O H 0.3398 0.9415 0.2011 0.191 Uiso 0.50 1 calc PR A 1
H12P H 0.4361 0.9154 0.2012 0.191 Uiso 0.50 1 calc PR A 2
H12Q H 0.3044 0.9191 0.2061 0.191 Uiso 0.50 1 calc PR A 2
H12R H 0.3922 0.8833 0.2256 0.191 Uiso 0.50 1 calc PR A 2
C130 C 0.1859(13) 1.0260(6) 0.2155(3) 0.072(4) Uani 1 1 d . . .
H13J H 0.1780 1.0599 0.2040 0.108 Uiso 0.50 1 calc PR A 1
H13K H 0.1219 1.0250 0.2261 0.108 Uiso 0.50 1 calc PR A 1
H13L H 0.1860 0.9901 0.2052 0.108 Uiso 0.50 1 calc PR A 1
H13M H 0.1039 1.0302 0.2105 0.108 Uiso 0.50 1 calc PR A 2
H13N H 0.2207 1.0044 0.2021 0.108 Uiso 0.50 1 calc PR A 2
H13O H 0.2209 1.0648 0.2175 0.108 Uiso 0.50 1 calc PR A 2
C133 C 0.2721(13) 0.9439(6) 0.2932(3) 0.072(4) Uani 1 1 d . . .
H13P H 0.2109 0.9455 0.3046 0.107 Uiso 0.50 1 calc PR A 1
H13Q H 0.3431 0.9583 0.3024 0.107 Uiso 0.50 1 calc PR A 1
H13R H 0.2826 0.9034 0.2878 0.107 Uiso 0.50 1 calc PR A 1
H13S H 0.2848 0.9087 0.3038 0.107 Uiso 0.50 1 calc PR A 2
H13T H 0.1903 0.9484 0.2880 0.107 Uiso 0.50 1 calc PR A 2
H13U H 0.3002 0.9782 0.3031 0.107 Uiso 0.50 1 calc PR A 2
C136 C 0.4761(19) 1.0453(7) 0.2779(4) 0.131(9) Uani 1 1 d . . .
H13V H 0.5561 1.0435 0.2850 0.197 Uiso 0.50 1 calc PR A 1
H13W H 0.4276 1.0512 0.2918 0.197 Uiso 0.50 1 calc PR A 1
H13X H 0.4656 1.0780 0.2657 0.197 Uiso 0.50 1 calc PR A 1
H13Y H 0.4934 1.0860 0.2827 0.197 Uiso 0.50 1 calc PR A 2
H13Z H 0.5386 1.0291 0.2691 0.197 Uiso 0.50 1 calc PR A 2
H16A H 0.4671 1.0224 0.2934 0.197 Uiso 0.50 1 calc PR A 2
C137 C 0.8492(13) 0.5380(7) 0.1539(3) 0.086(5) Uiso 1 1 d D . .
H16B H 0.8822 0.5732 0.1624 0.129 Uiso 1 1 calc R . .
H16C H 0.8473 0.5424 0.1352 0.129 Uiso 1 1 calc R . .
H16D H 0.8959 0.5039 0.1594 0.129 Uiso 1 1 calc R . .
C138 C 0.7329(13) 0.5296(7) 0.1608(3) 0.079(4) Uiso 1 1 d D . .
H16E H 0.7348 0.5264 0.1798 0.095 Uiso 1 1 calc R . .
H16F H 0.6860 0.5641 0.1553 0.095 Uiso 1 1 calc R . .
O17 O 0.6814(7) 0.4782(4) 0.14923(16) 0.060(2) Uiso 1 1 d D . .
C139 C 0.5709(11) 0.4657(6) 0.1564(3) 0.062(3) Uiso 1 1 d D . .
H16G H 0.5200 0.4997 0.1525 0.074 Uiso 1 1 calc R . .
H16H H 0.5750 0.4578 0.1751 0.074 Uiso 1 1 calc R . .
C140 C 0.5255(13) 0.4138(6) 0.1418(3) 0.077(4) Uiso 1 1 d D . .
H14J H 0.4489 0.4049 0.1464 0.116 Uiso 1 1 calc R . .
H14K H 0.5758 0.3803 0.1459 0.116 Uiso 1 1 calc R . .
H14L H 0.5219 0.4220 0.1233 0.116 Uiso 1 1 calc R . .
C141 C 0.804(3) 0.0815(14) 0.1349(7) 0.091(10) Uiso 0.50 1 d P B 2
H14M H 0.7849 0.0598 0.1188 0.137 Uiso 0.50 1 calc PR B 2
H14N H 0.7977 0.0556 0.1496 0.137 Uiso 0.50 1 calc PR B 2
H14O H 0.8830 0.0959 0.1354 0.137 Uiso 0.50 1 calc PR B 2
C142 C 0.727(2) 0.1307(12) 0.1360(5) 0.068(8) Uiso 0.50 1 d P B 2
H14B H 0.7330 0.1554 0.1206 0.081 Uiso 0.50 1 calc PR B 2
H14C H 0.6482 0.1153 0.1348 0.081 Uiso 0.50 1 calc PR B 2
O18 O 0.7424(12) 0.1651(6) 0.1569(3) 0.046(4) Uiso 0.50 1 d P B 2
C143 C 0.672(2) 0.2106(12) 0.1558(6) 0.070(8) Uiso 0.50 1 d P B 2
H14D H 0.5924 0.1968 0.1554 0.084 Uiso 0.50 1 calc PR B 2
H14E H 0.6796 0.2332 0.1399 0.084 Uiso 0.50 1 calc PR B 2
C144 C 0.699(3) 0.2461(15) 0.1772(7) 0.099(11) Uiso 0.50 1 d P B 2
H14P H 0.6465 0.2795 0.1765 0.148 Uiso 0.50 1 calc PR B 2
H14Q H 0.7774 0.2602 0.1774 0.148 Uiso 0.50 1 calc PR B 2
H14R H 0.6913 0.2235 0.1929 0.148 Uiso 0.50 1 calc PR B 2
C145 C 0.785(5) 0.470(2) 0.2970(11) 0.22(3) Uiso 0.50 1 d PD C 1
H14S H 0.7370 0.4647 0.2808 0.326 Uiso 0.50 1 calc PR C 1
H14T H 0.8538 0.4923 0.2937 0.326 Uiso 0.50 1 calc PR C 1
H14U H 0.7429 0.4923 0.3090 0.326 Uiso 0.50 1 calc PR C 1
C146 C 0.818(3) 0.4136(16) 0.3081(7) 0.113(13) Uiso 0.50 1 d PD C 1
H14F H 0.7472 0.3919 0.3102 0.136 Uiso 0.50 1 calc PR C 1
H14G H 0.8576 0.3920 0.2951 0.136 Uiso 0.50 1 calc PR C 1
O19 O 0.887(3) 0.4100(18) 0.3314(7) 0.210(17) Uiso 0.50 1 d PD C 1
C147 C 0.872(3) 0.418(2) 0.3574(7) 0.157(19) Uiso 0.50 1 d PD C 1
H14H H 0.8343 0.3843 0.3646 0.188 Uiso 0.50 1 calc PR C 1
H14I H 0.8260 0.4540 0.3599 0.188 Uiso 0.50 1 calc PR C 1
C148 C 0.993(4) 0.425(2) 0.3690(9) 0.18(2) Uiso 0.50 1 d PD C 1
H14V H 0.9940 0.4329 0.3875 0.263 Uiso 0.50 1 calc PR C 1
H14W H 1.0285 0.4581 0.3608 0.263 Uiso 0.50 1 calc PR C 1
H14X H 1.0354 0.3893 0.3663 0.263 Uiso 0.50 1 calc PR C 1
O20 O 0.4091(10) 0.4812(5) 0.0774(2) 0.095(3) Uiso 1 1 d D . .
C149 C 0.3647(17) 0.5730(8) 0.0587(4) 0.116(6) Uiso 1 1 d D . .
H14Y H 0.3048 0.5505 0.0487 0.173 Uiso 1 1 calc R . .
H14Z H 0.4130 0.5921 0.0469 0.173 Uiso 1 1 calc R . .
H15C H 0.3298 0.6028 0.0689 0.173 Uiso 1 1 calc R . .
C150 C 0.4353(11) 0.5332(6) 0.0761(3) 0.059(3) Uiso 1 1 d D . .
C151 C 0.5290(13) 0.5572(7) 0.0925(3) 0.084(5) Uiso 1 1 d D . .
H15D H 0.5684 0.5257 0.1026 0.126 Uiso 1 1 calc R . .
H15E H 0.5002 0.5859 0.1042 0.126 Uiso 1 1 calc R . .
H15F H 0.5824 0.5763 0.0820 0.126 Uiso 1 1 calc R . .
O21 O 0.803(3) 0.4121(15) 0.4458(7) 0.194(16) Uiso 0.50 1 d PD D 1
C152 C 0.743(2) 0.4907(12) 0.4166(6) 0.080(9) Uiso 0.50 1 d PD D 1
H15G H 0.6727 0.4689 0.4119 0.120 Uiso 0.50 1 calc PR D 1
H15H H 0.7771 0.5022 0.4010 0.120 Uiso 0.50 1 calc PR D 1
H15I H 0.7264 0.5257 0.4264 0.120 Uiso 0.50 1 calc PR D 1
C153 C 0.825(2) 0.4529(13) 0.4328(6) 0.089(10) Uiso 0.50 1 d PD D 1
C154 C 0.937(2) 0.4757(16) 0.4385(7) 0.117(13) Uiso 0.50 1 d PD D 1
H15J H 0.9851 0.4470 0.4484 0.175 Uiso 0.50 1 calc PR D 1
H15K H 0.9342 0.5118 0.4485 0.175 Uiso 0.50 1 calc PR D 1
H15L H 0.9703 0.4842 0.4224 0.175 Uiso 0.50 1 calc PR D 1


_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O13 2.205(8) . ?
Dy1 O5 2.223(7) . ?
Dy1 O9 2.258(7) . ?
Dy1 O1 2.259(6) . ?
Dy1 O10 2.547(7) . ?
Dy1 O2 2.558(7) . ?
Dy1 N3 2.639(9) . ?
Dy1 N7 2.628(9) . ?
Dy2 O11 2.185(7) . ?
Dy2 O3 2.201(7) . ?
Dy2 O15 2.228(7) . ?
Dy2 O7 2.234(7) . ?
Dy2 O16 2.637(7) . ?
Dy2 N2 2.642(8) . ?
Dy2 N6 2.651(8) . ?
Dy2 O8 2.659(7) . ?
N1 C8 1.272(12) . ?
N1 C9 1.438(13) . ?
N2 C22 1.269(13) . ?
N2 C19 1.444(12) . ?
N3 C37 1.292(13) . ?
N3 C38 1.444(13) . ?
N4 C51 1.275(13) . ?
N4 C48 1.426(14) . ?
N5 C66 1.277(13) . ?
N5 C67 1.405(14) . ?
N6 C80 1.261(13) . ?
N6 C77 1.429(12) . ?
N7 C95 1.282(13) . ?
N7 C96 1.415(12) . ?
N8 C109 1.272(13) . ?
N8 C106 1.428(13) . ?
N9 C117 1.486(16) . ?
N9 C121 1.525(16) . ?
N9 C119 1.510(16) . ?
N9 C123 1.540(17) . ?
N10 C128 1.42(2) . ?
N10 C132 1.45(3) . ?
N10 C129 1.53(3) . ?
N10 C125 1.52(2) . ?
N10 C135 1.55(3) . ?
N10 C126 1.55(3) . ?
N10 C134 1.56(3) . ?
N10 C131 1.57(2) . ?
O1 C1 1.315(12) . ?
O2 C2 1.367(12) . ?
O2 C7 1.437(13) . ?
O3 C23 1.296(12) . ?
O4 C29 1.351(18) . ?
O4 C28 1.373(15) . ?
O5 C30 1.300(13) . ?
O6 C31 1.362(15) . ?
O6 C36 1.425(14) . ?
O7 C52 1.307(12) . ?
O8 C57 1.373(13) . ?
O8 C58 1.441(12) . ?
O9 C59 1.295(12) . ?
O10 C60 1.379(12) . ?
O10 C65 1.420(13) . ?
O11 C81 1.304(12) . ?
O12 C86 1.375(13) . ?
O12 C87 1.397(16) . ?
O13 C88 1.314(14) . ?
O14 C89 1.371(17) . ?
O14 C94 1.420(15) . ?
O15 C110 1.313(11) . ?
O16 C115 1.362(12) . ?
O16 C116 1.440(12) . ?
C1 C6 1.406(14) . ?
C1 C2 1.429(14) . ?
C2 C3 1.356(15) . ?
C3 C4 1.391(16) . ?
C4 C5 1.351(16) . ?
C5 C6 1.401(15) . ?
C6 C8 1.452(14) . ?
C9 C14 1.366(14) . ?
C9 C10 1.387(15) . ?
C10 C11 1.377(16) . ?
C11 C12 1.367(16) . ?
C12 C13 1.373(15) . ?
C12 C15 1.513(15) . ?
C13 C14 1.389(15) . ?
C15 C16 1.527(14) . ?
C16 C17 1.384(14) . ?
C16 C21 1.401(15) . ?
C17 C18 1.371(14) . ?
C18 C19 1.406(13) . ?
C19 C20 1.369(14) . ?
C20 C21 1.379(15) . ?
C22 C24 1.472(15) . ?
C23 C24 1.421(16) . ?
C23 C28 1.427(15) . ?
C24 C25 1.402(15) . ?
C25 C26 1.395(18) . ?
C26 C27 1.38(2) . ?
C27 C28 1.367(18) . ?
C30 C35 1.423(16) . ?
C30 C31 1.464(15) . ?
C31 C32 1.363(18) . ?
C32 C33 1.40(2) . ?
C33 C34 1.378(17) . ?
C34 C35 1.391(16) . ?
C35 C37 1.433(15) . ?
C38 C43 1.363(15) . ?
C38 C39 1.404(15) . ?
C39 C40 1.370(14) . ?
C40 C41 1.408(14) . ?
C41 C42 1.377(15) . ?
C41 C44 1.492(14) . ?
C42 C43 1.393(14) . ?
C44 C45 1.516(14) . ?
C45 C50 1.373(15) . ?
C45 C46 1.400(15) . ?
C46 C47 1.383(16) . ?
C47 C48 1.384(15) . ?
C48 C49 1.375(15) . ?
C49 C50 1.374(16) . ?
C51 C53 1.458(15) . ?
C52 C53 1.400(15) . ?
C52 C57 1.440(15) . ?
C53 C54 1.400(16) . ?
C54 C55 1.356(18) . ?
C55 C56 1.403(19) . ?
C56 C57 1.356(17) . ?
C59 C60 1.411(14) . ?
C59 C64 1.419(15) . ?
C60 C61 1.381(15) . ?
C61 C62 1.405(17) . ?
C62 C63 1.354(17) . ?
C63 C64 1.414(15) . ?
C64 C66 1.452(15) . ?
C67 C72 1.355(16) . ?
C67 C68 1.375(18) . ?
C68 C69 1.402(19) . ?
C69 C70 1.372(17) . ?
C70 C71 1.363(17) . ?
C70 C73 1.518(15) . ?
C71 C72 1.377(17) . ?
C73 C74 1.493(15) . ?
C74 C79 1.399(15) . ?
C74 C75 1.395(15) . ?
C75 C76 1.379(14) . ?
C76 C77 1.421(14) . ?
C77 C78 1.372(15) . ?
C78 C79 1.403(15) . ?
C80 C82 1.450(15) . ?
C81 C82 1.394(15) . ?
C81 C86 1.441(15) . ?
C82 C83 1.410(16) . ?
C83 C84 1.368(18) . ?
C84 C85 1.409(19) . ?
C85 C86 1.359(16) . ?
C88 C93 1.392(17) . ?
C88 C89 1.454(17) . ?
C89 C90 1.38(2) . ?
C90 C91 1.36(2) . ?
C91 C92 1.35(2) . ?
C92 C93 1.400(17) . ?
C93 C95 1.461(16) . ?
C96 C101 1.376(14) . ?
C96 C97 1.383(14) . ?
C97 C98 1.392(15) . ?
C98 C99 1.412(15) . ?
C99 C100 1.367(16) . ?
C99 C102 1.502(15) . ?
C100 C101 1.393(15) . ?
C102 C103 1.513(15) . ?
C103 C104 1.367(15) . ?
C103 C108 1.387(14) . ?
C104 C105 1.382(16) . ?
C105 C106 1.389(15) . ?
C106 C107 1.376(14) . ?
C107 C108 1.388(14) . ?
C109 C111 1.442(14) . ?
C110 C115 1.418(13) . ?
C110 C111 1.437(14) . ?
C111 C112 1.405(15) . ?
C112 C113 1.378(16) . ?
C113 C114 1.420(17) . ?
C114 C115 1.357(15) . ?
C117 C118 1.511(19) . ?
C119 C120 1.51(2) . ?
C121 C122 1.525(17) . ?
C123 C124 1.522(19) . ?
C125 C127 1.44(3) . ?
C128 C130 1.54(3) . ?
C131 C133 1.42(2) . ?
C134 C136 1.34(3) . ?
C126 C127 1.38(3) . ?
C129 C130 1.45(3) . ?
C132 C133 1.50(3) . ?
C135 C136 1.40(3) . ?
C137 C138 1.466(19) . ?
C138 O17 1.429(16) . ?
O17 C139 1.419(14) . ?
C139 C140 1.482(18) . ?
C141 C142 1.45(4) . ?
C142 O18 1.34(3) . ?
O18 C143 1.33(3) . ?
C143 C144 1.39(4) . ?
C145 C146 1.46(3) . ?
C146 O19 1.40(2) . ?
O19 C147 1.40(2) . ?
C147 C148 1.51(3) . ?
O20 C150 1.231(15) . ?
C149 C150 1.48(2) . ?
C150 C151 1.437(18) . ?
O21 C153 1.20(2) . ?
C152 C153 1.49(2) . ?
C153 C154 1.42(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O13 Dy1 O5 88.5(3) . . ?
O13 Dy1 O9 137.9(3) . . ?
O5 Dy1 O9 97.5(3) . . ?
O13 Dy1 O1 97.9(3) . . ?
O5 Dy1 O1 138.9(3) . . ?
O9 Dy1 O1 104.0(2) . . ?
O13 Dy1 O10 78.1(3) . . ?
O5 Dy1 O10 72.7(3) . . ?
O9 Dy1 O10 64.4(2) . . ?
O1 Dy1 O10 148.3(2) . . ?
O13 Dy1 O2 73.7(3) . . ?
O5 Dy1 O2 78.8(3) . . ?
O9 Dy1 O2 148.4(2) . . ?
O1 Dy1 O2 64.6(2) . . ?
O10 Dy1 O2 140.1(2) . . ?
O13 Dy1 N3 142.5(3) . . ?
O5 Dy1 N3 72.1(3) . . ?
O9 Dy1 N3 77.7(2) . . ?
O1 Dy1 N3 78.8(2) . . ?
O10 Dy1 N3 123.2(2) . . ?
O2 Dy1 N3 71.3(2) . . ?
O13 Dy1 N7 72.2(3) . . ?
O5 Dy1 N7 141.8(3) . . ?
O9 Dy1 N7 77.9(3) . . ?
O1 Dy1 N7 77.7(2) . . ?
O10 Dy1 N7 71.1(2) . . ?
O2 Dy1 N7 123.9(2) . . ?
N3 Dy1 N7 140.6(2) . . ?
O11 Dy2 O3 88.3(3) . . ?
O11 Dy2 O15 98.8(3) . . ?
O3 Dy2 O15 140.4(3) . . ?
O11 Dy2 O7 138.8(3) . . ?
O3 Dy2 O7 95.0(3) . . ?
O15 Dy2 O7 104.1(2) . . ?
O11 Dy2 O16 72.8(3) . . ?
O3 Dy2 O16 82.2(3) . . ?
O15 Dy2 O16 63.4(2) . . ?
O7 Dy2 O16 148.3(2) . . ?
O11 Dy2 N2 138.8(3) . . ?
O3 Dy2 N2 71.0(3) . . ?
O15 Dy2 N2 78.6(2) . . ?
O7 Dy2 N2 79.7(2) . . ?
O16 Dy2 N2 69.5(2) . . ?
O11 Dy2 N6 70.6(3) . . ?
O3 Dy2 N6 139.7(3) . . ?
O15 Dy2 N6 78.3(2) . . ?
O7 Dy2 N6 81.0(2) . . ?
O16 Dy2 N6 120.8(2) . . ?
N2 Dy2 N6 145.1(2) . . ?
O11 Dy2 O8 78.5(3) . . ?
O3 Dy2 O8 74.6(3) . . ?
O15 Dy2 O8 145.0(2) . . ?
O7 Dy2 O8 63.1(2) . . ?
O16 Dy2 O8 143.4(2) . . ?
N2 Dy2 O8 126.0(2) . . ?
N6 Dy2 O8 67.9(2) . . ?
C8 N1 C9 119.3(9) . . ?
C22 N2 C19 113.8(8) . . ?
C22 N2 Dy2 127.6(7) . . ?
C19 N2 Dy2 117.5(5) . . ?
C37 N3 C38 114.7(9) . . ?
C37 N3 Dy1 127.6(7) . . ?
C38 N3 Dy1 116.9(6) . . ?
C51 N4 C48 117.6(9) . . ?
C66 N5 C67 119.7(10) . . ?
C80 N6 C77 116.4(9) . . ?
C80 N6 Dy2 127.4(7) . . ?
C77 N6 Dy2 115.4(6) . . ?
C95 N7 C96 116.2(9) . . ?
C95 N7 Dy1 126.6(7) . . ?
C96 N7 Dy1 116.5(6) . . ?
C109 N8 C106 117.5(9) . . ?
C117 N9 C121 109.1(10) . . ?
C117 N9 C119 114.6(11) . . ?
C121 N9 C119 108.0(10) . . ?
C117 N9 C123 107.2(10) . . ?
C121 N9 C123 110.4(10) . . ?
C119 N9 C123 107.6(10) . . ?
C128 N10 C132 167.7(19) . . ?
C128 N10 C129 59.3(13) . . ?
C132 N10 C129 110.1(16) . . ?
C128 N10 C125 116.2(16) . . ?
C132 N10 C125 68.5(16) . . ?
C129 N10 C125 93.6(14) . . ?
C128 N10 C135 68.3(15) . . ?
C132 N10 C135 112.0(18) . . ?
C129 N10 C135 106.6(15) . . ?
C125 N10 C135 157.5(16) . . ?
C128 N10 C126 81.2(17) . . ?
C132 N10 C126 110(2) . . ?
C129 N10 C126 112.5(16) . . ?
C125 N10 C126 56.0(15) . . ?
C135 N10 C126 105.7(16) . . ?
C128 N10 C134 110.5(15) . . ?
C132 N10 C134 77.3(16) . . ?
C129 N10 C134 159.1(15) . . ?
C125 N10 C134 107.2(15) . . ?
C135 N10 C134 53.3(14) . . ?
C126 N10 C134 81.5(15) . . ?
C128 N10 C131 111.1(15) . . ?
C132 N10 C131 56.8(16) . . ?
C129 N10 C131 66.6(12) . . ?
C125 N10 C131 106.0(15) . . ?
C135 N10 C131 91.4(15) . . ?
C126 N10 C131 162.0(16) . . ?
C134 N10 C131 105.1(14) . . ?
C1 O1 Dy1 124.3(6) . . ?
C2 O2 C7 118.3(9) . . ?
C2 O2 Dy1 115.6(6) . . ?
C7 O2 Dy1 126.0(7) . . ?
C23 O3 Dy2 146.0(7) . . ?
C29 O4 C28 119.0(12) . . ?
C30 O5 Dy1 143.7(7) . . ?
C31 O6 C36 116.2(11) . . ?
C52 O7 Dy2 128.9(6) . . ?
C57 O8 C58 117.2(9) . . ?
C57 O8 Dy2 115.0(6) . . ?
C58 O8 Dy2 127.6(7) . . ?
C59 O9 Dy1 125.4(6) . . ?
C60 O10 C65 119.2(9) . . ?
C60 O10 Dy1 116.9(6) . . ?
C65 O10 Dy1 123.7(7) . . ?
C81 O11 Dy2 146.4(7) . . ?
C86 O12 C87 119.5(10) . . ?
C88 O13 Dy1 143.9(8) . . ?
C89 O14 C94 117.3(12) . . ?
C110 O15 Dy2 128.0(6) . . ?
C115 O16 C116 117.6(8) . . ?
C115 O16 Dy2 115.6(5) . . ?
C116 O16 Dy2 126.4(7) . . ?
O1 C1 C6 122.9(9) . . ?
O1 C1 C2 119.1(9) . . ?
C6 C1 C2 118.0(9) . . ?
C3 C2 O2 126.6(9) . . ?
C3 C2 C1 121.4(10) . . ?
O2 C2 C1 112.0(9) . . ?
C4 C3 C2 119.5(10) . . ?
C3 C4 C5 120.7(11) . . ?
C4 C5 C6 121.6(10) . . ?
C1 C6 C5 118.8(9) . . ?
C1 C6 C8 118.3(9) . . ?
C5 C6 C8 122.9(10) . . ?
N1 C8 C6 124.2(10) . . ?
C14 C9 C10 116.5(10) . . ?
C14 C9 N1 117.4(9) . . ?
C10 C9 N1 126.1(9) . . ?
C11 C10 C9 122.4(10) . . ?
C12 C11 C10 120.5(11) . . ?
C11 C12 C13 117.8(10) . . ?
C11 C12 C15 121.3(10) . . ?
C13 C12 C15 120.8(10) . . ?
C12 C13 C14 121.4(10) . . ?
C9 C14 C13 121.2(10) . . ?
C12 C15 C16 116.0(9) . . ?
C17 C16 C21 117.2(10) . . ?
C17 C16 C15 122.5(10) . . ?
C21 C16 C15 120.2(9) . . ?
C18 C17 C16 122.5(10) . . ?
C17 C18 C19 119.6(9) . . ?
C20 C19 C18 118.5(9) . . ?
C20 C19 N2 122.0(8) . . ?
C18 C19 N2 119.4(8) . . ?
C19 C20 C21 121.5(9) . . ?
C16 C21 C20 120.7(9) . . ?
N2 C22 C24 128.2(10) . . ?
O3 C23 C24 123.4(9) . . ?
O3 C23 C28 119.0(10) . . ?
C24 C23 C28 117.5(10) . . ?
C25 C24 C23 119.8(10) . . ?
C25 C24 C22 118.1(10) . . ?
C23 C24 C22 122.0(9) . . ?
C24 C25 C26 121.2(12) . . ?
C27 C26 C25 118.5(12) . . ?
C26 C27 C28 122.2(12) . . ?
C27 C28 O4 119.2(11) . . ?
C27 C28 C23 120.6(12) . . ?
O4 C28 C23 120.1(11) . . ?
O5 C30 C35 124.6(9) . . ?
O5 C30 C31 117.8(11) . . ?
C35 C30 C31 117.6(11) . . ?
C32 C31 O6 126.8(11) . . ?
C32 C31 C30 119.1(13) . . ?
O6 C31 C30 114.1(11) . . ?
C31 C32 C33 122.9(12) . . ?
C34 C33 C32 118.1(13) . . ?
C33 C34 C35 122.6(14) . . ?
C34 C35 C30 119.6(11) . . ?
C34 C35 C37 116.5(11) . . ?
C30 C35 C37 123.7(10) . . ?
N3 C37 C35 127.6(11) . . ?
C43 C38 C39 118.9(9) . . ?
C43 C38 N3 121.8(10) . . ?
C39 C38 N3 119.3(9) . . ?
C40 C39 C38 120.2(10) . . ?
C39 C40 C41 121.2(10) . . ?
C42 C41 C40 117.7(10) . . ?
C42 C41 C44 121.0(9) . . ?
C40 C41 C44 121.1(9) . . ?
C41 C42 C43 121.1(10) . . ?
C38 C43 C42 120.9(10) . . ?
C41 C44 C45 115.1(9) . . ?
C50 C45 C46 117.5(10) . . ?
C50 C45 C44 121.2(10) . . ?
C46 C45 C44 121.3(9) . . ?
C47 C46 C45 120.4(10) . . ?
C46 C47 C48 121.0(10) . . ?
C49 C48 C47 118.4(10) . . ?
C49 C48 N4 117.9(10) . . ?
C47 C48 N4 123.6(10) . . ?
C48 C49 C50 120.5(10) . . ?
C45 C50 C49 122.1(11) . . ?
N4 C51 C53 124.2(10) . . ?
O7 C52 C53 123.8(9) . . ?
O7 C52 C57 119.2(9) . . ?
C53 C52 C57 116.9(10) . . ?
C54 C53 C52 120.5(11) . . ?
C54 C53 C51 122.5(11) . . ?
C52 C53 C51 117.0(10) . . ?
C55 C54 C53 120.7(13) . . ?
C54 C55 C56 120.6(12) . . ?
C57 C56 C55 119.6(11) . . ?
C56 C57 O8 126.8(11) . . ?
C56 C57 C52 121.6(11) . . ?
O8 C57 C52 111.5(9) . . ?
O9 C59 C60 120.8(10) . . ?
O9 C59 C64 122.9(9) . . ?
C60 C59 C64 116.3(10) . . ?
C59 C60 O10 111.0(9) . . ?
C59 C60 C61 124.6(10) . . ?
O10 C60 C61 124.4(10) . . ?
C60 C61 C62 117.1(10) . . ?
C63 C62 C61 120.7(11) . . ?
C62 C63 C64 122.3(11) . . ?
C63 C64 C59 118.9(10) . . ?
C63 C64 C66 120.6(10) . . ?
C59 C64 C66 120.5(9) . . ?
N5 C66 C64 123.8(11) . . ?
C72 C67 N5 117.7(10) . . ?
C72 C67 C68 116.1(11) . . ?
N5 C67 C68 126.1(10) . . ?
C67 C68 C69 121.2(12) . . ?
C70 C69 C68 121.9(13) . . ?
C71 C70 C69 115.7(11) . . ?
C71 C70 C73 122.5(11) . . ?
C69 C70 C73 121.6(12) . . ?
C70 C71 C72 122.4(11) . . ?
C67 C72 C71 122.7(12) . . ?
C74 C73 C70 115.6(10) . . ?
C79 C74 C75 115.9(10) . . ?
C79 C74 C73 120.7(10) . . ?
C75 C74 C73 123.0(10) . . ?
C76 C75 C74 123.4(10) . . ?
C75 C76 C77 119.8(9) . . ?
C78 C77 C76 117.5(9) . . ?
C78 C77 N6 122.2(9) . . ?
C76 C77 N6 120.2(9) . . ?
C77 C78 C79 121.7(10) . . ?
C74 C79 C78 121.4(10) . . ?
N6 C80 C82 129.1(10) . . ?
O11 C81 C82 124.2(10) . . ?
O11 C81 C86 117.4(10) . . ?
C82 C81 C86 118.3(10) . . ?
C81 C82 C83 119.9(10) . . ?
C81 C82 C80 121.8(10) . . ?
C83 C82 C80 118.2(10) . . ?
C84 C83 C82 119.9(12) . . ?
C83 C84 C85 121.7(12) . . ?
C86 C85 C84 118.8(11) . . ?
C85 C86 O12 123.9(10) . . ?
C85 C86 C81 121.3(11) . . ?
O12 C86 C81 114.8(9) . . ?
O13 C88 C93 125.1(11) . . ?
O13 C88 C89 117.9(12) . . ?
C93 C88 C89 116.9(12) . . ?
O14 C89 C90 126.3(13) . . ?
O14 C89 C88 114.4(12) . . ?
C90 C89 C88 119.3(15) . . ?
C91 C90 C89 122.6(14) . . ?
C92 C91 C90 118.6(15) . . ?
C91 C92 C93 122.5(16) . . ?
C88 C93 C92 120.0(12) . . ?
C88 C93 C95 121.8(10) . . ?
C92 C93 C95 118.0(12) . . ?
N7 C95 C93 129.2(11) . . ?
C101 C96 C97 118.4(9) . . ?
C101 C96 N7 123.6(8) . . ?
C97 C96 N7 118.0(9) . . ?
C96 C97 C98 119.7(10) . . ?
C97 C98 C99 122.0(10) . . ?
C100 C99 C98 117.0(10) . . ?
C100 C99 C102 120.5(10) . . ?
C98 C99 C102 122.3(10) . . ?
C99 C100 C101 121.0(10) . . ?
C96 C101 C100 121.9(10) . . ?
C99 C102 C103 117.0(9) . . ?
C104 C103 C108 116.9(10) . . ?
C104 C103 C102 120.8(9) . . ?
C108 C103 C102 122.0(9) . . ?
C103 C104 C105 122.3(10) . . ?
C104 C105 C106 120.6(11) . . ?
C107 C106 C105 117.7(10) . . ?
C107 C106 N8 116.4(9) . . ?
C105 C106 N8 125.8(9) . . ?
C106 C107 C108 120.9(10) . . ?
C107 C108 C103 121.6(10) . . ?
N8 C109 C111 124.0(10) . . ?
O15 C110 C115 120.2(9) . . ?
O15 C110 C111 121.8(8) . . ?
C115 C110 C111 118.0(9) . . ?
C112 C111 C110 119.5(10) . . ?
C112 C111 C109 122.2(10) . . ?
C110 C111 C109 118.2(9) . . ?
C113 C112 C111 120.5(11) . . ?
C112 C113 C114 120.2(11) . . ?
C115 C114 C113 120.1(10) . . ?
C114 C115 O16 127.0(10) . . ?
C114 C115 C110 121.6(10) . . ?
O16 C115 C110 111.4(9) . . ?
N9 C117 C118 115.6(11) . . ?
N9 C119 C120 114.9(12) . . ?
N9 C121 C122 115.8(12) . . ?
C124 C123 N9 116.2(12) . . ?
C127 C125 N10 118.0(19) . . ?
N10 C128 C130 117.8(17) . . ?
C133 C131 N10 118.7(17) . . ?
C136 C134 N10 124(2) . . ?
C127 C126 N10 120(2) . . ?
C130 C129 N10 116.4(16) . . ?
N10 C132 C133 121(2) . . ?
C136 C135 N10 120(2) . . ?
C126 C127 C125 61.4(17) . . ?
C129 C130 C128 58.2(14) . . ?
C131 C133 C132 59.1(14) . . ?
C134 C136 C135 61.1(16) . . ?
O17 C138 C137 111.7(12) . . ?
C139 O17 C138 114.5(10) . . ?
O17 C139 C140 108.5(11) . . ?
O18 C142 C141 117(3) . . ?
C142 O18 C143 113(2) . . ?
O18 C143 C144 110(3) . . ?
O19 C146 C145 120(3) . . ?
C147 O19 C146 135(3) . . ?
O19 C147 C148 101(3) . . ?
O20 C150 C151 121.2(13) . . ?
O20 C150 C149 119.9(13) . . ?
C151 C150 C149 118.8(13) . . ?
O21 C153 C154 115(3) . . ?
O21 C153 C152 127(3) . . ?
C154 C153 C152 116(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O11 Dy2 N2 C22 52.2(10) . . . . ?
O3 Dy2 N2 C22 -11.6(8) . . . . ?
O15 Dy2 N2 C22 142.6(9) . . . . ?
O7 Dy2 N2 C22 -110.6(9) . . . . ?
O16 Dy2 N2 C22 77.0(9) . . . . ?
N6 Dy2 N2 C22 -168.2(8) . . . . ?
O8 Dy2 N2 C22 -65.0(9) . . . . ?
O11 Dy2 N2 C19 -114.7(7) . . . . ?
O3 Dy2 N2 C19 -178.5(7) . . . . ?
O15 Dy2 N2 C19 -24.3(6) . . . . ?
O7 Dy2 N2 C19 82.5(6) . . . . ?
O16 Dy2 N2 C19 -89.9(6) . . . . ?
N6 Dy2 N2 C19 24.9(8) . . . . ?
O8 Dy2 N2 C19 128.1(6) . . . . ?
O13 Dy1 N3 C37 -53.7(10) . . . . ?
O5 Dy1 N3 C37 8.6(8) . . . . ?
O9 Dy1 N3 C37 110.7(9) . . . . ?
O1 Dy1 N3 C37 -142.1(9) . . . . ?
O10 Dy1 N3 C37 62.8(9) . . . . ?
O2 Dy1 N3 C37 -75.4(8) . . . . ?
N7 Dy1 N3 C37 163.6(8) . . . . ?
O13 Dy1 N3 C38 115.3(7) . . . . ?
O5 Dy1 N3 C38 177.6(7) . . . . ?
O9 Dy1 N3 C38 -80.3(7) . . . . ?
O1 Dy1 N3 C38 26.9(7) . . . . ?
O10 Dy1 N3 C38 -128.2(6) . . . . ?
O2 Dy1 N3 C38 93.6(7) . . . . ?
N7 Dy1 N3 C38 -27.4(9) . . . . ?
O11 Dy2 N6 C80 -5.5(9) . . . . ?
O3 Dy2 N6 C80 57.0(10) . . . . ?
O15 Dy2 N6 C80 -109.3(9) . . . . ?
O7 Dy2 N6 C80 144.2(9) . . . . ?
O16 Dy2 N6 C80 -60.4(9) . . . . ?
N2 Dy2 N6 C80 -158.6(8) . . . . ?
O8 Dy2 N6 C80 79.7(9) . . . . ?
O11 Dy2 N6 C77 -174.8(7) . . . . ?
O3 Dy2 N6 C77 -112.3(7) . . . . ?
O15 Dy2 N6 C77 81.4(6) . . . . ?
O7 Dy2 N6 C77 -25.1(6) . . . . ?
O16 Dy2 N6 C77 130.3(6) . . . . ?
N2 Dy2 N6 C77 32.1(9) . . . . ?
O8 Dy2 N6 C77 -89.6(7) . . . . ?
O13 Dy1 N7 C95 4.7(8) . . . . ?
O5 Dy1 N7 C95 -58.5(10) . . . . ?
O9 Dy1 N7 C95 -145.3(9) . . . . ?
O1 Dy1 N7 C95 107.3(9) . . . . ?
O10 Dy1 N7 C95 -78.4(8) . . . . ?
O2 Dy1 N7 C95 59.9(9) . . . . ?
N3 Dy1 N7 C95 161.9(8) . . . . ?
O13 Dy1 N7 C96 174.7(7) . . . . ?
O5 Dy1 N7 C96 111.5(7) . . . . ?
O9 Dy1 N7 C96 24.7(6) . . . . ?
O1 Dy1 N7 C96 -82.7(6) . . . . ?
O10 Dy1 N7 C96 91.6(6) . . . . ?
O2 Dy1 N7 C96 -130.2(6) . . . . ?
N3 Dy1 N7 C96 -28.1(8) . . . . ?
O13 Dy1 O1 C1 -86.1(7) . . . . ?
O5 Dy1 O1 C1 10.8(9) . . . . ?
O9 Dy1 O1 C1 130.1(7) . . . . ?
O10 Dy1 O1 C1 -166.2(6) . . . . ?
O2 Dy1 O1 C1 -18.5(7) . . . . ?
N3 Dy1 O1 C1 56.0(7) . . . . ?
N7 Dy1 O1 C1 -155.9(7) . . . . ?
O13 Dy1 O2 C2 123.9(7) . . . . ?
O5 Dy1 O2 C2 -144.4(7) . . . . ?
O9 Dy1 O2 C2 -58.3(9) . . . . ?
O1 Dy1 O2 C2 16.5(7) . . . . ?
O10 Dy1 O2 C2 170.6(6) . . . . ?
N3 Dy1 O2 C2 -69.7(7) . . . . ?
N7 Dy1 O2 C2 69.3(7) . . . . ?
O13 Dy1 O2 C7 -58.8(9) . . . . ?
O5 Dy1 O2 C7 33.0(9) . . . . ?
O9 Dy1 O2 C7 119.1(9) . . . . ?
O1 Dy1 O2 C7 -166.2(9) . . . . ?
O10 Dy1 O2 C7 -12.1(10) . . . . ?
N3 Dy1 O2 C7 107.6(9) . . . . ?
N7 Dy1 O2 C7 -113.3(9) . . . . ?
O11 Dy2 O3 C23 -128.4(13) . . . . ?
O15 Dy2 O3 C23 -26.5(15) . . . . ?
O7 Dy2 O3 C23 92.7(13) . . . . ?
O16 Dy2 O3 C23 -55.5(13) . . . . ?
N2 Dy2 O3 C23 15.4(12) . . . . ?
N6 Dy2 O3 C23 174.8(11) . . . . ?
O8 Dy2 O3 C23 153.1(13) . . . . ?
O13 Dy1 O5 C30 143.0(12) . . . . ?
O9 Dy1 O5 C30 -78.8(12) . . . . ?
O1 Dy1 O5 C30 42.6(13) . . . . ?
O10 Dy1 O5 C30 -139.1(12) . . . . ?
O2 Dy1 O5 C30 69.3(12) . . . . ?
N3 Dy1 O5 C30 -4.4(11) . . . . ?
N7 Dy1 O5 C30 -158.8(10) . . . . ?
O11 Dy2 O7 C52 -9.3(10) . . . . ?
O3 Dy2 O7 C52 84.0(8) . . . . ?
O15 Dy2 O7 C52 -131.1(8) . . . . ?
O16 Dy2 O7 C52 167.3(7) . . . . ?
N2 Dy2 O7 C52 153.6(8) . . . . ?
N6 Dy2 O7 C52 -55.6(8) . . . . ?
O8 Dy2 O7 C52 14.0(7) . . . . ?
O11 Dy2 O8 C57 153.9(7) . . . . ?
O3 Dy2 O8 C57 -114.6(7) . . . . ?
O15 Dy2 O8 C57 64.9(8) . . . . ?
O7 Dy2 O8 C57 -10.7(7) . . . . ?
O16 Dy2 O8 C57 -167.3(6) . . . . ?
N2 Dy2 O8 C57 -62.7(8) . . . . ?
N6 Dy2 O8 C57 80.4(7) . . . . ?
O11 Dy2 O8 C58 -21.1(9) . . . . ?
O3 Dy2 O8 C58 70.3(9) . . . . ?
O15 Dy2 O8 C58 -110.1(9) . . . . ?
O7 Dy2 O8 C58 174.3(9) . . . . ?
O16 Dy2 O8 C58 17.7(10) . . . . ?
N2 Dy2 O8 C58 122.2(9) . . . . ?
N6 Dy2 O8 C58 -94.7(9) . . . . ?
O13 Dy1 O9 C59 17.8(9) . . . . ?
O5 Dy1 O9 C59 -78.3(8) . . . . ?
O1 Dy1 O9 C59 137.0(7) . . . . ?
O10 Dy1 O9 C59 -11.5(7) . . . . ?
O2 Dy1 O9 C59 -159.1(7) . . . . ?
N3 Dy1 O9 C59 -148.0(8) . . . . ?
N7 Dy1 O9 C59 63.2(7) . . . . ?
O13 Dy1 O10 C60 -151.2(7) . . . . ?
O5 Dy1 O10 C60 116.6(7) . . . . ?
O9 Dy1 O10 C60 9.2(6) . . . . ?
O1 Dy1 O10 C60 -65.4(9) . . . . ?
O2 Dy1 O10 C60 163.3(6) . . . . ?
N3 Dy1 O10 C60 62.7(7) . . . . ?
N7 Dy1 O10 C60 -76.1(7) . . . . ?
O13 Dy1 O10 C65 35.4(9) . . . . ?
O5 Dy1 O10 C65 -56.8(9) . . . . ?
O9 Dy1 O10 C65 -164.2(10) . . . . ?
O1 Dy1 O10 C65 121.2(9) . . . . ?
O2 Dy1 O10 C65 -10.1(11) . . . . ?
N3 Dy1 O10 C65 -110.7(9) . . . . ?
N7 Dy1 O10 C65 110.5(9) . . . . ?
O3 Dy2 O11 C81 -137.4(13) . . . . ?
O15 Dy2 O11 C81 81.8(13) . . . . ?
O7 Dy2 O11 C81 -41.6(15) . . . . ?
O16 Dy2 O11 C81 140.3(14) . . . . ?
N2 Dy2 O11 C81 164.5(12) . . . . ?
N6 Dy2 O11 C81 7.6(13) . . . . ?
O8 Dy2 O11 C81 -62.7(13) . . . . ?
O5 Dy1 O13 C88 152.8(12) . . . . ?
O9 Dy1 O13 C88 53.3(13) . . . . ?
O1 Dy1 O13 C88 -67.9(12) . . . . ?
O10 Dy1 O13 C88 80.2(12) . . . . ?
O2 Dy1 O13 C88 -128.4(12) . . . . ?
N3 Dy1 O13 C88 -149.8(11) . . . . ?
N7 Dy1 O13 C88 6.4(12) . . . . ?
O11 Dy2 O15 C110 76.8(7) . . . . ?
O3 Dy2 O15 C110 -21.4(9) . . . . ?
O7 Dy2 O15 C110 -137.7(7) . . . . ?
O16 Dy2 O15 C110 11.2(7) . . . . ?
N2 Dy2 O15 C110 -61.5(7) . . . . ?
N6 Dy2 O15 C110 144.8(8) . . . . ?
O8 Dy2 O15 C110 159.4(6) . . . . ?
O11 Dy2 O16 C115 -118.6(7) . . . . ?
O3 Dy2 O16 C115 150.7(7) . . . . ?
O15 Dy2 O16 C115 -9.1(6) . . . . ?
O7 Dy2 O16 C115 63.7(8) . . . . ?
N2 Dy2 O16 C115 78.1(7) . . . . ?
N6 Dy2 O16 C115 -64.7(7) . . . . ?
O8 Dy2 O16 C115 -158.6(6) . . . . ?
O11 Dy2 O16 C116 68.5(8) . . . . ?
O3 Dy2 O16 C116 -22.2(8) . . . . ?
O15 Dy2 O16 C116 178.0(8) . . . . ?
O7 Dy2 O16 C116 -109.2(8) . . . . ?
N2 Dy2 O16 C116 -94.7(8) . . . . ?
N6 Dy2 O16 C116 122.4(8) . . . . ?
O8 Dy2 O16 C116 28.5(9) . . . . ?
Dy1 O1 C1 C6 -161.7(7) . . . . ?
Dy1 O1 C1 C2 19.2(12) . . . . ?
C7 O2 C2 C3 -12.9(17) . . . . ?
Dy1 O2 C2 C3 164.7(10) . . . . ?
C7 O2 C2 C1 168.8(10) . . . . ?
Dy1 O2 C2 C1 -13.6(11) . . . . ?
O1 C1 C2 C3 -179.7(10) . . . . ?
C6 C1 C2 C3 1.2(16) . . . . ?
O1 C1 C2 O2 -1.3(14) . . . . ?
C6 C1 C2 O2 179.6(9) . . . . ?
O2 C2 C3 C4 -180.0(11) . . . . ?
C1 C2 C3 C4 -1.8(18) . . . . ?
C2 C3 C4 C5 2.1(19) . . . . ?
C3 C4 C5 C6 -2(2) . . . . ?
O1 C1 C6 C5 -179.8(9) . . . . ?
C2 C1 C6 C5 -0.7(15) . . . . ?
O1 C1 C6 C8 2.1(15) . . . . ?
C2 C1 C6 C8 -178.8(9) . . . . ?
C4 C5 C6 C1 1.0(17) . . . . ?
C4 C5 C6 C8 178.9(11) . . . . ?
C9 N1 C8 C6 -179.1(9) . . . . ?
C1 C6 C8 N1 -178.9(9) . . . . ?
C5 C6 C8 N1 3.1(16) . . . . ?
C8 N1 C9 C14 -165.5(10) . . . . ?
C8 N1 C9 C10 18.6(15) . . . . ?
C14 C9 C10 C11 4.8(17) . . . . ?
N1 C9 C10 C11 -179.2(10) . . . . ?
C9 C10 C11 C12 -1.7(18) . . . . ?
C10 C11 C12 C13 -2.0(17) . . . . ?
C10 C11 C12 C15 -180.0(10) . . . . ?
C11 C12 C13 C14 2.5(17) . . . . ?
C15 C12 C13 C14 -179.5(10) . . . . ?
C10 C9 C14 C13 -4.2(17) . . . . ?
N1 C9 C14 C13 179.4(10) . . . . ?
C12 C13 C14 C9 0.7(18) . . . . ?
C11 C12 C15 C16 102.7(12) . . . . ?
C13 C12 C15 C16 -75.2(13) . . . . ?
C12 C15 C16 C17 -59.1(14) . . . . ?
C12 C15 C16 C21 124.6(11) . . . . ?
C21 C16 C17 C18 2.3(16) . . . . ?
C15 C16 C17 C18 -174.1(10) . . . . ?
C16 C17 C18 C19 0.4(16) . . . . ?
C17 C18 C19 C20 -2.5(15) . . . . ?
C17 C18 C19 N2 174.4(9) . . . . ?
C22 N2 C19 C20 -43.8(13) . . . . ?
Dy2 N2 C19 C20 124.9(9) . . . . ?
C22 N2 C19 C18 139.4(10) . . . . ?
Dy2 N2 C19 C18 -51.9(10) . . . . ?
C18 C19 C20 C21 1.8(16) . . . . ?
N2 C19 C20 C21 -175.0(10) . . . . ?
C17 C16 C21 C20 -2.9(16) . . . . ?
C15 C16 C21 C20 173.5(10) . . . . ?
C19 C20 C21 C16 0.9(17) . . . . ?
C19 N2 C22 C24 175.8(10) . . . . ?
Dy2 N2 C22 C24 8.4(16) . . . . ?
Dy2 O3 C23 C24 -12(2) . . . . ?
Dy2 O3 C23 C28 170.2(9) . . . . ?
O3 C23 C24 C25 178.8(11) . . . . ?
C28 C23 C24 C25 -3.6(16) . . . . ?
O3 C23 C24 C22 -2.0(17) . . . . ?
C28 C23 C24 C22 175.6(10) . . . . ?
N2 C22 C24 C25 -179.7(11) . . . . ?
N2 C22 C24 C23 1.1(18) . . . . ?
C23 C24 C25 C26 2.6(18) . . . . ?
C22 C24 C25 C26 -176.6(12) . . . . ?
C24 C25 C26 C27 -1(2) . . . . ?
C25 C26 C27 C28 0(2) . . . . ?
C26 C27 C28 O4 174.9(13) . . . . ?
C26 C27 C28 C23 -1(2) . . . . ?
C29 O4 C28 C27 113.3(15) . . . . ?
C29 O4 C28 C23 -70.5(16) . . . . ?
O3 C23 C28 C27 -179.3(11) . . . . ?
C24 C23 C28 C27 3.0(18) . . . . ?
O3 C23 C28 O4 4.5(17) . . . . ?
C24 C23 C28 O4 -173.2(10) . . . . ?
Dy1 O5 C30 C35 -0.8(19) . . . . ?
Dy1 O5 C30 C31 178.3(8) . . . . ?
C36 O6 C31 C32 12.0(18) . . . . ?
C36 O6 C31 C30 -166.5(10) . . . . ?
O5 C30 C31 C32 178.4(11) . . . . ?
C35 C30 C31 C32 -2.4(16) . . . . ?
O5 C30 C31 O6 -2.9(14) . . . . ?
C35 C30 C31 O6 176.2(10) . . . . ?
O6 C31 C32 C33 -177.4(12) . . . . ?
C30 C31 C32 C33 1.0(19) . . . . ?
C31 C32 C33 C34 1(2) . . . . ?
C32 C33 C34 C35 -2(2) . . . . ?
C33 C34 C35 C30 0.9(19) . . . . ?
C33 C34 C35 C37 176.6(12) . . . . ?
O5 C30 C35 C34 -179.4(11) . . . . ?
C31 C30 C35 C34 1.5(16) . . . . ?
O5 C30 C35 C37 5.2(18) . . . . ?
C31 C30 C35 C37 -173.9(10) . . . . ?
C38 N3 C37 C35 -178.1(10) . . . . ?
Dy1 N3 C37 C35 -8.9(16) . . . . ?
C34 C35 C37 N3 -174.8(11) . . . . ?
C30 C35 C37 N3 0.7(18) . . . . ?
C37 N3 C38 C43 46.1(13) . . . . ?
Dy1 N3 C38 C43 -124.4(9) . . . . ?
C37 N3 C38 C39 -135.7(10) . . . . ?
Dy1 N3 C38 C39 53.9(10) . . . . ?
C43 C38 C39 C40 0.8(15) . . . . ?
N3 C38 C39 C40 -177.5(9) . . . . ?
C38 C39 C40 C41 0.2(15) . . . . ?
C39 C40 C41 C42 -1.1(15) . . . . ?
C39 C40 C41 C44 173.6(10) . . . . ?
C40 C41 C42 C43 1.1(15) . . . . ?
C44 C41 C42 C43 -173.6(10) . . . . ?
C39 C38 C43 C42 -0.9(15) . . . . ?
N3 C38 C43 C42 177.4(9) . . . . ?
C41 C42 C43 C38 -0.1(16) . . . . ?
C42 C41 C44 C45 -127.8(11) . . . . ?
C40 C41 C44 C45 57.7(13) . . . . ?
C41 C44 C45 C50 81.0(13) . . . . ?
C41 C44 C45 C46 -96.7(12) . . . . ?
C50 C45 C46 C47 1.6(17) . . . . ?
C44 C45 C46 C47 179.3(11) . . . . ?
C45 C46 C47 C48 0.3(19) . . . . ?
C46 C47 C48 C49 -2.4(18) . . . . ?
C46 C47 C48 N4 -179.5(11) . . . . ?
C51 N4 C48 C49 149.8(11) . . . . ?
C51 N4 C48 C47 -33.1(16) . . . . ?
C47 C48 C49 C50 2.7(18) . . . . ?
N4 C48 C49 C50 180.0(11) . . . . ?
C46 C45 C50 C49 -1.3(17) . . . . ?
C44 C45 C50 C49 -179.0(10) . . . . ?
C48 C49 C50 C45 -0.9(19) . . . . ?
C48 N4 C51 C53 179.1(10) . . . . ?
Dy2 O7 C52 C53 166.8(8) . . . . ?
Dy2 O7 C52 C57 -15.9(14) . . . . ?
O7 C52 C53 C54 -178.7(11) . . . . ?
C57 C52 C53 C54 3.9(17) . . . . ?
O7 C52 C53 C51 -0.7(17) . . . . ?
C57 C52 C53 C51 -178.1(10) . . . . ?
N4 C51 C53 C54 -3.3(19) . . . . ?
N4 C51 C53 C52 178.7(11) . . . . ?
C52 C53 C54 C55 -3(2) . . . . ?
C51 C53 C54 C55 179.4(14) . . . . ?
C53 C54 C55 C56 1(3) . . . . ?
C54 C55 C56 C57 -1(3) . . . . ?
C55 C56 C57 O8 177.8(13) . . . . ?
C55 C56 C57 C52 3(2) . . . . ?
C58 O8 C57 C56 7.8(18) . . . . ?
Dy2 O8 C57 C56 -167.8(11) . . . . ?
C58 O8 C57 C52 -176.7(10) . . . . ?
Dy2 O8 C57 C52 7.7(11) . . . . ?
O7 C52 C57 C56 178.5(11) . . . . ?
C53 C52 C57 C56 -4.0(17) . . . . ?
O7 C52 C57 O8 2.8(14) . . . . ?
C53 C52 C57 O8 -179.8(10) . . . . ?
Dy1 O9 C59 C60 13.0(13) . . . . ?
Dy1 O9 C59 C64 -168.7(7) . . . . ?
O9 C59 C60 O10 -2.7(13) . . . . ?
C64 C59 C60 O10 178.9(9) . . . . ?
O9 C59 C60 C61 176.3(10) . . . . ?
C64 C59 C60 C61 -2.1(16) . . . . ?
C65 O10 C60 C59 167.0(10) . . . . ?
Dy1 O10 C60 C59 -6.7(11) . . . . ?
C65 O10 C60 C61 -12.1(16) . . . . ?
Dy1 O10 C60 C61 174.2(9) . . . . ?
C59 C60 C61 C62 0.7(18) . . . . ?
O10 C60 C61 C62 179.7(11) . . . . ?
C60 C61 C62 C63 -0.5(19) . . . . ?
C61 C62 C63 C64 2(2) . . . . ?
C62 C63 C64 C59 -3.2(18) . . . . ?
C62 C63 C64 C66 178.1(12) . . . . ?
O9 C59 C64 C63 -175.2(10) . . . . ?
C60 C59 C64 C63 3.1(15) . . . . ?
O9 C59 C64 C66 3.5(15) . . . . ?
C60 C59 C64 C66 -178.1(9) . . . . ?
C67 N5 C66 C64 177.8(10) . . . . ?
C63 C64 C66 N5 2.6(17) . . . . ?
C59 C64 C66 N5 -176.2(10) . . . . ?
C66 N5 C67 C72 173.0(11) . . . . ?
C66 N5 C67 C68 -9.9(19) . . . . ?
C72 C67 C68 C69 2(2) . . . . ?
N5 C67 C68 C69 -175.4(15) . . . . ?
C67 C68 C69 C70 -2(3) . . . . ?
C68 C69 C70 C71 1(2) . . . . ?
C68 C69 C70 C73 175.9(15) . . . . ?
C69 C70 C71 C72 0(2) . . . . ?
C73 C70 C71 C72 -174.6(12) . . . . ?
N5 C67 C72 C71 176.9(12) . . . . ?
C68 C67 C72 C71 -1(2) . . . . ?
C70 C71 C72 C67 0(2) . . . . ?
C71 C70 C73 C74 -64.0(16) . . . . ?
C69 C70 C73 C74 121.6(14) . . . . ?
C70 C73 C74 C79 132.3(12) . . . . ?
C70 C73 C74 C75 -55.0(16) . . . . ?
C79 C74 C75 C76 2.0(17) . . . . ?
C73 C74 C75 C76 -171.0(11) . . . . ?
C74 C75 C76 C77 1.3(16) . . . . ?
C75 C76 C77 C78 -4.8(15) . . . . ?
C75 C76 C77 N6 172.5(9) . . . . ?
C80 N6 C77 C78 -44.4(14) . . . . ?
Dy2 N6 C77 C78 126.1(9) . . . . ?
C80 N6 C77 C76 138.4(10) . . . . ?
Dy2 N6 C77 C76 -51.0(11) . . . . ?
C76 C77 C78 C79 4.9(17) . . . . ?
N6 C77 C78 C79 -172.3(10) . . . . ?
C75 C74 C79 C78 -1.9(18) . . . . ?
C73 C74 C79 C78 171.3(11) . . . . ?
C77 C78 C79 C74 -1.6(19) . . . . ?
C77 N6 C80 C82 173.3(11) . . . . ?
Dy2 N6 C80 C82 4.0(17) . . . . ?
Dy2 O11 C81 C82 -7(2) . . . . ?
Dy2 O11 C81 C86 171.2(9) . . . . ?
O11 C81 C82 C83 179.7(11) . . . . ?
C86 C81 C82 C83 2.0(17) . . . . ?
O11 C81 C82 C80 -0.3(18) . . . . ?
C86 C81 C82 C80 -178.0(10) . . . . ?
N6 C80 C82 C81 0.1(19) . . . . ?
N6 C80 C82 C83 -179.9(12) . . . . ?
C81 C82 C83 C84 -1(2) . . . . ?
C80 C82 C83 C84 178.6(13) . . . . ?
C82 C83 C84 C85 1(2) . . . . ?
C83 C84 C85 C86 -1(2) . . . . ?
C84 C85 C86 O12 -177.8(12) . . . . ?
C84 C85 C86 C81 1(2) . . . . ?
C87 O12 C86 C85 4.2(19) . . . . ?
C87 O12 C86 C81 -174.9(12) . . . . ?
O11 C81 C86 C85 -179.8(12) . . . . ?
C82 C81 C86 C85 -1.9(17) . . . . ?
O11 C81 C86 O12 -0.7(15) . . . . ?
C82 C81 C86 O12 177.2(10) . . . . ?
Dy1 O13 C88 C93 -12(2) . . . . ?
Dy1 O13 C88 C89 165.7(9) . . . . ?
C94 O14 C89 C90 11(2) . . . . ?
C94 O14 C89 C88 -169.1(12) . . . . ?
O13 C88 C89 O14 0.0(15) . . . . ?
C93 C88 C89 O14 178.0(10) . . . . ?
O13 C88 C89 C90 -179.7(12) . . . . ?
C93 C88 C89 C90 -1.7(17) . . . . ?
O14 C89 C90 C91 179.8(14) . . . . ?
C88 C89 C90 C91 -1(2) . . . . ?
C89 C90 C91 C92 2(3) . . . . ?
C90 C91 C92 C93 -1(3) . . . . ?
O13 C88 C93 C92 -179.5(12) . . . . ?
C89 C88 C93 C92 2.6(17) . . . . ?
O13 C88 C93 C95 5.3(18) . . . . ?
C89 C88 C93 C95 -172.6(10) . . . . ?
C91 C92 C93 C88 -2(2) . . . . ?
C91 C92 C93 C95 173.9(14) . . . . ?
C96 N7 C95 C93 179.7(10) . . . . ?
Dy1 N7 C95 C93 -10.3(16) . . . . ?
C88 C93 C95 N7 5.7(19) . . . . ?
C92 C93 C95 N7 -169.6(12) . . . . ?
C95 N7 C96 C101 47.3(14) . . . . ?
Dy1 N7 C96 C101 -123.8(9) . . . . ?
C95 N7 C96 C97 -135.3(10) . . . . ?
Dy1 N7 C96 C97 53.6(10) . . . . ?
C101 C96 C97 C98 1.1(14) . . . . ?
N7 C96 C97 C98 -176.4(9) . . . . ?
C96 C97 C98 C99 0.3(15) . . . . ?
C97 C98 C99 C100 -0.6(15) . . . . ?
C97 C98 C99 C102 173.8(10) . . . . ?
C98 C99 C100 C101 -0.5(15) . . . . ?
C102 C99 C100 C101 -175.1(10) . . . . ?
C97 C96 C101 C100 -2.3(15) . . . . ?
N7 C96 C101 C100 175.1(9) . . . . ?
C99 C100 C101 C96 2.0(16) . . . . ?
C100 C99 C102 C103 -133.7(11) . . . . ?
C98 C99 C102 C103 52.0(15) . . . . ?
C99 C102 C103 C104 -147.5(11) . . . . ?
C99 C102 C103 C108 39.1(15) . . . . ?
C108 C103 C104 C105 2.1(16) . . . . ?
C102 C103 C104 C105 -171.6(11) . . . . ?
C103 C104 C105 C106 -2.4(18) . . . . ?
C104 C105 C106 C107 2.5(16) . . . . ?
C104 C105 C106 N8 177.9(10) . . . . ?
C109 N8 C106 C107 -154.5(9) . . . . ?
C109 N8 C106 C105 30.0(15) . . . . ?
C105 C106 C107 C108 -2.5(15) . . . . ?
N8 C106 C107 C108 -178.3(9) . . . . ?
C106 C107 C108 C103 2.3(15) . . . . ?
C104 C103 C108 C107 -2.1(15) . . . . ?
C102 C103 C108 C107 171.6(10) . . . . ?
C106 N8 C109 C111 179.2(9) . . . . ?
Dy2 O15 C110 C115 -12.4(12) . . . . ?
Dy2 O15 C110 C111 168.4(7) . . . . ?
O15 C110 C111 C112 179.5(10) . . . . ?
C115 C110 C111 C112 0.3(15) . . . . ?
O15 C110 C111 C109 -4.9(14) . . . . ?
C115 C110 C111 C109 175.9(9) . . . . ?
N8 C109 C111 C112 -9.2(17) . . . . ?
N8 C109 C111 C110 175.4(10) . . . . ?
C110 C111 C112 C113 -2.2(18) . . . . ?
C109 C111 C112 C113 -177.5(12) . . . . ?
C111 C112 C113 C114 2(2) . . . . ?
C112 C113 C114 C115 -1(2) . . . . ?
C113 C114 C115 O16 179.5(11) . . . . ?
C113 C114 C115 C110 -0.9(18) . . . . ?
C116 O16 C115 C114 0.1(16) . . . . ?
Dy2 O16 C115 C114 -173.5(9) . . . . ?
C116 O16 C115 C110 -179.6(9) . . . . ?
Dy2 O16 C115 C110 6.9(10) . . . . ?
O15 C110 C115 C114 -178.0(10) . . . . ?
C111 C110 C115 C114 1.2(15) . . . . ?
O15 C110 C115 O16 1.6(13) . . . . ?
C111 C110 C115 O16 -179.2(8) . . . . ?
C121 N9 C117 C118 172.3(13) . . . . ?
C119 N9 C117 C118 51.1(18) . . . . ?
C123 N9 C117 C118 -68.2(16) . . . . ?
C117 N9 C119 C120 55.2(17) . . . . ?
C121 N9 C119 C120 -66.6(15) . . . . ?
C123 N9 C119 C120 174.3(12) . . . . ?
C117 N9 C121 C122 64.3(15) . . . . ?
C119 N9 C121 C122 -170.6(12) . . . . ?
C123 N9 C121 C122 -53.2(14) . . . . ?
C117 N9 C123 C124 -172.2(12) . . . . ?
C121 N9 C123 C124 -53.5(15) . . . . ?
C119 N9 C123 C124 64.1(15) . . . . ?
C128 N10 C125 C127 41(3) . . . . ?
C132 N10 C125 C127 -151(3) . . . . ?
C129 N10 C125 C127 99(2) . . . . ?
C135 N10 C125 C127 -55(6) . . . . ?
C126 N10 C125 C127 -16(2) . . . . ?
C134 N10 C125 C127 -83(2) . . . . ?
C131 N10 C125 C127 165(2) . . . . ?
C132 N10 C128 C130 -55(9) . . . . ?
C129 N10 C128 C130 -22.5(17) . . . . ?
C125 N10 C128 C130 55(2) . . . . ?
C135 N10 C128 C130 -149(2) . . . . ?
C126 N10 C128 C130 100(2) . . . . ?
C134 N10 C128 C130 177.7(18) . . . . ?
C131 N10 C128 C130 -66(2) . . . . ?
C128 N10 C131 C133 -166.3(18) . . . . ?
C132 N10 C131 C133 16.5(19) . . . . ?
C129 N10 C131 C133 154(2) . . . . ?
C125 N10 C131 C133 67(2) . . . . ?
C135 N10 C131 C133 -99(2) . . . . ?
C126 N10 C131 C133 63(6) . . . . ?
C134 N10 C131 C133 -47(2) . . . . ?
C128 N10 C134 C136 50(3) . . . . ?
C132 N10 C134 C136 -120(3) . . . . ?
C129 N10 C134 C136 -7(6) . . . . ?
C125 N10 C134 C136 177(2) . . . . ?
C135 N10 C134 C136 10(2) . . . . ?
C126 N10 C134 C136 127(3) . . . . ?
C131 N10 C134 C136 -70(3) . . . . ?
C128 N10 C126 C127 -113(3) . . . . ?
C132 N10 C126 C127 62(3) . . . . ?
C129 N10 C126 C127 -61(3) . . . . ?
C125 N10 C126 C127 17(2) . . . . ?
C135 N10 C126 C127 -177(3) . . . . ?
C134 N10 C126 C127 135(3) . . . . ?
C131 N10 C126 C127 22(7) . . . . ?
C128 N10 C129 C130 23.6(18) . . . . ?
C132 N10 C129 C130 -163(2) . . . . ?
C125 N10 C129 C130 -95(2) . . . . ?
C135 N10 C129 C130 75(2) . . . . ?
C126 N10 C129 C130 -40(2) . . . . ?
C134 N10 C129 C130 89(5) . . . . ?
C131 N10 C129 C130 159(2) . . . . ?
C128 N10 C132 C133 -29(9) . . . . ?
C129 N10 C132 C133 -58(3) . . . . ?
C125 N10 C132 C133 -144(3) . . . . ?
C135 N10 C132 C133 61(3) . . . . ?
C126 N10 C132 C133 178(2) . . . . ?
C134 N10 C132 C133 102(2) . . . . ?
C131 N10 C132 C133 -16.1(19) . . . . ?
C128 N10 C135 C136 -149(3) . . . . ?
C132 N10 C135 C136 44(3) . . . . ?
C129 N10 C135 C136 165(2) . . . . ?
C125 N10 C135 C136 -43(6) . . . . ?
C126 N10 C135 C136 -76(3) . . . . ?
C134 N10 C135 C136 -9(2) . . . . ?
C131 N10 C135 C136 99(3) . . . . ?
N10 C126 C127 C125 -17(2) . . . . ?
N10 C125 C127 C126 17(2) . . . . ?
N10 C129 C130 C128 -21.8(16) . . . . ?
N10 C128 C130 C129 24.0(18) . . . . ?
N10 C131 C133 C132 -15.6(17) . . . . ?
N10 C132 C133 C131 17(2) . . . . ?
N10 C134 C136 C135 -10(2) . . . . ?
N10 C135 C136 C134 10(2) . . . . ?
C137 C138 O17 C139 176.6(12) . . . . ?
C138 O17 C139 C140 176.5(12) . . . . ?
C141 C142 O18 C143 177(3) . . . . ?
C142 O18 C143 C144 -176(3) . . . . ?
C145 C146 O19 C147 75(8) . . . . ?
C146 O19 C147 C148 -162(5) . . . . ?

_diffrn_measured_fraction_theta_max 0.994
_diffrn_reflns_theta_full        21.97
_diffrn_measured_fraction_theta_full 0.994
_refine_diff_density_max         1.308
_refine_diff_density_min         -1.918
_refine_diff_density_rms         0.114


