####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_sad
_audit_block_doi                 10.5517/ccsprqx
_database_code_depnum_ccdc_archive 'CCDC 735900'
loop_
_citation_id
_citation_doi
_citation_year
1 10.1002/anie.200903199 2009
_audit_update_record             
;
2009-06-11 deposited with the CCDC.
2018-08-31 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C64 H64 Cl2 Dy4 N12 O18'
_chemical_formula_weight         2010.17

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.8651(9)
_cell_length_b                   20.3761(16)
_cell_length_c                   14.5767(11)
_cell_angle_alpha                90.00
_cell_angle_beta                 102.3160(10)
_cell_angle_gamma                90.00
_cell_volume                     3443.0(5)
_cell_formula_units_Z            2
_cell_measurement_temperature    200(2)
_cell_measurement_reflns_used    9577
_cell_measurement_theta_min      2.25
_cell_measurement_theta_max      26.34

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      n/a
_exptl_crystal_density_diffrn    1.939
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1948
_exptl_absorpt_coefficient_mu    4.447
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4700
_exptl_absorpt_correction_T_max  0.6647
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      200(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            36039
_diffrn_reflns_av_R_equivalents  0.0994
_diffrn_reflns_av_sigmaI/netI    0.0828
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         1.74
_diffrn_reflns_theta_max         26.43
_reflns_number_total             7062
_reflns_number_gt                4356
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
Refinement of F² against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F², conventional R-factors R are based
on F, with F set to zero for negative F². The threshold expression of
F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F² are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0535P)²+10.7887P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7062
_refine_ls_number_parameters     455
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1042
_refine_ls_R_factor_gt           0.0491
_refine_ls_wR_factor_ref         0.1296
_refine_ls_wR_factor_gt          0.1066
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_restrained_S_all      1.040
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.83150(4) 0.57135(2) 0.62429(3) 0.03006(14) Uani 1 1 d . . .
Dy2 Dy 0.93184(4) 0.41927(2) 0.52273(3) 0.02783(14) Uani 1 1 d . . .
Cl1 Cl 0.6698(2) 0.61613(14) 0.47594(19) 0.0438(7) Uani 1 1 d . . .
N1 N 0.7120(6) 0.4664(4) 0.6242(6) 0.0316(19) Uani 1 1 d . . .
N2 N 0.7395(7) 0.4141(4) 0.5680(6) 0.0338(19) Uani 1 1 d . . .
N3 N 1.1543(8) 0.3084(4) 0.3303(7) 0.047(2) Uani 1 1 d . . .
N4 N 1.2592(8) 0.2731(5) 0.3335(8) 0.070(3) Uani 1 1 d . . .
H4A H 1.2574 0.2340 0.3076 0.084 Uiso 1 1 calc R . .
H4B H 1.3256 0.2905 0.3615 0.084 Uiso 1 1 calc R . .
N5 N 1.0835(7) 0.3588(4) 0.6306(6) 0.035(2) Uani 1 1 d . . .
N6 N 1.1189(8) 0.3014(4) 0.5918(7) 0.054(3) Uani 1 1 d . . .
H6A H 1.1837 0.2820 0.6191 0.065 Uiso 1 1 calc R . .
H6B H 1.0764 0.2848 0.5401 0.065 Uiso 1 1 calc R . .
O1 O 0.6255(7) 0.6625(4) 0.8296(6) 0.058(2) Uani 1 1 d . . .
O2 O 0.6966(6) 0.5893(3) 0.7037(5) 0.0448(19) Uani 1 1 d . . .
O3 O 0.8734(6) 0.3168(3) 0.5150(5) 0.0354(16) Uani 1 1 d . . .
O4 O 0.8858(7) 0.1996(4) 0.4395(6) 0.053(2) Uani 1 1 d . . .
O5 O 0.7770(6) 0.4229(3) 0.3676(4) 0.0355(16) Uani 1 1 d . . .
O6 O 0.9935(5) 0.3864(3) 0.3898(4) 0.0345(16) Uani 1 1 d . . .
O7 O 0.9370(6) 0.5654(3) 0.7914(5) 0.0398(17) Uani 1 1 d . . .
O8 O 0.9596(5) 0.4768(3) 0.6651(4) 0.0289(15) Uani 1 1 d . . .
O9 O 0.8864(5) 0.5280(3) 0.4897(4) 0.0270(14) Uani 1 1 d . . .
C1 C 0.5972(12) 0.7023(7) 0.9017(11) 0.092(6) Uani 1 1 d . . .
H1A H 0.6232 0.7474 0.8952 0.139 Uiso 1 1 calc R . .
H1B H 0.6354 0.6850 0.9632 0.139 Uiso 1 1 calc R . .
H1C H 0.5135 0.7020 0.8965 0.139 Uiso 1 1 calc R . .
C2 C 0.5998(9) 0.5959(6) 0.8290(8) 0.045(3) Uani 1 1 d . . .
C3 C 0.5379(9) 0.5664(6) 0.8881(7) 0.048(3) Uani 1 1 d . . .
H3B H 0.5128 0.5919 0.9345 0.057 Uiso 1 1 calc R . .
C4 C 0.5121(9) 0.4997(6) 0.8801(7) 0.046(3) Uani 1 1 d . . .
H4C H 0.4698 0.4792 0.9207 0.055 Uiso 1 1 calc R . .
C5 C 0.5489(9) 0.4644(5) 0.8127(8) 0.041(3) Uani 1 1 d . . .
H5A H 0.5295 0.4192 0.8061 0.049 Uiso 1 1 calc R . .
C6 C 0.6136(8) 0.4916(5) 0.7533(7) 0.030(2) Uani 1 1 d . . .
C7 C 0.6399(9) 0.5601(5) 0.7593(8) 0.040(3) Uani 1 1 d . . .
C8 C 0.6509(8) 0.4497(5) 0.6844(7) 0.032(2) Uani 1 1 d . . .
H8A H 0.6278 0.4050 0.6834 0.039 Uiso 1 1 calc R . .
C9 C 0.6571(9) 0.3743(5) 0.5317(7) 0.038(2) Uani 1 1 d . . .
H9A H 0.5818 0.3851 0.5395 0.046 Uiso 1 1 calc R . .
C10 C 0.6690(9) 0.3161(5) 0.4812(7) 0.037(2) Uani 1 1 d . . .
C11 C 0.5653(9) 0.2817(6) 0.4381(9) 0.056(3) Uani 1 1 d . . .
H11A H 0.4924 0.3004 0.4400 0.068 Uiso 1 1 calc R . .
C12 C 0.5696(12) 0.2233(7) 0.3950(10) 0.075(4) Uani 1 1 d . . .
H12A H 0.5005 0.2018 0.3649 0.090 Uiso 1 1 calc R . .
C13 C 0.6771(11) 0.1948(6) 0.3952(9) 0.063(4) Uani 1 1 d . . .
H13A H 0.6797 0.1532 0.3664 0.075 Uiso 1 1 calc R . .
C14 C 0.7775(10) 0.2248(5) 0.4353(8) 0.047(3) Uani 1 1 d . . .
C15 C 0.7761(9) 0.2876(5) 0.4792(7) 0.037(2) Uani 1 1 d . . .
C16 C 0.8941(12) 0.1427(6) 0.3844(9) 0.063(4) Uani 1 1 d . . .
H16A H 0.9751 0.1298 0.3928 0.094 Uiso 1 1 calc R . .
H16B H 0.8627 0.1525 0.3181 0.094 Uiso 1 1 calc R . .
H16C H 0.8500 0.1068 0.4046 0.094 Uiso 1 1 calc R . .
C17 C 0.6699(9) 0.4554(6) 0.3447(8) 0.054(3) Uani 1 1 d . . .
H17A H 0.6513 0.4653 0.2773 0.082 Uiso 1 1 calc R . .
H17B H 0.6740 0.4963 0.3805 0.082 Uiso 1 1 calc R . .
H17C H 0.6098 0.4271 0.3601 0.082 Uiso 1 1 calc R . .
C18 C 0.7990(9) 0.3725(6) 0.3056(7) 0.045(3) Uani 1 1 d . . .
C19 C 0.7157(11) 0.3434(6) 0.2402(9) 0.058(3) Uani 1 1 d . . .
H19A H 0.6374 0.3568 0.2299 0.070 Uiso 1 1 calc R . .
C20 C 0.7518(11) 0.2921(6) 0.1883(9) 0.062(4) Uani 1 1 d . . .
H20A H 0.6962 0.2711 0.1408 0.074 Uiso 1 1 calc R . .
C21 C 0.8623(11) 0.2717(6) 0.2035(9) 0.062(4) Uani 1 1 d . . .
H21A H 0.8834 0.2360 0.1688 0.075 Uiso 1 1 calc R . .
C22 C 0.9468(10) 0.3043(6) 0.2724(8) 0.049(3) Uani 1 1 d . . .
C23 C 0.9181(9) 0.3535(5) 0.3229(7) 0.038(3) Uani 1 1 d . . .
C24 C 1.0622(11) 0.2778(6) 0.2873(9) 0.059(3) Uani 1 1 d . . .
H24A H 1.0713 0.2350 0.2639 0.071 Uiso 1 1 calc R . .
C25 C 0.9139(10) 0.6037(6) 0.8663(8) 0.054(3) Uani 1 1 d . . .
H25A H 0.9026 0.5748 0.9173 0.081 Uiso 1 1 calc R . .
H25B H 0.8440 0.6297 0.8441 0.081 Uiso 1 1 calc R . .
H25C H 0.9791 0.6331 0.8894 0.081 Uiso 1 1 calc R . .
C26 C 1.0330(9) 0.5251(5) 0.8138(7) 0.038(3) Uani 1 1 d . . .
C27 C 1.1123(11) 0.5308(7) 0.8960(8) 0.060(4) Uani 1 1 d . . .
H27A H 1.1038 0.5634 0.9407 0.072 Uiso 1 1 calc R . .
C28 C 1.2067(12) 0.4880(8) 0.9135(9) 0.080(5) Uani 1 1 d . . .
H28A H 1.2644 0.4922 0.9695 0.096 Uiso 1 1 calc R . .
C29 C 1.2156(10) 0.4396(6) 0.8492(9) 0.056(3) Uani 1 1 d . . .
H29A H 1.2783 0.4096 0.8628 0.068 Uiso 1 1 calc R . .
C30 C 1.1355(9) 0.4336(5) 0.7655(8) 0.042(3) Uani 1 1 d . . .
C31 C 1.0396(9) 0.4774(5) 0.7450(7) 0.034(2) Uani 1 1 d . . .
C32 C 1.1523(9) 0.3783(5) 0.7058(8) 0.042(3) Uani 1 1 d . . .
H32A H 1.2219 0.3542 0.7249 0.050 Uiso 1 1 calc R . .


_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O2 2.197(7) . ?
Dy1 O6 2.297(6) 3_766 ?
Dy1 O9 2.367(6) . ?
Dy1 O8 2.448(6) . ?
Dy1 O7 2.493(7) . ?
Dy1 N3 2.534(9) 3_766 ?
Dy1 N1 2.565(8) . ?
Dy1 Cl1 2.724(3) . ?
Dy1 Dy2 3.7367(7) . ?
Dy1 Dy2 3.8834(6) 3_766 ?
Dy2 O3 2.196(6) . ?
Dy2 O9 2.306(6) . ?
Dy2 O6 2.312(6) . ?
Dy2 O8 2.344(6) . ?
Dy2 O9 2.451(6) 3_766 ?
Dy2 N5 2.454(8) . ?
Dy2 N2 2.509(8) . ?
Dy2 O5 2.592(6) . ?
Dy2 Dy2 3.7861(9) 3_766 ?
Dy2 Dy1 3.8835(6) 3_766 ?
N1 C8 1.298(11) . ?
N1 N2 1.425(10) . ?
N2 C9 1.293(12) . ?
N3 C24 1.298(14) . ?
N3 N4 1.430(12) . ?
N3 Dy1 2.534(9) 3_766 ?
N5 C32 1.283(13) . ?
N5 N6 1.401(11) . ?
O1 C2 1.391(13) . ?
O1 C1 1.425(13) . ?
O2 C7 1.303(12) . ?
O3 C15 1.304(12) . ?
O4 C14 1.372(13) . ?
O4 C16 1.425(12) . ?
O5 C17 1.409(11) . ?
O5 C18 1.428(13) . ?
O6 C23 1.353(12) . ?
O6 Dy1 2.297(6) 3_766 ?
O7 C26 1.385(12) . ?
O7 C25 1.417(12) . ?
O8 C31 1.337(11) . ?
O9 Dy2 2.451(6) 3_766 ?
C2 C3 1.381(15) . ?
C2 C7 1.414(14) . ?
C3 C4 1.394(16) . ?
C4 C5 1.362(14) . ?
C5 C6 1.389(13) . ?
C6 C7 1.429(14) . ?
C6 C8 1.457(13) . ?
C9 C10 1.419(14) . ?
C10 C15 1.403(14) . ?
C10 C11 1.439(14) . ?
C11 C12 1.352(17) . ?
C12 C13 1.400(17) . ?
C13 C14 1.355(16) . ?
C14 C15 1.433(14) . ?
C18 C19 1.355(15) . ?
C18 C23 1.435(15) . ?
C19 C20 1.411(16) . ?
C20 C21 1.347(16) . ?
C21 C22 1.424(16) . ?
C22 C23 1.331(14) . ?
C22 C24 1.444(16) . ?
C26 C27 1.361(15) . ?
C26 C31 1.411(14) . ?
C27 C28 1.400(18) . ?
C28 C29 1.381(17) . ?
C29 C30 1.383(15) . ?
C30 C31 1.426(14) . ?
C30 C32 1.463(15) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Dy1 O6 139.3(2) . 3_766 ?
O2 Dy1 O9 149.2(2) . . ?
O6 Dy1 O9 69.6(2) 3_766 . ?
O2 Dy1 O8 119.2(2) . . ?
O6 Dy1 O8 77.9(2) 3_766 . ?
O9 Dy1 O8 69.0(2) . . ?
O2 Dy1 O7 76.3(2) . . ?
O6 Dy1 O7 80.2(2) 3_766 . ?
O9 Dy1 O7 128.5(2) . . ?
O8 Dy1 O7 64.4(2) . . ?
O2 Dy1 N3 73.5(3) . 3_766 ?
O6 Dy1 N3 69.5(3) 3_766 3_766 ?
O9 Dy1 N3 124.3(3) . 3_766 ?
O8 Dy1 N3 134.0(3) . 3_766 ?
O7 Dy1 N3 78.5(3) . 3_766 ?
O2 Dy1 N1 71.0(2) . . ?
O6 Dy1 N1 145.3(2) 3_766 . ?
O9 Dy1 N1 86.5(2) . . ?
O8 Dy1 N1 70.0(2) . . ?
O7 Dy1 N1 97.0(2) . . ?
N3 Dy1 N1 144.3(3) 3_766 . ?
O2 Dy1 Cl1 83.9(2) . . ?
O6 Dy1 Cl1 107.50(18) 3_766 . ?
O9 Dy1 Cl1 74.85(15) . . ?
O8 Dy1 Cl1 138.79(15) . . ?
O7 Dy1 Cl1 156.05(17) . . ?
N3 Dy1 Cl1 83.1(2) 3_766 . ?
N1 Dy1 Cl1 89.04(19) . . ?
O2 Dy1 Dy2 132.58(18) . . ?
O6 Dy1 Dy2 84.55(16) 3_766 . ?
O9 Dy1 Dy2 36.35(14) . . ?
O8 Dy1 Dy2 37.77(14) . . ?
O7 Dy1 Dy2 102.15(16) . . ?
N3 Dy1 Dy2 153.7(2) 3_766 . ?
N1 Dy1 Dy2 62.06(17) . . ?
Cl1 Dy1 Dy2 101.15(6) . . ?
O2 Dy1 Dy2 167.51(19) . 3_766 ?
O6 Dy1 Dy2 32.70(15) 3_766 3_766 ?
O9 Dy1 Dy2 37.03(15) . 3_766 ?
O8 Dy1 Dy2 71.82(15) . 3_766 ?
O7 Dy1 Dy2 105.67(16) . 3_766 ?
N3 Dy1 Dy2 94.6(2) 3_766 3_766 ?
N1 Dy1 Dy2 120.36(17) . 3_766 ?
Cl1 Dy1 Dy2 90.88(6) . 3_766 ?
Dy2 Dy1 Dy2 59.547(13) . 3_766 ?
O3 Dy2 O9 147.7(2) . . ?
O3 Dy2 O6 80.5(2) . . ?
O9 Dy2 O6 101.8(2) . . ?
O3 Dy2 O8 120.3(2) . . ?
O9 Dy2 O8 71.8(2) . . ?
O6 Dy2 O8 151.3(2) . . ?
O3 Dy2 O9 133.4(2) . 3_766 ?
O9 Dy2 O9 74.6(2) . 3_766 ?
O6 Dy2 O9 67.9(2) . 3_766 ?
O8 Dy2 O9 83.5(2) . 3_766 ?
O3 Dy2 N5 74.7(3) . . ?
O9 Dy2 N5 136.3(3) . . ?
O6 Dy2 N5 94.1(3) . . ?
O8 Dy2 N5 74.8(2) . . ?
O9 Dy2 N5 74.4(2) 3_766 . ?
O3 Dy2 N2 71.2(2) . . ?
O9 Dy2 N2 84.8(2) . . ?
O6 Dy2 N2 132.6(2) . . ?
O8 Dy2 N2 75.7(2) . . ?
O9 Dy2 N2 154.4(2) 3_766 . ?
N5 Dy2 N2 113.2(3) . . ?
O3 Dy2 O5 79.9(2) . . ?
O9 Dy2 O5 72.5(2) . . ?
O6 Dy2 O5 64.5(2) . . ?
O8 Dy2 O5 134.2(2) . . ?
O9 Dy2 O5 113.2(2) 3_766 . ?
N5 Dy2 O5 149.3(2) . . ?
N2 Dy2 O5 73.5(2) . . ?
O3 Dy2 Dy1 133.26(17) . . ?
O9 Dy2 Dy1 37.46(15) . . ?
O6 Dy2 Dy1 139.20(17) . . ?
O8 Dy2 Dy1 39.76(14) . . ?
O9 Dy2 Dy1 91.45(13) 3_766 . ?
N5 Dy2 Dy1 114.5(2) . . ?
N2 Dy2 Dy1 63.02(18) . . ?
O5 Dy2 Dy1 95.48(14) . . ?
O3 Dy2 Dy2 163.62(16) . 3_766 ?
O9 Dy2 Dy2 38.61(15) . 3_766 ?
O6 Dy2 Dy2 83.21(16) . 3_766 ?
O8 Dy2 Dy2 74.68(15) . 3_766 ?
O9 Dy2 Dy2 35.96(13) 3_766 3_766 ?
N5 Dy2 Dy2 105.46(19) . 3_766 ?
N2 Dy2 Dy2 121.94(18) . 3_766 ?
O5 Dy2 Dy2 94.15(15) . 3_766 ?
Dy1 Dy2 Dy2 62.153(15) . 3_766 ?
O3 Dy2 Dy1 106.02(16) . 3_766 ?
O9 Dy2 Dy1 90.11(15) . 3_766 ?
O6 Dy2 Dy1 32.46(16) . 3_766 ?
O8 Dy2 Dy1 118.82(15) . 3_766 ?
O9 Dy2 Dy1 35.55(14) 3_766 3_766 ?
N5 Dy2 Dy1 82.00(19) . 3_766 ?
N2 Dy2 Dy1 162.24(18) . 3_766 ?
O5 Dy2 Dy1 88.78(15) . 3_766 ?
Dy1 Dy2 Dy1 120.453(13) . 3_766 ?
Dy2 Dy2 Dy1 58.300(13) 3_766 3_766 ?
C8 N1 N2 114.9(8) . . ?
C8 N1 Dy1 127.5(7) . . ?
N2 N1 Dy1 115.5(5) . . ?
C9 N2 N1 117.3(8) . . ?
C9 N2 Dy2 124.8(7) . . ?
N1 N2 Dy2 116.9(5) . . ?
C24 N3 N4 114.3(9) . . ?
C24 N3 Dy1 126.4(8) . 3_766 ?
N4 N3 Dy1 118.0(6) . 3_766 ?
C32 N5 N6 114.4(9) . . ?
C32 N5 Dy2 129.7(7) . . ?
N6 N5 Dy2 113.7(6) . . ?
C2 O1 C1 118.3(10) . . ?
C7 O2 Dy1 141.4(7) . . ?
C15 O3 Dy2 134.2(6) . . ?
C14 O4 C16 117.1(9) . . ?
C17 O5 C18 117.7(8) . . ?
C17 O5 Dy2 131.0(6) . . ?
C18 O5 Dy2 109.9(5) . . ?
C23 O6 Dy1 126.4(6) . 3_766 ?
C23 O6 Dy2 117.9(6) . . ?
Dy1 O6 Dy2 114.8(3) 3_766 . ?
C26 O7 C25 115.4(8) . . ?
C26 O7 Dy1 118.4(6) . . ?
C25 O7 Dy1 125.9(6) . . ?
C31 O8 Dy2 135.7(6) . . ?
C31 O8 Dy1 119.5(6) . . ?
Dy2 O8 Dy1 102.5(2) . . ?
Dy2 O9 Dy1 106.2(2) . . ?
Dy2 O9 Dy2 105.4(2) . 3_766 ?
Dy1 O9 Dy2 107.4(2) . 3_766 ?
C3 C2 O1 124.4(10) . . ?
C3 C2 C7 121.9(11) . . ?
O1 C2 C7 113.6(10) . . ?
C2 C3 C4 120.5(10) . . ?
C5 C4 C3 118.5(10) . . ?
C4 C5 C6 123.0(10) . . ?
C5 C6 C7 119.6(9) . . ?
C5 C6 C8 119.0(9) . . ?
C7 C6 C8 121.4(9) . . ?
O2 C7 C2 120.6(10) . . ?
O2 C7 C6 123.0(9) . . ?
C2 C7 C6 116.5(10) . . ?
N1 C8 C6 127.4(9) . . ?
N2 C9 C10 125.8(9) . . ?
C15 C10 C9 123.2(9) . . ?
C15 C10 C11 118.9(10) . . ?
C9 C10 C11 117.6(10) . . ?
C12 C11 C10 121.2(11) . . ?
C11 C12 C13 119.2(12) . . ?
C14 C13 C12 122.1(12) . . ?
C13 C14 O4 125.4(11) . . ?
C13 C14 C15 120.1(11) . . ?
O4 C14 C15 114.5(10) . . ?
O3 C15 C10 122.1(9) . . ?
O3 C15 C14 119.4(9) . . ?
C10 C15 C14 118.4(10) . . ?
C19 C18 O5 123.8(10) . . ?
C19 C18 C23 123.2(11) . . ?
O5 C18 C23 112.9(9) . . ?
C18 C19 C20 116.3(12) . . ?
C21 C20 C19 122.4(12) . . ?
C20 C21 C22 119.1(12) . . ?
C23 C22 C21 121.1(11) . . ?
C23 C22 C24 123.1(11) . . ?
C21 C22 C24 115.7(11) . . ?
C22 C23 O6 124.3(10) . . ?
C22 C23 C18 117.8(10) . . ?
O6 C23 C18 117.9(9) . . ?
N3 C24 C22 124.5(11) . . ?
C27 C26 O7 122.4(10) . . ?
C27 C26 C31 123.5(11) . . ?
O7 C26 C31 114.1(9) . . ?
C26 C27 C28 118.9(11) . . ?
C29 C28 C27 119.7(12) . . ?
C28 C29 C30 121.6(12) . . ?
C29 C30 C31 119.8(10) . . ?
C29 C30 C32 115.9(10) . . ?
C31 C30 C32 124.2(10) . . ?
O8 C31 C26 119.3(9) . . ?
O8 C31 C30 124.2(9) . . ?
C26 C31 C30 116.4(10) . . ?
N5 C32 C30 127.2(10) . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        26.43
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         1.580
_refine_diff_density_min         -0.949
_refine_diff_density_rms         0.202

